CAS: 21679-31-2; Chromium(Iii) Acetylacetonate

该化合物是配方Cr(C5H7O2)3的协调化合物.该化合物的特点是一种铬离子,它与三种丙烯酸酯(酸酯)相协调,它们是染色剂.该化合物一般是紫色或紫色固体,在乙醇和丙酮等有机溶剂中溶解,但水溶解较少.其特点是其稳定的铬结构,它能增强不同氧化状态中铬离子的稳定性.Tris(acytylacetonato)chromium经常用于有机合成,催化以及制铬材料的前体.此外,该化合物具有有趣的磁性和电子性,成为协调化学的一个研究对象.在处理该化合物时,应当采取安全防范措施,因为铬化合物可以是有毒的,并构成环境危害.适当的储存和处置方法对于减轻其相关风险至关重要.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    Sodioacetylacetone 反应生成 Chromium(III) Acetylacetonate
    参考文献:Makhaew W. D.,Borisow A. P.,Aleshin W. W.,Petrowa L. A.,Isw. An. Ser. Khim,(1995) N 6,S 1150-1152
    标题:Makhaew W. D.,Borisow A. P.,Aleshin W. W.,Petrowa L. A.,Isw. An. Ser. Khim,(1995) N 6,S 1150-1152

    海关参考信息

    专利信息


    专利号:US-6479685-B2
    优先权日:1998-01-09
    标题 :Metallocene catalysts for synthesis of high-melting polyolefin copolymer elastomers
    发明人:WAYMOUTH ROBERT M; KRAVCHENKO RAISA L; MACIEJEWSKI PETOFF JENNIFER; HUNG JOYCE
    权利人:TRUSTEES OF THE LELAND STANDAR
    摘要:Metallocene catalysts having plural coordination geometries for synthesis of high melting polyolefin copolymers suitable as thermoplastic elastomers. The inventive catalysts comprise unbridged, substituted or unsubstituted cyclopentadienyl metallocene catalysts that are capable of inter-converting between states with different polymerization or copolymerization characteristics, which interconversion is controlled by selecting the substituents of the cyclopentadienyl ligands so that the rate of interconversion of the two states is within several orders of magnitude of the rate of formation of a single polymer chain. Where r i >r f the polymer can be characterized as multiblock; where r i
    专利号:US-5166110-A
    优先权日:1989-12-22
    标 题 :Process for the synthesis of ziegler-type catalytic solids or solid constituents of the same
    发明人:BRUN CLAUDE
    权利人:ATOCHEM ELF SA
    摘要:A process is provided for the synthesis of a solid Ziegler catalyst or of a transition metal solid constituent thereof, which entails preparing the solid catalyst or constituent thereof as a suspension in an inert liquid medium by contacting precursors or ingredients of the catalyst or of the constituent in the inert liquid medium in one or more steps, and drying the suspension, and collecting the catalyst or constituent thereof; and wherein the process is conducted in a single multi-function reactor having a longitudinal axis and which can pivot around an axis which intersects perpendicularly with this axis.

    专利号:US-2024327997-A1
    优先权日:2023-03-28
    标题 :Electrocatalytic Conversion of Nitrates and Nitrites to Ammonia
    发明人:ATANASSOV PLAMEN; MURPHY EAMONN; LIU YUANCHAO; SPOERKE ERIK DAVID
    权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC; UNIV CALIFORNIA
    摘要:Electrocatalytic reduction of waste nitrates (NO3−) enables the synthesis of ammonia (NH3) in a carbon neutral and decentralized manner. The present invention uses atomically dispersed transition metal-nitrogen-carbon (M-N—C) catalysts with varying metal centers to uniquely favor mono-nitrogen products (e.g., NH3) via the electrochemical nitrate reduction reaction (NO3RR).

    专利号:US-7348395-B2
    优先权日:2003-12-15
    标 题:Synthesis of oligomeric cyanate esters
    发明人:KELLER TEDDY M; LASKOSKI MATTHEW
    权利人:US NAVY
    摘要:A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.n nHO—Ar 2 O—Ar 1 —O—Ar 2 n OH

    专利号:US-7338647-B2
    优先权日:2004-05-20
    标 题:Synthesis of cathode active materials
    发明人:HUANG BIYING; SWOYER JEFFREY; SAIDI M YAZID; HUANG HAITAO
    权利人:VALENCE TECHNOLOGY INC
    摘要:The present invention relates to a method for preparing an electroactive metal polyanion or a mixed metal polyanion comprising forming a slurry comprising a polymeric material, a solvent, a polyanion source or alkali metal polyanion source and at least one metal ion source; heating said slurry at a temperature and for a time sufficient to remove the solvent and form an essentially dried mixture; and heating said mixture at a temperature and for a time sufficient to produce an electroactive metal polyanion or electroactive mixed metal polyanion. In an alternative embodiment the present invention relates to a method for preparing a metal polyanion or a mixed metal polyanion which comprises mixing a polymeric material with a polyanion source or alternatively an alkali metal polyanion source and a source of at least one metal ion to produce a fine mixture and heating the mixture to a temperature higher than the melting point of the polymeric material, milling the resulting material and then heating the milled material. It is another object of the invention to provide electrochemically active materials produced by said methods. The electrochemically active materials so produced are useful in making electrodes and batteries.

    专利号:US-5162592-A
    优先权日:1991-11-25
    标题:One-step synthesis of methyl t-butyl ether from t-butanol using multimetal-modified zeolite catalysts
    发明人:KNIFTON JOHN F; SANDERSON JOHN R; DAI PEISHING E
    权利人:TEXACO CHEMICAL
    摘要:Disclosed is an improved process for preparing methyl t-butyl ether in one step which comprises reacting tertiary butanol and methanol in the presence of a catalyst comprising a zeolite modified with a metal selected from the group consisting of Groups IB, VB, VIB, VIIB or VIII of the Periodic Table at a temperature of about 20° C. to 250° C. and atmospheric pressure to about 1000 psig, wherein when the temperature is in the operating range above about 160° C., the product comprises a two-phase mix of an isobutylene-MTBE product-rich phase and a heavier aqueous methanol-rich phase.
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    摘要:Toxicology and Applied Pharmacology., 28(313), 1974 []
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