CAS: 367-28-2; 2-Fluorocyclohexa-2,5-Diene-1,4-Dione

相似化合物

527-21-9 3958-82-5 1633-14-3

📜氟苯置于10-Molybdo-2-Vanadophosphoric Acid,硫酸,氧气体系中,用 水 作为反应溶剂,170.0 °C,1.0 Mpa 条件下,反应 6.0H,反应生成 5-氯-2-硝基甲苯
参考文献:苯的电子转移氧化和好氧氧化制苯酚
标题:苯的电子转移氧化和好氧氧化制苯酚
摘要:非常强的c-h键(例如在苯中发现的键)的活化对于寻找使其功能化的新途径也很重要.使用h 5 Pv 2 Mo 10 O 40多金属氧酸盐作为电子转移氧化剂,在> 50%的h 2 So 4水溶液中作作为反应溶剂,通过可见光谱和epr光谱(在x-验证了包括eldor检测的NMR在内的w波段和w波段.通过dft计算可以证明苯的et氧化的可行性,表明在这些条件下该反应是剧烈的.此外,我们证明了在存在o 2的情况下,发生非常选择性地羟基化为苯酚.
DOI:10.1021/acscatal.6B02083

专利信息

专利号:US-6051383-A
优先权日:1995-06-26
标题:Sequences for production of 2,4-diacetylphloroglucinol and methods
发明人：THOMASHOW LINDA S; BANGERA MAHALAXMI; WELLER DAVID M; COOK R JAMES
权利人:US AGRICULTURE; UNIV WASHINGTON
摘要:DNA sequences which function specifically in the synthesis of 2,4-diacetylphloroglucinol (Phl) are described. The sequences include phl genes which encode phl gene proteins and coding and regulatory sequences for production of Phl as well as sequences containing phl genes, which sequences have the capability of conferring or enhancing Phl biosynthetic capability in bacterial strains. The transformed strains are useful as biocontrol agents against fungal pathogens.

专利号:CN-113045503-B
优先权日:2020-07-31
标题:Preparation method of 2-trifluoromethyl substituted quinazolinone compound and application of compound in synthesis of drug molecules

专利号:WO-2010058421-A2
优先权日:2008-11-18
标题:A process for synthesis of 2, 4-dichloro-5- fluoroacetophenone (dcfa)

专利号:CN-104725325-A
优先权日:2015-04-10
标题 :A kind of 2-(1-phenylethyl) quinazolinone and its catalytic synthesis method

专利号:US-8951771-B2
优先权日:2007-06-28
标题 :Modified 13-hydroperoxide lyases and uses thereof
发明人：BRUHLMANN FREDI; FOURAGE LAURENT; WAHLER DENIS
权利人:FIRMENICH & CIE
摘要:Fatty acid 13-hydroperoxide lyase proteins which have been modified with respect to a previously described guava 13-hydroperoxide lyase and the nucleic acid sequences encoding these proteins. Also, recombinant nucleic acid molecules for expressing the modified 13-hydroperoxide lyases and methods of using such lyases in the field of organic synthesis.

专利号:WO-9411382-A1
优先权日:1992-11-09
标题 :Antineoplastic heteronaphthoquinones
发明人：ATTARDO GIORGIO; BREINING TIBOR; COURCHESNE MARC; KRAUS JEAN-LOUIS; LAMOTHE SERGE; LAVALLEE JEAN-FRANCOIS; LEBEAU ELAINE; NGUYEN DIEU; REJ RABINDRA; ST-DENIS YVES; WANG WUYI; XU YAO-CHANG; BARBEAU FRANCE
权利人:IAF BIOCHEM INT; ATTARDO GIORGIO; BREINING TIBOR; COURCHESNE MARC; KRAUS JEAN LOUIS; LAMOTHE SERGE; LAVALLEE JEAN FRANCOIS; LEBEAU ELAINE; NGUYEN DIEU; REJ RABINDRA; ST DENIS YVES; WANG WUYI; XU YAO CHANG; BARBEAU FRANCE
摘要:Tricyclic heteronaphthoquinone derivatives, that have antineoplastic activity, are disclosed, together with processes for their synthesis. Some of these anti-neoplastics compounds have a saccharide moiety. Some members of this structurally distinct group exhibit activity against multiple drug resistant cancer cells.