CAS: 97985-66-5; (E)-3-(3-Bromophenyl)Acrylaldehyde

英文名称(E)-3-(3-Bromophenyl)Acrylaldehyde
中文名称3-溴肉桂醛
IUPAC名称(E)-3-(3-bromophenyl)acrylaldehyde
其它别名3-Bromocinnamaldehyde; 2-Propenal, 3-(3-Bromophenyl)-,(2E); (E)-3-(3-Bromophenyl)-2-Propenal; Trans-3-Bromocinnamaldehyde; (E)-3-(3-Bromophenyl)Acrylaldehyde; 3-(3-Bromophenyl)Prop-2-En-1-Al; 3-Bromocinnamaldehyde Usp/ep/bp; (2E)-3-(3-Bromphenyl)Prop-2-Enal
CAS编号97985-66-5
MFCD编号:MFCD00996500
分子式:C9H7BrO分子量:211.06
产品CID: 2023836
产品分类香精与香料 → 合成香料 → 羧酸及酯类香料

相似结构搜索
InChIKey: QICJGJJHIQBWJR-DUXPYHPUSA-N
InChI=1S/C9H7BrO/c10-9-5-1-3-8(7-9)4-2-6-11/h1-7H/b4-2+
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数2.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302
防范说明P280-P305+P351+P338

上下游产品

1-bromo-3-cyclopropylbenzene m-bromobenzoic aldehyde (triphenylphosphoranylidene)acetaldehyde 3-(3-bromophenyl)propanal (4S)-4-(3-bromophenyl)-2-hydroxy-3,4,7,8-tetrahydro-2H-chromen-5(6H)-one (4S)-4-(3-bromophenyl)-2-hydroxy-7,7-dimethyl-3,4,7,8-tetrahydro-2H-chromen-5(6H)-one 4-(3-bromophenyl)-4,5-dihydro-8-methylbenzo[b][1,4]oxazepin-2(3H)-one (1S,5S,6R,7R)-7-(3-bromophenyl)-5-hydroxy-8-oxobicyclo[3.2.1]°Ctane-6-carbaldehyde

合成工艺路线路线简述

32507-45-2 = 97985-66-5
反应条件:1.1 Reagents: Oxygen Catalysts: 2,2′-Dipyridyl Disulfide Solvents: Acetone; 18 H,Rt
标题:Regioselective Disulfide-Catalyzed Photocatalytic Oxidative Cleavage Of 1-Arylbutadienes To Cinnamaldehydes
作者:Fernandes,Rodney A.; Kumar,Praveen; Bhowmik,Amit; Gorve,Dnyaneshwar A.
参考文献:Organic Letters 日期:2022 卷标:24(19) 页码:3435-3439]

32507-45-2 = 97985-66-5
反应条件:1.1 Reagents: Oxygen,Ferric Sulfate Hydrate Solvents: Acetonitrile,Water; Rt -> 45 °C; 21 H,45 °C
标题:Iron(Iii)/o2-Mediated Regioselective Oxidative Cleavage Of 1-Arylbutadienes To Cinnamaldehydes
作者:Bhowmik,Amit; Fernandes,Rodney A.
参考文献:Organic Letters 日期:2019 卷标:21(22) 页码:9203-9207]

86610-62-0 = 97985-66-5
反应条件:1.1 Reagents: Dipyridinium Dichromate Solvents: Dichloromethane; 24 H,25 °C
标题:Highly Enantioselective Synthesis Of Functionalized Glutarimide Using Oxidative N-Heterocyclic Carbene Catalysis: A Formal Synthesis Of (-)-Paroxetine
作者:Porey,Arka; Santra,Surojit; Guin,Joyram
参考文献:Journal Of Organic Chemistry 日期:2019 卷标:84(9) 页码:5313-5327]

3132-99-8 = 97985-66-5
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 25 °C; Overnight,Rt1.2 Reagents: Acetic Acid Solvents: Water; Neutralized,Rt
标题:Production Of Myxopyronin And Its Derivatives By Mutasynthesis Employing A Genetically Modified Myxopyronin Genes
参考文献:World Intellectual Property Organization]

3132-99-8 = 97985-66-5
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol,Water; Rt
标题:Synthesis Of N-Vinyl Cinnamaldehyde Nitrones Through Atropisomeric Quinoxaline-Derived N,N,O-Ligand-Promoted Chan-Lam Reaction
作者:Chen,Hao; Wei,Cui; Pang,Guang-Li; Liang,Cui; Mo,Dong-Liang; Et Al
参考文献:Organic Letters 日期:2022 卷标:24(32) 页码:6013-6017]

3132-99-8 + 1099-45-2 = 97985-66-5
反应条件:1.1 -1.2 Reagents: Diisobutylaluminum Hydride1.3 Reagents: Manganese Oxide (Mno2)
标题:Secondary Amine-Catalyzed [3 + 3] Benzannulation To Access Polysubstituted Benzenes Through Iminium Activation
作者:Jiang,Lin; Li,Hang; Zhou,Jiang-Feng; Yuan,Ming-Wei; Li,Hong-Li; Et Al
参考文献:Synthetic Communications 日期:2018 卷标:48(3) 页码:336-343]

3132-99-8 + 2136-75-6 = 97985-66-5
反应条件:1.1 Solvents: Toluene; 50 °C
标题:Synergistic Catalysis: Cis-Cyclopropanation Of Benzoxazoles
作者:Meazza,Marta; Light,Mark E.; Mazzanti,Andrea; Rios,Ramon
参考文献:Chemical Science 日期:2016 卷标:7(2) 页码:984-988]

= 97985-66-5 [标题:Reaction Conditions
标题:One-Pot,Four-Step Organocatalytic Asymmetric Synthesis Of Functionalized Nitrocyclopropanes
作者:Zaghi,Anna; Bernardi,Tatiana; Bertolasi,Valerio; Bortolini,Olga; Massi,Alessandro; Et Al
参考文献:Journal Of Organic Chemistry 日期:2015 卷标:80(18) 页码:9176-9184]

86610-62-0 = 97985-66-5
反应条件:1.1 Reagents: Manganese Oxide (Mno2) Solvents: Hexane,Ethyl Acetate; 1 - 4 H,Rt
标题:Titanium-Catalyzed Intermolecular Hydroaminoalkylation Of Conjugated Dienes
作者:Preuss,Till; Saak,Wolfgang; Doye,Sven
参考文献:Chemistry - A European Journal 日期:2013 卷标:19(12) 页码:3833-3837]

86610-62-0 = 97985-66-5
反应条件:1.1 Reagents: Dess-Martin Periodinane Solvents: Dichloromethane; Rt
标题:Emission Wavelength Prediction Of A Full-Color-Tunable Fluorescent Core Skeleton,9-Aryl-1,2-Dihydropyrrolo[3,4-B]Indolizin-3-One
作者:Kim,Eunha; Koh,Minseob; Lim,Byung Joon; Park,Seung Bum
参考文献:Journal Of The American Chemical Society 日期:2011 卷标:133(17) 页码:6642-6649]

210115-30-3 = 97985-66-5
反应条件:1.1 Reagents: P-Toluenesulfonic Acid,Oxygen Catalysts: Tert-Butyl Nitrite,Bis(Benzonitrile)Dichloropalladium Solvents: Tert-Butanol,Mesitylene; 8 H,1 Atm,25 °C1.2 Solvents: Water; 25 °C
标题:Dehydrogenative Synthesis Of Linear α,β-Unsaturated Aldehydes With Oxygen At Room Temperature Enabled By Tbuono
作者:Wang,Mei-Mei; Ning,Xiao-Shan; Qu,Jian-Ping; Kang,Yan-Biao
参考文献:Acs Catalysis 日期:2017 卷标:7(6) 页码:4000-4003]

210115-30-3 = 97985-66-5
反应条件:1.1 Reagents: Tempo Catalysts: 1,10-Phenanthroline,Iron Chloride (Fecl3) Solvents: Chlorobenzene; 12 H,120 °C
标题:Iron-Catalyzed α,β-Dehydrogenation Of Carbonyl Compounds
作者:Zhang,Xiao-Wei; Jiang,Guo-Qing; Lei,Shu-Hui; Shan,Xiang-Huan; Qu,Jian-Ping; Et Al
参考文献:Organic Letters 日期:2021 卷标:23(5) 页码:1611-1615]

3132-99-8 + 2136-75-6 = 97985-66-5
反应条件:1.1 Solvents: Toluene; Overnight,80 °C
标题:Potent Inhibition Of Nicotinamide N-Methyltransferase By Alkene-Linked Bisubstrate Mimics Bearing Electron Deficient Aromatics
作者:Gao,Yongzhi; Van Haren,Matthijs J.; Buijs,Ned; Innocenti,Paolo; Zhang,Yurui; Et Al
参考文献:Journal Of Medicinal Chemistry 日期:2021 卷标:64(17) 页码:12938-12963]

3132-99-8 = 97985-66-5
反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Copper Oxide (Cuo) (Supported On Magnesium Exchanged Zeolite-Y) Solvents: Ethanol; 10 H,100 °C
标题:Dehydrogenation Of Ethanol Over Cuo-Mg-Y For Cross-Aldol Condensation With Aryl Aldehydes
作者:Biswas,Subir; Baruah,Manash J.; Gogoi,Gautam; Hoque,Nazimul; Lee,Seonghwan; Et Al
参考文献:Microporous And Mesoporous Materials 日期:2022 卷标:336]

3132-99-8 + 2136-75-6 = 97985-66-5
反应条件:1.1 Solvents: Tetrahydrofuran; 16 H,70 °C
标题:Enantioselective Conjugate Addition Of Malonates To α,β-Unsaturated Aldehydes Catalysed By 4-Oxalocrotonate Tautomerase
作者:Yu,Ming-Zhu; Chen,Kai-Yue; Zhang,Yi-Bin; Zhang,Chang-Xuan; Xiang,Zheng
参考文献:Organic & Biomolecular Chemistry 日期:2023 卷标:21(10) 页码:2086-2090]

3132-99-8 + 62942-43-2 = 97985-66-5
反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; Rt; 92 H,Rt
标题:Visible-Light Excitation Of Iminium Ions Enables The Enantioselective Catalytic β-Alkylation Of Enals
作者:Silvi,Mattia; Verrier,Charlie; Rey,Yannick P.; Buzzetti,Luca; Melchiorre,Paolo
参考文献:Nature Chemistry 日期:2017 卷标:9(9) 页码:868-873]

3132-99-8 = 97985-66-5
反应条件:1.1 Reagents: 1,1,1,3,3,3-Hexafluoro-2-Propanol,Water Solvents: Acetonitrile; Rt
标题:Electrochemical Formation Of Cinnamaldehyde By The Electrolyte System N,N-Diisopropylethylamine And 1,1,1,3,3,3-Hexafluoropropan-2-Ol
作者:Imada,Yasushi; Okada,Yohei; Chiba,Kazuhiro
参考文献:Chemelectrochem 日期:2020 卷标:7(7) 页码:1619-1622]

3132-99-8 = 97985-66-5
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 25 °C; Overnight,25 °C1.2 Reagents: Acetic Acid; Neutralized
标题:Advanced Mutasynthesis Studies On The Natural α-Pyrone Antibiotic Myxopyronin From Myxococcus Fulvus
作者:Sahner,J. Henning; Sucipto,Hilda; Wenzel,Silke C.; Groh,Matthias; Hartmann,Rolf W.; Et Al
参考文献:Chembiochem 日期:2015 卷标:16(6) 页码:946-953]

3132-99-8 + 2136-75-6 = 97985-66-5
反应条件:1.1 Solvents: Dichloromethane; Rt
标题:Palladium-Catalyzed [5 + 2] Annulation Of Vinylethylene Carbonates With Barbiturate-Derived Alkenes
作者:Gao,Xing; Zhu,Dongyu; Chen,Yuehua; Deng,Hao; Jiang,Feng; Et Al
参考文献:Organic Letters 日期:2020 卷标:22(18) 页码:7158-7163]

141-82-2 + 3132-99-8 = 97985-66-5
反应条件:1.1 Reagents: Piperidine Solvents: Acetic Acid; Rt; 2.5 Min1.2 Reagents: Triethylamine,Ethyl Chloroformate Solvents: Tetrahydrofuran; -7 °C; 1 H,-7 °C; -7 °C -> Rt1.3 Reagents: Methanol,Sodium Borohydride; 0 °C; 12 H,25 °C1.4 Reagents: Pyridinium Chlorochromate Solvents: Dichloromethane; 12 H,25 °C
标题:De Novo Synthesis Of Functionalized 1,3-Enynes And Extended Conjugated Molecular Systems
作者:Rao,Maddali L. N.; Dasgupta,Priyabrata; Murty,Venneti N.
参考文献:Rsc Advances 日期:2015 卷标:5(32) 页码:24834-24845

📜3-溴肉桂酸置于manganese(Iv) Oxide,氯化亚砜体系中,用甲醇,正己烷,乙酸乙酯作为反应溶剂,化学反应 4.5H,反应生成 3-溴肉桂醛
参考文献:钛催化共轭二烯的分子间氢氨基烷基化
标题:钛催化共轭二烯的分子间氢氨基烷基化
摘要:钛我袋鼠向下:共轭二烯分子间经历在hydroaminoalkylation Ti催化剂的存在下[工业2时间2](茚=η 5-茚基).这项新反应为从1,3-丁二烯制得的均胺提供了高效的原子效率方法.
DOI:10.1002/chem.201203693