CAS: 961-38-6; 2,4,6-Tri-Tert-Butylaniline

该化合物是有机化合物,其结构特征为一个以三个大成的三丁基聚变体和氨基氨基化合物替代的苯环,该化合物一般在室温下是固体,以其稳定性和耐氧化性而著称,在各种应用中,特别是在聚合物和其他材料中的抗氧化剂方面,该产品十分有用;氨基聚物的存在具有基本特性,使其能够参与各种化学反应,包括核生殖替代物;其散装的乙基丁基替代物助长了不孕障碍,从而影响其在有机溶剂中的再活动性和溶解性;此外,该复合物在材料科学领域和工业工艺中作为稳定剂的潜在应用,经常受到研究;安全数据表明,由于与接触相关的潜在健康危害,应当谨慎处理该化合物,如同许多有机氨一样.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2,4,6-tri-tert-butylnitrobenzene nona-1(9),2,4-triene2,4,6-tri-tert-butyl-7,8,9-dithiazabicyclo4.3.0nona-1(9),2,4-triene triphenylphosphine 2,4,6-tri-tert-butyl-1-nitrosobenzene N-(2,4,6-tri-tert-butylphenyl)-acetamide 2,4-Di-tert-butylformanilid tert-butyl-4-nitro-aniline2,6-di-tert-butyl-4-nitro-aniline 2,6-di-tert-butyl-4-methoxyaniline

合成工艺路线路线简述

  • 4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Triethylamine,Hydrogen Catalysts: Cobalt Acetate Tetrahydrate (Complexes With Phenanthroline,N Doped Graphene) Solvents: Ethanol,Water; 55 H,20 Bar,70 °C
    标题:Fe2O3/ngr@c- And Co-Co3O4/ngr@c-Catalysed Hydrogenation Of Nitroarenes Under Mild Conditions
    作者:Formenti,Dario; Topf,Christoph; Junge,Kathrin; Ragaini,Fabio; Beller,Matthias
    参考文献:Catalysis Science & Technology 日期:2016 卷标:6(12) 页码:4473-4477]

    4074-25-3 = 961-38-6
    反应条件:1.1 Solvents: Ethanol
    标题:Steric Effects On Mesomerism. Xvii. Properties Of Aromatic Nitro,Amino,And Acylamino Compounds With Bulky Ortho Substituents
    作者:Burgers,J.; Hoefnagel,M. A.; Verkade,P. E.; Visser,H.; Wepster,B. M.
    参考文献:Recueil Des Travaux Chimiques Des Pays-Bas Et De La Belgique 日期:1958 卷标:77 页码:491-530]

    4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Triethylamine,Hydrogen Catalysts: Cobalt Oxide (Co3O4) (Carbon-Supported),Cobalt (Carbon-Supported) Solvents: Ethanol,Water; 15 H,40 Bar,110 °C
    标题:Biomass-Derived Catalysts For Selective Hydrogenation Of Nitroarenes
    作者:Sahoo,Basudev; Formenti,Dario; Topf,Christoph; Bachmann,Stephan; Scalone,Michelangelo; Et Al
    参考文献:Chemsuschem 日期:2017 卷标:10(15) 页码:3035-3039]

    4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Zinc,Hydrochloric Acid Solvents: Ethanol,Ethyl Acetate; 0.5 H,Rt; 4 H,Rt -> 70 °C1.2 Reagents: Ammonia Solvents: Water; Ph 7 - 8
    标题:Direct C-H Heteroarylation By An Acenaphthyl-Based α-Diimine Palladium Complex: Improvement Of The Reaction Efficiency For Bi(Hetero)Aryls Under Aerobic Conditions
    作者:Chen,Fu-Min; Huang,Fei-Dong; Yao,Xue-Yi; Li,Tian; Liu,Feng-Shou
    参考文献:Organic Chemistry Frontiers 日期:2017 卷标:4(12) 页码:2336-2342]

    4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 0 °C -> Rt; 15 Min,Rt; Rt -> Reflux; 20 Min,Reflux; 10 Min,Heated; 3 H,Reflux; Reflux -> 0 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 0 °C
    标题:Dichloro-Cycloazatriphosphane: The Missing Link Between N2P2 And P4 Ring Systems In The Systematic Development Of Np Chemistry
    作者:Bresien,Jonas; Hinz,Alexander; Schulz,Axel; Suhrbier,Tim; Thomas,Max; Et Al
    参考文献:Chemistry - A European Journal 日期:2017 卷标:23(59) 页码:14738-14742]

    58949-87-4 = 961-38-6
    反应条件:1.1 Catalysts: Triphenylphosphine
    标题:Chemistry Of N-(Thiosulfinyl)Anilines. V. Reactions Of N-(Thiosulfinyl)Anilines With Nucleophilic Reagents
    作者:Inagaki,Yoshio; Hosogai,Takeo; Okazaki,Renji; Inamoto,Naoki
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:1980 卷标:53(1) 页码:205-9]

    = 961-38-6 [标题:Reaction Conditions
    标题:Chemistry Of N-Thiosulfinylanilines. Ii. Thermolysis And Photolysis Of N-Thiosulfinylanilines
    作者:Inagaki,Yoshio; Okazaki,Renji; Inamoto,Naoki
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:1979 卷标:52(7) 页码:2002-7]

    = 961-38-6 [标题:Reaction Conditions
    标题:Sterically Hindered Aromatic Compounds. Vii. Deoxygenation Of 2,5-Di-Tert-Butyl- And 2,4,6-Tri-Tert-Butylnitrosobenzene
    作者:Ross,L.; Barclay,C.; Khazanie,Prabhaker G.; Adams,Kenneth A. H.; Reid,Elaine
    参考文献:Canadian Journal Of Chemistry 日期:1977 卷标:55(18) 页码:3273-9]

    4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Sodium Amalgam Solvents: Ethanol
    标题:Studies In Organosulphur-Nitrogen And Organoselenium-Nitrogen Chemistry
    作者:Setiloane,Busang Peter
    参考文献:1979]

    4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Diethylene Glycol Dibutyl Ether,Sodium Borohydride Catalysts: 2409985-26-6 Solvents: Water; 2 H,Rt
    标题:Synthesis Of Water Soluble Pd-Piperidoimidazolin-2-Ylidene Complexes And Their Catalytic Activities In Neat Water
    作者:Cakir,Sinem; Tuerkmen,Hayati
    参考文献:Applied Organometallic Chemistry 日期:2020 卷标:34(4)]

    343971-98-2 = 961-38-6 [标题:Reaction Conditions
    标题:Oxidation Of A 5H-1,2,3-Dithiazole Derivative. Formation Of A New Type Of Thiolsulfinate And Its Decomposition Involving Oxygen Migration
    作者:Inagaki,Yoshio; Okazaki,Renji; Inamoto,Naoki
    参考文献:Chemistry Letters 日期:1978 卷标:(10) 页码:1095-8]

    24973-59-9 = 961-38-6
    反应条件:1.1 Reagents: Triethylamine,Thiazolium,2-(1-Hydroxyethyl)-3,4-Dimethyl-,1,1,1-Trifluoromethanesulfonate (1... Solvents: Dichloromethane; 0.5 - 2 H,Rt1.2 Reagents: Sodium Hydroxide Solvents: Water; Rt1.3 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; -30 °C1.4 Reagents: Acetyl Chloride; -30 °C -> Rt; Rt
    标题:Reaction Of Aromatic Nitroso Compounds With Chemical Models Of Thiamine Active Aldehyde
    作者:Ferreira,Luisa M.; Marques,M. Manuel B.; Gloria,Paulo M. C.; Chaves,Humberto T.; Franco,Joao-Pedro P.; Et Al
    参考文献:Tetrahedron 日期:2008 卷标:64(33) 页码:7759-7770]

    4074-25-3 = 961-38-6 [标题:Reaction Conditions
    标题:Reaction Of 2,4,6-Tri-Tert-Butylnitrobenzene With Alkyl Grignard Reagents
    作者:Inagaki,Yoshio; Okazaki,Renji; Inamoto,Naoki
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:1975 卷标:48(12) 页码:3727-32]

    4074-25-3 = 961-38-6
    反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Toluene; 1 H,80 °C
    标题:Efficient Adjustment Of Product Selectivity Using Controllable Pd Nanoparticles In Nitroarene Hydrogenation
    作者:Zhang,Jian; Wang,Liang; Chen,Fang; Xiao,Feng-Shou
    参考文献:Particuology 日期:2020 卷标:48 页码:13-18]

    7377-26-6 + 116233-17-1 = 961-38-6
    反应条件:1.1 Solvents: Benzene,Pyridine
    标题:Retinobenzoic Acids. 1. Structure-Activity Relationships Of Aromatic Amides With Retinoidal Activity
    作者:Kagechika,Hiroyuki; Kawachi,Emiko; Hashimoto,Yuichi; Shudo,Koichi; Himi,Toshiyuki
    参考文献:Journal Of Medicinal Chemistry 日期:1988 卷标:31(11) 页码:2182-92]

    = 961-38-6 [标题:Reaction Conditions
    标题:Novel Heterocumulenes: Bisiminopropadienes And Linear Ketenimines
    作者:Wolf,Reinhard; Stadtmueller,Stefan; Wong,Ming Wah; Barbieux-Flammang,Monique; Flammang,Robert; Et Al
    参考文献:Chemistry - A European Journal 日期:1996 卷标:2(10) 页码:1318-1329]

    = 961-38-6 [标题:Reaction Conditions
    标题:Picosecond Laser Photolysis Studies Of Hydrogen-Atom Transfer Reaction Via Heteroexcimer State In Pyrene-Primary And Pyrene-Secondary Aromatic Amine Systems: Role Of Hydrogen-Bonding Interaction Between Amino Group Of Donor And π Electrons Of Acceptor In The Heteroexcimer
    作者:Okada,Tadashi; Karaki,Ichiro; Mataga,Noboru
    参考文献:Journal Of The American Chemical Society 日期:1982 卷标:104(25) 页码:7191-5]

    = 961-38-6 [标题:Reaction Conditions
    标题:Chemistry Of N-Thiosulfinylanilines. Iv. Reactions Of N-Thiosulfinylanilines With Electrophilic Reagents
    作者:Inagaki,Yoshio; Okazaki,Renji; Inamoto,Naoki
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:1979 卷标:52(12) 页码:3615-18]

    = 961-38-6 [标题:Reaction Conditions
    标题:Reactions Of 2,4,6-Tri-Tert-Butylnitrosobenzene With Grignard Reagents
    作者:Inagaki,Yoshio; Okazaki,Renji; Inamoto,Naoki
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:1975 卷标:48(2) 页码:621-5]

    = 961-38-6 [标题:Reaction Conditions
    标题:Photochemistry Of Aromatic Nitro Compounds. Ix. Products From Photolysis Of 1,3,5-Tri-Tert-Butyl-2-Nitrobenzene
    作者:Doepp,Dietrich; Sailer,Karl H.
    参考文献:Chemische Berichte 日期:1975 卷标:108(1) 页码:301-13
📜叔丁基苯置于sodium Amalgam,三氯化铝,硝酸体系中,用 甲醇,乙酸酐,溶剂黄146 作为反应溶剂,化学反应 74.0H,反应生成 2,4,6-三叔丁基苯胺
参考文献:Picosecond Laser Photolysis Studies Of Hydrogen-Atom Transfer Reaction Via Heteroexcimer State In Pyrene-Primary And Pyrene-Secondary Aromatic Amine Systems: Role Of Hydrogen-Bonding Interaction Between Amino Group Of Donor And π Electrons Of Acceptor In The Heteroexcimer
标题:Picosecond Laser Photolysis Studies Of Hydrogen-Atom Transfer Reaction Via Heteroexcimer State In Pyrene-Primary And Pyrene-Secondary Aromatic Amine Systems: Role Of Hydrogen-Bonding Interaction Between Amino Group Of Donor And π Electrons Of Acceptor In The Heteroexcimer
摘要:
DOI:10.1021/ja00389A049

海关参考信息

专利信息


专利号:WO-2009143405-A2
优先权日:2008-05-22
标 题:Synthesis of graphene sheets and nanoparticle composites comprising same

专利号:US-2011186789-A1
优先权日:2008-05-22
标题:Synthesis of graphene sheets and nanoparticle composites comprising same
发明人：SAMULSKI EDWARD T; SI YONGCHAO; DINGEMANS THEO
权利人:UNIV NORTH CAROLINA
摘要:A method for producing isolatable and dispersible graphene sheets, wherein the graphene sheets may be tailored to be soluble in aqueous, non-aqueous or semi-aqueous solutions. The water soluble graphene sheets may be used to produce a metal nanoparticle-graphene composite having a specific surface area that is 20 times greater than aggregated graphene sheets. Graphene sheets that are soluble in organic solvents may be used to make graphene-polymer composites.

专利号:CN-112778125-A
优先权日:2021-02-01
标题:A kind of aryl phenolic compound and its synthesis method and application

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主要参考文献

[参考文献]: Michael D. Mikoluk, Et Al. Chemistry Of Diazaphospholephosphines. 2. Exocyclic Phosphine-Sulfido, -Selenido, And -Imido Derivatives Of A Diazaphospholephosphine System. Crystal And Molecular Structures Of Two Diazaphospholephosphine Imines: 4-(Difluoro((P-Cyanotetrafluorophenyl)Imino)Phosphorano)-2,5-Dimethyl-2H-1,2,3Sigma(2)-Diazaphosphole And 4-(Bis(Dimethylamino)(((Pentamethylcyclopentadienyl)Dichlorotitanio)Imino)Phosphorano)-2,5-Dimethyl-2H-1,2,3Sigma(2)-Diazaphosphole. Inorg Chem. 1999 Jun 14;38(12):2791-2801.

合成参考文献


摘要:S120 | DUSTCT2024 | Substances from Second NORMAN Collaborative Dust Trial | DOI:10.5281/zenodo.13835254
摘要:Argyropoulos, N. G., Science of Synthesis, (2004) 13, 23.
摘要:Aitken, R. A., Science of Synthesis, (2004) 13, 780.
摘要:Braverman, S.; Cherkinsky, M.; Birsa, M. L., Science of Synthesis, (2005) 18, 226.
摘要:Perst, H., Science of Synthesis, (2006) 23, 828.
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