CAS: 1438-82-0; 1,1,1,3,3-Pentamethyldisiloxane

上下游产品

CAS号3277-26-7 1,1,3,3-四甲基二硅氧烷 | CAS号107-46-0 六甲基二硅氧烷 | CAS号812-15-7 五甲基二硅烷 | CAS号18156-38-2 Disiloxane, met... | CAS号2943-62-6 Chloropentameth... | CAS号75-77-4 三甲基氯硅烷 | CAS号1066-35-9 二甲基一氯硅烷 | CAS号2441-21-6 iododimethylsilane | CAS号1825-62-3 三甲基乙氧基硅烷 | CAS号1066-40-6 三甲基硅醇 | CAS号1438-79-5 乙烯基五甲基二硅氧烷 | CAS号18044-44-5 (3-GLYCIDOXYPRO... | CAS号18151-85-4 甲基丙烯酰氧丙基五甲基二硅氧烷 | CAS号18537-50-3 2-[dimethyl(tri... | CAS号23029-21-2 3-氨基丙基五甲基二硅氧烷 | CAS号107-46-0 六甲基二硅氧烷 | CAS号1873-88-7 双三甲基硅氧基甲基硅烷 | CAS号107-51-7 八甲基三硅氧烷 | CAS号141-62-8 十甲基四硅氧烷 | CAS号2895-07-0 1,1,1,3,3,5,5-七...

氯五甲基二硅氧烷置于lithium Aluminium Tetrahydride体系中,用 乙醚 用作溶剂,化学反应 1.0H,以80%的收率获得五甲基二硅氧烷
参考文献:Sonnek,Georg; Engelbrecht,Lothar,Zeitschrift Fur Chemie,1987,Vol. 27,# 11,P. 411-412
标题:Sonnek,Georg; Engelbrecht,Lothar,Zeitschrift Fur Chemie,1987,Vol. 27,# 11,P. 411-412

专利信息

专利号:US-9421532-B2
优先权日:2013-03-01
标 题:Mononuclear iron complex and organic synthesis reaction using same
发明人：NAGASHIMA HIDEO; SUNADA YUSUKE; TSUTSUMI HIRONORI; HASHIMOTO TORU; SAKUTA KOJI
权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO
摘要:Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. n n n n n n n n n n In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.

专利号:US-10363551-B2
优先权日:2015-03-09
标 题:Mononuclear iron complex and organic synthesis reaction using same
发明人：NAGASHIMA HIDEO; SUNADA YUSUKE; SAWANO Mina; NODA DAISUKE; SAKUTA KOJI
权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO
摘要:A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound. n n n n n n n n n n (In the formula, R 1 to R 6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L 1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L 1 's are present, two L 1 's may be bonded to each other; L 2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L 1 , wherein, when multiple L 2 's are present, two L 2 's may be bonded to each other; and m 1 represents an integer of 1 to 4 and m 2 represents an integer of 0 to 3, wherein the sum total of m 1 and m 2 (i.e., m 1 +m 2 ) satisfies 3 or 4.)

专利号:EP-2076521-B1
优先权日:2006-08-16
标题:Synthesis of silylsubstituted 1,2-alkynes
发明人：MARCINIEC BOGDAN; DUDZIEC BEATA; SZUBERT KAROL; WALKOWIAK JEDRZEJ
权利人:UNIV ADAM MICKIEWICZ

专利号:EP-2076521-A1
优先权日:2006-08-16
标 题:New silylsubstituted 1,2-alkynes and synthesis of silylsubstituted 1,2-aikynes

专利号:CN-113444119-B
优先权日:2020-03-27
标 题:Synthesis of carbonate-modified siloxane additives

专利号:WO-2008020774-A1
优先权日:2006-08-16
标 题:New silylsubstituted 1,2-alkynes and synthesis of silylsubstituted 1,2-aikynes