专利号:US-7538061-B2 优先权日:2001-05-18 标题 :One-step production of 1,3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst 发明人:KNIFTON JOHN FREDERICK; JAMES TALMADGE GAIL; SLAUGH LYNN HENRY; WEIDER PAUL RICHARD; ALLEN KEVIN DALE; POWELL JOSEPH BROUN 权利人:SHELL OIL CO 摘要:Disclosed is a new catalyst composition comprising a bimetallic Co—Fe catalyst, optionally complexed with a ligand selected from a N-heterocycle, phosphine, or porphorine ligand, that provides a lower cost alternative for the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, a catalyst containing cobalt carbonyl: iron carbonyl with no ligand, or a catalyst containing a cobalt carbonyl: octaethylporphine iron acetate provide moderate yields of 1,3-PDO in a one step synthesis under mild conditions.
专利号:US-6903044-B2 优先权日:2001-05-18 标题:One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand 发明人:KNIFTON JOHN FREDERICK; JAMES TALMADGE GAIL; ALLEN KEVIN DALE; WEIDER PAUL RICHARD; POWELL JOSEPH BROUN; SLAUGH LYNN HENRY; WILLIAMS TIMOTHY 权利人:SHELL OIL CO 摘要:Disclosed is a new catalyst composition comprising a bimetallic Co—Ru catalyst complexed with a N-heterocylcic ligand that is effective, economical, and provides improvements in oxidative stability in the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, cobalt-ruthenium-2,2′-bipyrimidine, 2,2′-dipyridyl, or 2,4,6-tripridyl-s-triazine catalyst precursors in cyclic ether solvents, such as 1,3-dioxolane, 1,4-dioxolane, 1,4-dioxane, and 2-ethyl-2-methyl-1,3-dioxolane, provide good yields of 1,3-PDO in a one step synthesis.
专利号:US-8709129-B2 优先权日:2009-07-21 标题 :Compounds useful as ligands of actinides, their synthesis and their uses 发明人:MARIE CÉCILE; MIGUIRDITCHIAN MANUEL; BISSON JULIA; GUILLANEUX DENIS; DUBREUIL DIDIER 权利人:MARIE CÉCILE; MIGUIRDITCHIAN MANUEL; BISSON JULIA; GUILLANEUX DENIS; DUBREUIL DIDIER; COMMISSARIAT ENERGIE ATOMIQUE 摘要:The invention relates to novel compounds which are useful as ligands of actinides, to the synthesis of these compounds and to their uses. n These compounds fit the general formula (I) hereafter: n nwherein R 1 and R 2 , either identical or different, represent H, a linear or branched, saturated or unsaturated C 1 -C 12 hydrocarbon group, a phenyl, benzyl, diphenyl or tolyl group; R 3 represents H, a linear or branched, saturated or unsaturated C 1 -C 12 hydrocarbon group, a phenyl, tolyl or linear or branched C 1 -C 12 alkoxy group; while R 4 represents H, a linear or branched, saturated or unsaturated C 1 -C 12 hydrocarbon group, a phenyl or tolyl group.n n Field of applications: the processing of used nuclear fuels via a hydrometallurgical route.
专利号:WO-2022200731-A1 优先权日:2021-03-26 标 题 :Ecologic method for preparing silver nanoparticles from an extract of hubertia ambaviilla and uses thereof 发明人:BEN HADDADA MAROUA; MOREL ANNE-LAURE 权利人:TORSKAL 摘要:The invention relates to the field of metal nanoparticles prepared from plant extract. More particularly, the invention relates to an ecological method for the synthesis of biocompatible and stable silver nanoparticles from an extract of Hubertia ambavilla. The invention also relates to the silver nanoparticle obtained and to the uses thereof as an antioxidant, antimicrobial agent and anticancer agent.
专利号:US-7115540-B2 优先权日:2002-02-13 标题 :Synthesis of aliphatic 1,3-diols utilizing reduced ligand concentration and water extraction 发明人:POWELL JOSEPH BROUN; WEIDER PAUL RICHARD; KNIFTON JOHN FREDERICK; ALLEN KEVIN DALE; SLAUGH LYNN HENRY; ARHANCET JUAN PEDRO 权利人:SHELL OIL CO 摘要:This invention is a process for synthesizing aliphatic 1,3-diols in one step by hydroformylation and hydrogenation of oxirane, carbon monoxide, and hydrogen employing a catalyst comprising a cobalt carbonyl compound and a cocatalyst metal compound ligated with a ligand in a ligand to cocatalyst metal atom molar ratio in the range of 0.2:1.0 to 0.6:1.0, optionally in the presence of a promoter, where recovery of product is preferably accomplished via water extraction of a diol rich phase from the bulk reaction mixture. The process modifications can, particularly in combination, be beneficial with respect to product recovery, catalyst recycle, and overall economics of a one-step process for producing aliphatic 1,3-diols.
专利号:US-4469895-A 优先权日:1982-10-21 标题 :Process for preparing alcohols from olefins and synthesis gas 发明人:KNIFTON JOHN F; GRIGSBY JR ROBERT A 权利人:TEXACO INC 摘要:This invention concerns an improved process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound in conjunction with one or more tertiary amine promoters, dispersed in a low melting quaternary phosphonium salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.
1. Collins, P.F., and Diehl, H. 2,4,6-Tripyridyl-s-triazine as a reagent for iron. Determination of iron in limestone, silicates, and refractories. Anal. Chem. 31(11), 1862-1867 (1959). 2. Dehghani, Z., Dadfarnia, S., Shabani, A.M.H., et al. Determination of iron species by combination of solvent assisted-dispersive solid phase extraction and spectrophotometry. Anal. Bioanal. Chem. Res. 2(1), 13-21 (2015).
合成参考文献
参考文献:10.3389/fmicb.2011.00037 摘要:Veith A, Urich T, Seyfarth K, Protze J, Frazão C, Kletzin A. Substrate pathways and mechanisms of inhibition in the sulfur oxygenase reductase of acidianus ambivalens. Front Microbiol. 2011;2():37. 参考文献:10.1107/s1600536811006842 摘要:Jin CH. Aqua-glutarato(2,4,6-tri-2-pyridyl-1,3,5-triazine)nickel(II) trihydrate. Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 01;67(Pt 4):m393. 参考文献:10.1107/s1600536811012517 摘要:Cao M, Shi L. [2-Amino-4,6-bis(2-pyridyl)-1,3,5-triazine-κ3N4,N5,N6]dichloridocadmium(II). Acta Crystallogr E Struct Rep Online. 2011 Apr 29;67(5):m638. doi: 10.1107/s1600536811012517. 参考文献:10.1107/s1600536811014589 摘要:Zhou J, Lu GX, Zhang YG, Wei DY. Aqua-trinitrato[2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate. Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 01;67(Pt 6):m699. 参考文献:10.1007/s11130-011-0246-0 摘要:Korekar G, Stobdan T, Arora R, Yadav A, Singh SB. Antioxidant capacity and phenolics content of apricot (Prunus armeniaca L.) kernel as a function of genotype. Plant Foods Hum Nutr. 2011 Nov;66(4):376–83. doi: 10.1007/s11130-011-0246-0.