CAS: 19812-64-7; Tetradecane-1,14-Diol

该化合物是一种直链脂性二醇,分子式为C14H30O2.它拥有位于14碳链终端位置的两个氢氧(-OH)功能组,有助于将其分类为二醇,该化合物通常是无色的,在室温下不毛的固体,在有机溶剂中可溶解,同时由于它具有疏水碳氢链,在水中表现出有限的溶解性.氢氧基体的存在具有一定程度的极性,允许氢联结,从而能够影响其物理特性和再活动. 在各种应用中经常使用1,14-Tetradecanediol, 包括作为表面活性剂,乳化剂,以及聚合物和其他化学中间体的合成.它的特点使得它对于化妆品,润滑剂和其他工业产品的配制具有价值.此外,它可能表现出低毒性,但处理和使用准则时必须参考安全数据.

结构式图片

相似化合物

821-38-5 5024-21-5 17278-74-9

上下游产品

CAS号821-38-5 十四烷二酸 | CAS号5024-21-5 十四烯二酸二甲酯 | CAS号19812-63-6 十四烷二酸二乙酯 | CAS号21964-49-8 1,13-十四烷二烯 | CAS号72312-51-7 tetradeca-2,12-... | CAS号75-21-8 环氧乙烷 | CAS号107921-24-4 (4E,10E)-tetrad... | CAS号877122-95-7 tetradeca-2c,12... | CAS号37688-96-3 1,14-二溴十四烷 | CAS号72995-94-9 14-溴-1-十四烷醇 | CAS号286854-05-5 14-phenylmethox... | CAS号24772-66-5 1,14-diiodotetr... | CAS号871-70-5 十八烷二酸 | CAS号505-54-4 十六烷二酸 | CAS号116754-57-5 2-(14-bromotetr... | CAS号824404-33-3 17-[tert-butyl(... | CAS号824404-36-6 tert-butyl-(14-... | CAS号824404-38-8 14-iodotetradec...

合成工艺路线路线简述

  • 合成目标产物 1,14-Tetradecanediol 主要起始原料 Dimethyl Tetradecanedioate
  • (文献来源)合成步骤主要原料 Dimethyl Tetradecanedioate
(1,13-十四烷二)烯置于9-Borabicyclo[3.3.1]Nonane Dimer,Dimethyl Sulfide Borane体系中,用38%的收率获得1,14-十四烷二醇
参考文献:Hydroboration. 67. Cyclic Hydroboration Of Acyclic .Alpha.,.Omega.-Dienes With 9-Borabicyclo[3.3.1]Nonane/borane-Dimethyl Sulfide
标题:Hydroboration. 67. Cyclic Hydroboration Of Acyclic .Alpha.,.Omega.-Dienes With 9-Borabicyclo[3.3.1]Nonane/borane-Dimethyl Sulfide
摘要:
Doi:10.1021/jo00180A023

海关参考信息

专利信息


专利号:US-6538153-B1
优先权日:2001-09-25
标 题:Method of synthesis of water soluble fullerene polyacids using a macrocyclic malonate reactant
发明人:HIRSCH ANDREAS; REUTHER UWE
权利人:SIXTY INC C
摘要:A method for synthesizing compounds of the formulawhere C60 is a C60 fullerene. The method comprises the steps of forming a macrocyclic malonate compound of the formulawhere each Z is the same or different and is a straight-chain or branched-chain aliphatic radical having from 1-30 carbon atoms which may be unsubstituted or monosubstituted or polysubstituted by identical or different substitutents, in which radicals up to every third CH2 unit can be replaced by O or NR where R is alkyl having 1-20 carbon atoms or a chain containing unsubstituted or substituted aryl or other cyclic groups and n is an integer from 2 to 10; reacting said macrocyclic malonate compound with C60 to form an adduct of the formulawhere the Z radicals are linked together to form said macrocycle adduct; and hydrolyzing said macrocycle adduct to form a compound of the formula

专利号:US-8877977-B2
优先权日:2011-11-25
标题 :Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
权利人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO; BASF SE
摘要:Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

专利号:WO-2013076053-A1
优先权日:2011-11-25
标题:Synthesis of polyalkylene polyamines with low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
权利人:BASF SE; STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
摘要:The invention relates to a method for the production of polyalkylene polyamines by homogeneously catalyzed alcohol amination, wherein aliphatic alkanolamines are reacted with each other or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols in the presence of a homogeneous catalyst while eliminating water and in the presence of hydrogen gas. The invention further relates to polyalkylene polyamines, which can be obtained by said methods, and to polyalkylene polyamines which contain hydroxyl groups, secondary amines or tertiary amines. The invention finally relates to uses of said polyalkylene polyamines as adhesion promoters in inks, adhesion promoters in composite films, cohesion promoters in adhesives, cross-linkers/hardeners for resins, primers for paints, wet adhesion promoters for dispersion paints, complexing agents and flocculants, penetration auxiliaries for use in wood preservation, corrosion inhibitors, and immobilization agents of proteins and enzymes.

专利号:US-11155505-B2
优先权日:2017-02-17
标题 :Synthesis of pheromones and related materials via olefin metathesis
发明人:WAMPLER KEITH M; BUI VU; ROZZELL DAVID; COELHO PEDRO; FLORUTI ARTHUR; ONDI LEVENTE; MEHDI HASAN; EROS GABOR
权利人:PROVIVI INC
摘要:Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

专利号:US-2009111737-A1
优先权日:1999-05-24
标题:Novel antibacterial agents
发明人:CHRISTENSEN BURTON G; MORAN EDMUND J; GRIFFIN JOHN H; JUDICE J KEVIN; MU YONGQI; PACE JOHN L; MAMMEN MATHAI; AGGEN JAMES
权利人:CHRISTENSEN BURTON G; MORAN EDMUND J; GRIFFIN JOHN H; JUDICE J KEVIN; MU YONGQI; PACE JOHN L; MAMMEN MATHAI; AGGEN JAMES
摘要:This invention relates to novel multibinding compounds (agents) that are antibacterial agents. The multibinding compounds of the invention comprise from 2-10 ligands covalently connected by a linker or linkers, wherein each of said ligands in their monovalent (i.e., unlinked) state have the ability to bind to a an enzyme involved in cell wall biosynthesis and metabolism, a precursor used in the synthesis of the bacterial cell wall and/or the bacterial cell surface thereby interfere with the synthesis and/or metabolism of the cell wall. In particular the multibinding compounds of the invention comprise from 2-10 ligands covalently connected by a linker or linkers, wherein each of said ligands hasn a ligand domain capable of binding to penicillin binding proteins, a transpeptidase enzyme, a substrate of a transpeptidase enzyme, a beta-lactamase enzyme, pencillinase enzyme, cephalosporinase enzyme, a transglycoslase enzyme, or a transglycosylase enzyme substrate; Preferably, the ligands are selected from the beta lactam or glycopeptide class of antibacterial agents.

专利号:US-9388345-B2
优先权日:2012-07-03
标题:Hydrocarbon synthesis methods, apparatus, and systems
发明人:MCNEFF CLAYTON V; MCNEFF LARRY C; NOWLAN DANIEL THOMAS; YAN BINGWEN; GREUEL PETER G
权利人:SARTEC CORP
摘要:Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.
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参考文献:10.1007/s11172-023-3867-4
摘要:Kadikova RN, Vyatkin AV, Gabdullin AM, Mozgovoj OS, Dzhemilev UM, Ramazanov IR. Negishi reaction in the synthesis of (ω-hydroxyalkyl-1-en-1-yl selenides. Russ Chem Bull. 2023 Apr;72(4):1023–8. doi: 10.1007/s11172-023-3867-4.
参考文献:10.1007/s13762-023-05158-3
摘要:Chen H, Hao Y, Zhang SL, Pan JR, Lang MF, Guo XT. Vertical migration and variation of crude oil in soil around typical oilfields under natural leaching. Int. J. Environ. Sci. Technol. 2023 Aug 28;21(3):3073–86. doi: 10.1007/s13762-023-05158-3.
参考文献:10.1007/s10118-025-3392-9
摘要:Sun Y, Cao Y, Huang H, Shen S, Xia Y, Shao T, Zhang C, Zhang X. Poly(thiocarbonate) Synthesis from Carbonyl Sulfide (or Carbon Disulfide), Diol, and Dichlorides: A Step Growth Route to PE-like Sulfur-containing Polymers. Chin J Polym Sci. 2025 Sep 10;43(10):1774–84. doi: 10.1007/s10118-025-3392-9.
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