CAS: 6180-99-0; Tributyl(Deuterio)Stannane

该化合物是有机锡化合物,其特征是附在锡原子上的三丁基化合物,以及稳定的氢同位素--氢,该化合物通常用作有机合成中的减少剂,特别是将碳基化合物减少到相应的酒精;与其他有机锡化合物相比,其毒性相对较低,但由于潜在的环境和健康影响,人们仍告诫要谨慎行事.三丁基脱氧化物是淡黄色液体的无色物质,可溶于有机溶剂中.其化学稳定性中度,可与湿度发生反应,释放有毒副产品.其结构中存在的能用于同位素标签研究,这可能有助于化学研究中追踪反应途径.

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CAS号1461-22-9 三丁基氯化锡 | CAS号1067-52-3 三正丁基甲氧基锡 | CAS号789-25-3 三苯基硅烷 | CAS号27262-82-4 tributylstannyl... | CAS号7789-20-0 重水 | CAS号56-35-9 三丁基氧化锡 | CAS号41968-75-6 tributyl(4-chlo... | CAS号40894-18-6 tributyl(3-chlo... | CAS号1067-24-9 Dimethylaminotr... | CAS号1461-23-0 三正丁基溴化锡 | CAS号1461-22-9 三丁基氯化锡 | CAS号1067-52-3 三正丁基甲氧基锡 | CAS号53716-53-3 n-butane-1-d1 | CAS号20763-88-6 tri-n-butylstan...

合成工艺路线路线简述

    📜三丁基氧化锡 反应生成 氘代三正丁基锡
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Comp.12,1.4.1.1.1.5.2.1.1,Page 38-56
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Comp.12,1.4.1.1.1.5.2.1.1,Page 38-56

    海关参考信息

    专利信息


    专利号:US-9512162-B2
    优先权日:2012-07-31
    标题 :Synthesis of deuterated ribo nucleosides, N-protected phosphoramidites and oligonucleotides
    发明人：SRIVASTAVA SURESH C; YASKO AMY
    权利人:ASED LLC
    摘要:The present invention is directed towards the synthesis of high purity deuterated sugars, deuterated phosphoramidites, deuterated nucleobases, deuterated nucleosides, deuterated oligonucleotides, and deuterated RNA's of defined sequences which can exhibit biochemically useful and biologically valuable properties, thus having potential for therapeutic uses.

    专利号:US-9493773-B2
    优先权日:2012-07-31
    标题:Synthesis of deuterated ribo nucleosides, N-protected phosphoramidites, and oligonucleotides
    发明人：SRIVASTAVA SURESH C; YASKO AMY
    权利人:ASED LLC
    摘要:The present invention is directed towards the synthesis of high purity deuterated sugars, deuterated phosphoramidites, deuterated nucleobases, deuterated nucleosides, deuterated oligonucleotides, and deuterated RNA's of defined sequences which can exhibit biochemically useful and biologically valuable properties, thus having potential for therapeutic uses.

    专利号:US-9365607-B1
    优先权日:2012-07-31
    标题 :Synthesis of deuterated ribo nucleosides, N-protected phosphoramidites, and oligonucleotides
    发明人：SRIVASTAVA SURESH C; YASKO AMY
    权利人:ASED LLC
    摘要:The present invention is directed towards the synthesis of high purity deuterated sugars, deuterated phosphoramidites, deuterated nucleobases, deuterated nucleosides, deuterated oligonucleotides, and deuterated RNA's of defined sequences which can exhibit biochemically useful and biologically valuable properties, thus having potential for therapeutic uses.

    专利号:US-9045521-B2
    优先权日:2012-07-31
    标 题 :Synthesis of deuterated ribo nucleosides N-protected phosphoramidites, and oligonucleotides
    发明人：SRIVASTAVA SURESH C; YASKO AMY
    权利人:SRIVASTAVA SURESH C; YASKO AMY; ASED LLC
    摘要:The present invention is directed towards the synthesis of high purity deuterated sugars, deuterated phosphoramidites, deuterated nucleobases, deuterated nucleosides, deuterated oligonucleotides, and deuterated RNA's of defined sequences which can exhibit biochemically useful and biologically valuable properties, thus having potential for therapeutic uses.

    专利号:US-6160128-A
    优先权日:1997-12-22
    标题:Tritioacetylating reagents and processes for preparation thereof
    发明人：SALJOUGHIAN MANOUCHEHR; MORIMOTO HIROMI; WILLIAMS PHILIP G; THAN CHIT
    权利人:UNIV CALIFORNIA
    摘要:Novel acetylating and tritioacetylating reagents suitable for preparation of nonlabelled and radiolabelled organic compounds. N-acetoxynaphthalimide, N-tritioacetoxyphthalimide, N-tritioacetoxysuccinimide, N-tritioacetoxynaphthalimide and processes of their preparation. The invention also concerns synthesis of nonlabelled acetylated and tritioacetylated organic compounds from precursors containing a free --NH 2 , --SH or --OH group.

    专利号:US-2014039175-A1
    优先权日:2012-07-31
    标 题:Synthesis of deuterated ribo nucleosides, N-protected phosphoramidites, and oligonucleotides

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    主要参考文献

    参考标题:One‐step Synthesis Of Dendritic Highly Branched Polystyrenes By Organotellurium‐mediated Copolymerization Of Styrene And A Dienyl Telluride Monomer
    作者:Yangtian Lu,Shigeru Yamago |发布日期:2019.3.18
    摘要:Dendritic Highly Branched Polystyrenes (Hb‐psts) Were Prepared By A One‐step Copolymerization Of Dienyl Telluride 6 And St In The Presence Of Organotellurium Chain Transfer Agent 2. The Molecular Weight (Mw), Dendritic Generation, And Branching Density Were Easily Controlled By The Ratio Of 2 To 6 To Styrene (St) With Maintaining Monodispersity. The Branching Efficiency Estimated By A Deuterium‐labeling

    合成参考文献


    摘要:Drabowicz, J.; Krasowska, D.; Wicha, J., Science of Synthesis, (2009) 48, 258.
    摘要:Tchabanenko, K., Science of Synthesis Knowledge Updates, (2013) 1, 7.
    摘要:Treacy, S. M.; Zhang, X.; Rovis, T., Science of Synthesis, (2021) , 623.
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