CAS: 15525-15-2; Tetraphenylphosphonium Tetraphenylborate

该化合物是一种磷基离子化合物,广泛用作有机合成中的逐步转移催化剂和催化剂,其主要优点包括高度稳定,水溶性低,以及有效促进与阴离子有关的反应. 该化合物对于其分离和净化大型有机碳化物的能力特别宝贵.

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14637-34-4 2751-90-8 2001-45-8

欧盟法规

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上下游产品

sodium tetraphenyl borate tetraphenyl phosphonium chloride pentaphenylphosphorane triphenylborane

合成工艺路线路线简述

    📜三苯基硼氢氧化钠加合物 以 乙醚,水 用作溶剂,化学反应生成四苯基硼四苯基膦
    参考文献:Wittig,G.; Raff,P.,Liebigs Annalen Der Chemie,1951,Vol. 573,P. 195-209
    标题:Wittig,G.; Raff,P.,Liebigs Annalen Der Chemie,1951,Vol. 573,P. 195-209

    专利信息


    专利号:US-6288202-B1
    优先权日:1997-04-11
    标题 :Synthesis of polycarbonates using Co2
    发明人:DESIMONE JOSEPH M; GIVENS RAMONE; JIKEI MITSUTOSHI; COHEN JEFFREY D
    权利人:UNIV NORTH CAROLINA
    摘要:A process of forming a polycarbonate comprises providing a reaction mixture of at least one polycarbonate-forming monomer and carbon dioxide; and then reacting the polycarbonate-forming monomer and carbon dioxide in the reaction mixture to form the polycarbonate. In one embodiment, the polycarbonate is present in a condensate, and the process further comprises removing carbon dioxide from the reaction mixture; and then collecting the condensate from the reaction mixture. Moreover, uncrystallized polycarbonate may be treated with carbon dioxide to form crystalline polycarbonate. The crystalline polycarbonate is then rendered useful for solid state polymerization.

    专利号:WO-2016033079-A1
    优先权日:2014-08-29
    标题:Synthesis of naphthol novolac
    发明人:FANG LIJING; LIAO GUIHONG; CHEN HONGYU; ZHANG CHAO; MULLINS MICHAEL J
    权利人:BLUE CUBE IP LLC
    摘要:A method for making naphthol novolac comprising: contacting a) a naphthol component comprising i) from 1 to 99 weight percent 1- naphthol; and ii) from 1 to 99 weight percent 2-naphthol; and b) an aldehyde in a reaction zone under reaction conditions to form the naphthol novolac, is disclosed. Also disclosed is a curable composition comprising: a) an epoxy resin; and b) a hardener component comprising i) an oligomeric compound comprising a phosphorus composition which is the reaction product of an etherified resole with 9,10-dihydro-9-oxa-10- phosphaphenanthrene-10-oxide, and ii) a naphthol novolac prepared by the above method. The curable composition can be used to prepare prepregs and electrical laminates.

    专利号:US-2023093326-A1
    优先权日:2020-06-19
    标 题 :Polyester Carbonates on the Basis of Cycloaliphatic Diacids, 1,4:3,6-Dianhydrohexitol and Specific Amounts of an Additional Aliphatic Dihydroxy Compound
    发明人:MEYER ALEXANDER; SCHULZ LUKAS FABIAN; PFINGST THOMAS
    权利人:COVESTRO DEUTSCHLAND AG
    摘要:The present invention relates to a process for preparing a polyester carbonate on the basis of cycloaliphatic diacids and at least one 1,4:3,6-dianhydrohexitol and at least one additional aliphatic dihydroxy compound, to the polyester carbonate prepared according to the process and to a molding compound and a molding body containing the polyester carbonate. The process according to the invention is a direct synthesis, in which all structural elements forming the subsequent polyester carbonate are present as monomers already in the first process step. It is characterized in that a specific ratio of 1,4:3,6-dianhydrohexitol and the at least one additional aliphatic dihydroxy compound is advantageous.

    专利号:WO-2016029451-A1
    优先权日:2014-08-29
    标题:Synthesis of naphthol novolac

    专利号:US-12173150-B2
    优先权日:2018-12-20
    标题:Polyester carbonates from cycloaliphatic diacids and aliphatic diols, and process for preparing same
    发明人:MEYER ALEXANDER; PFINGST THOMAS; HEUER HELMUT WERNER; HEIJL JAN; BERTIN ANNABELLE
    权利人:COVESTRO INTELLECTUAL PROPERTY GMBH & CO KG
    摘要:The present invention relates to a method for preparing a polyester carbonate starting from cycloaliphatic diacids and aliphatic diols and to the polyester carbonate prepared by the method. The method according to the invention is a direct synthesis in which all the structural elements that form the subsequent polyester carbonate are already present as monomers in the first step of the method.

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