CAS: 24464-63-9; Decylboronic Acid

相似化合物

28741-08-4 28741-07-3 3088-79-7

上下游产品

tridecylborane boric acid tributyl ester (n-decyl)dibromoborane 1-Decene4'-decyl-2'-hydroxyacetophenone 1-Decanol undecanenitrile

2-N-Decyl-1,3,2-Dithiaborolan置于h2O体系中,用 四氢呋喃,水 用作溶剂,化学反应生成正癸基硼酸
参考文献:Hydroboration Of Alkenes And Alkynes By 1,3,2-Dithiaborolane
标题:Hydroboration Of Alkenes And Alkynes By 1,3,2-Dithiaborolane
摘要:
Doi:10.1021/jo00440A009

专利信息

专利号:US-9243004-B2
优先权日:2011-07-22
标题 :Synthesis of boronic esters and boronic acids using grignard reagents
发明人：CLARY JACOB W; SINGARAM BAKTHAN
权利人:CLARY JACOB W; SINGARAM BAKTHAN; UNIV CALIFORNIA
摘要:Boronic esters and boronic acids are synthesized at ambient temperature in an ethereal solvent by the reaction of Grignard reagents with a boron-containing substrate. The boron-containing substrate may be a boronic ester such as pinacolborane, neopentylglycolborane, or a dialkylaminoborane compound such as diisopropylaminoborane. The Grignard reagents may be pre-formed or generated from an alkyl, alkenyl, aryl, arylalkyl, heteroaryl, vinyl, or allyl halide compound and Mg 0 . When the boron-containing substrate is a boronic ester, the reactions generally proceed at room temperature without added base in about 1 to 3 hours to form a boronic ester compound. When the boron-containing substrate is a dialkylaminoborane compound, the reactions generally proceed to completion at 0° C. in about 1 hour to form a boronic acid compound.

专利号:US-8207337-B2
优先权日:2007-01-29
标 题:Reagent for organic synthesis reaction containing organic triol borate salt
发明人：MIYAURA NORIO; YAMAMOTO YASUNORI
权利人:MIYAURA NORIO; YAMAMOTO YASUNORI; WAKO PURE CHEM IND LTD
摘要:[Problem] n To provide an organoboron compound-containing reagent for organic synthesis reactions which undergoes no trimerization with dehydration, does not necessitate activation with a base, and is stable and highly active. n [Means for Solving Problems] n The reagent for organic synthesis reactions contains an organic triol borate salt represented by any of the general formulae (I) to (III) and general formula (XVI): (wherein R 1 represents alkyl, alkenyl, etc.; R 2 represents optionally substituted alkyl, alkenyl, alkynyl, etc. or represents hydrogen; m + represents an alkaline metal ion, phosphonium ion, or given ammonium ion; M 2+ represents an alkaline earth metal; X represents halogen or alkoxide; Y represents an alkali metal ion, etc.; A represents optionally substituted methylene; and n represents an integer).

专利号:US-2015119580-A1
优先权日:2011-07-22
标 题 :Synthesis of boronic esters and boronic acids using grignard reagents

专利号:WO-2013016185-A1
优先权日:2011-07-22
标 题 :Synthesis of boronic esters and boronic acids using grignard reagents