Perfluorohexyl Radical置于氢碘酸体系中,用 Gas 作为反应溶剂,286.9~426.9 °C,40.0 Kpa 条件下,反应生成 全氟己基碘烷 参考文献:Skorobogatov,G. A.; Dymov,B. P.; Tedeev,R. Sh.,Journal Of General Chemistry Of The Ussr,1991,Vol. 61,# 1.2,P. 158-165 标题:Skorobogatov,G. A.; Dymov,B. P.; Tedeev,R. Sh.,Journal Of General Chemistry Of The Ussr,1991,Vol. 61,# 1.2,P. 158-165
专利号:US-4756739-A 优先权日:1985-12-21 标题 :Pyridine derivatives and the N-oxides thereof, and the use thereof as intermediates for the synthesis of plant protecting agents 发明人:FUSS ANDREAS; KOCH VOLKER 权利人:HOECHST AG 摘要:The compounds of the formula I (I) in which A denotes N or N->O, Z denotes O or NH, R denotes H, (halo)alkyl, (halo)alkenyl, (halo)alkynyl or alkoxycarbonyl, R1 denotes hydrogen, halogen, amino, -NHOH, hydroxyl, (substituted) phenylazo or a radical of the formulae Y=C=N-, Y1Y2C=N-, Y3NH- or K denotes 0 or 1, and m and n, independently of one another, denote a number from 1 to 4, with the proviso that, when Z-R denotes OH or NH2, (R1)n denotes at least one radical of the formula or represents two radicals, in the 5 or 6 position of the heterocyclic ring, which, in the 5 position, denote halogen and, in the 6 position, denote a radical of the group comprising halogen, amino, hydroxyl or phenylazo, which may be substituted as specified above, are valuable intermediates in the synthesis of plant protection agents.
专利号:US-9394394-B2 优先权日:2013-09-30 标题:Synthesis of chlorotrifluoroethylene-based block copolymers by iodine transfer polymerization 发明人:THENAPPAN ALAGAPPAN; AMEDURI BRUNO; LOPEZ GERALD 权利人:HONEYWELL INT INC 摘要:Methods for the synthesis of CTFE-based block copolymers through iodine transfer polymerization are disclosed. In an exemplary embodiment, a method includes reacting a fluoromonomer “Mâ€? with a chain transfer agent of the formula X—Y or Y—X—Y, wherein X represents a C 1 -C 3 hydrocarbon, a C 1 -C 6 hydrofluorocarbon, C 1 -C 6 hydrochlorofluorocarbon, or C 1 -C 6 fluorocarbon and Y represents iodine or bromine, in the presence of a radical initiator, to form a macro-initiator of the formula: X-poly(M)-Y or Y-poly(M)-X-poly(M)-Y, wherein poly(M) represents a polymer of the fluoromonomer. The method further includes reacting the macro-initiator with chlorotrifluoroethylene (CTFE) in the presence of a radical initiator to form a diblock or a triblock CTFE-based block copolymer of the formula: X-poly(M)-block-poly(CTFE) or PCTFE-block-poly(M)-X-poly(M)-block-PCTFE.
专利号:US-5382723-A 优先权日:1991-02-12 标 题 :Synthesis of hydrogen perfluoroalkanes 发明人:DURUAL PIERRE; LANTZ ANDRE 权利人:ATOCHEM ELF SA 摘要:The invention relates to the synthesis of hydrogenperfluoroalkanes R F H, R F denoting a perfluoroalkyl radical containing 2 to 20 carbon atoms, by reaction of the corresponding perfluoroalkyl iodide R F I with an alkali metal hydroxide. n The use of methanol as solvent allows the formation of tars to be avoided, an almost total conversion of R F I and an R F H of excellent purity to be obtained, and the alkali metal iodide by-product to be recovered easily.
专利号:US-2007100184-A1 优先权日:2005-10-27 标题 :Alkylation of aromatic compounds 发明人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA 权利人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA 摘要:The present invention relates to the synthesis of alkylated aromatic compounds using ionic liquids as the solvent. Alkylated aromatic compounds are synthesized by reacting an aromatic compound with a monoolefin in the presence of an acid catalyst.
专利号:US-6656446-B1 优先权日:1999-04-29 标题:Synthesis of hydrogen peroxide 发明人:BECKMAN ERIC J; HANCU DAN 权利人:UNIV PITTSBURGH 摘要:A method for synthesizing hydrogen peroxide comprises the step of: mixing an analog of a secondary alcohol that is soluble with carbon dioxide with a free radical initiator and oxygen in carbon dioxide to generate hydrogen peroxide. Another method of synthesizing hydrogen peroxide comprises the step of: mixing hydrogen, oxygen and a CO 2 -philic catalyst in carbon dioxide phase. The CO 2 -philic catalyst is soluble or miscible in carbon dioxide and is suitable to catalyze the reaction of hydrogen and oxygen to produce hydrogen peroxide. The method also comprises the step of reacting the hydrogen and oxygen to produce hydrogen peroxide.
专利号:US-4983776-A 优先权日:1988-05-04 标 题:Process for the preparation of functional fluoro derivatives 发明人:BENEFICE-MALOUET SYLVIE; BLANCOU HUBERT; COMMEYRAS AUGUSTE 权利人:ATOCHEM 摘要:The invention relates to the synthesis of functional fluoro derivatives and more particularly that of perfluorinated aldehydes of the type R F -CHO where R F denotes a linear or branched perfluoroalkyl radical. n A perfluoroalkyl iodide R F I is reacted over the zinc-copper metal couple, in the presence of a radical initiator, with an amide RCONR 1 R 2 , R denoting a hydrogen atom or a methyl or ethyl radical, and each of R 1 and R 2 denoting a C 1 -C 4 alkyl radical.
[参考文献]: Chang Wang, Et Al. The In Vitro Estrogenic Activities Of Polyfluorinated Iodine Alkanes. Environ Health Perspect. 2012 Jan;120(1):119-25. [参考文献]: V Kolaíková, Et Al. Transition Metal Complexes Bearing Nhc Ligands Substituted With Secondary Polyfluoroalkyl Groups. Dalton Trans. 2015 Dec 7;44(45):19663-73.
合成参考文献
摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 27. 摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1044. 摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 48. 摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 16. 摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 98.