CAS: 1306-38-3; Nano Cerium Oxide

该化合物是一种高纯度,无水化合物,特别在紫外线和可见光区域表现出特殊的光学特性,其主要优点包括高折射指数,透明度和化学惰性,使之适合用于陶瓷颜料,抛光剂等应用以及催化剂支持.

结构式图片

相似化合物

1306-38-3 1306-38-3 1306-38-3

物理性质

欧盟法规

REACH注册C&L通报CoRAP评估清单REACH预注册

合成工艺路线路线简述

    氢氧化铈 以96%的收率获得
    参考文献:Trofimov,G. V.;Masloboev,V. A.;Uklejn,G. I.,Fiz.-Xim. I Texnol. Probl. Pererab. Mineral. Syrya Kol. P-Ba,Apatity,(19+
    标题:Trofimov,G. V.;Masloboev,V. A.;Uklejn,G. I.,Fiz.-Xim. I Texnol. Probl. Pererab. Mineral. Syrya Kol. P-Ba,Apatity,(19+

    专利信息


    专利号:US-9289755-B2
    优先权日:2012-12-07
    标题 :Synthesis of ZSM-5 crystals with improved morphology
    发明人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S
    权利人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S; EXXONMOBIL RES & ENG CO
    摘要:Methods are provided for synthesizing crystals having a ZSM-5 framework structure from synthesis mixtures suitable for synthesis of ZSM-12 framework structure crystals in the absence of seed crystals with a ZSM-5 framework structure, such as in the absence of any seed crystals. For synthesis mixtures with a sufficiently high XO 2 :Y 2 O 3 ratio, seeding a synthesis mixture with ZSM-5 seed crystals can result in production of pure phase ZSM-5 crystals with a new morphology. The morphology can include rod-like primary crystallites with a length of about 0.5 μm or less that are organized/aggregated into larger secondary crystal structures. The aggregation of the primary crystallites into a secondary crystal structure can allow for an unexpectedly large mesoporous surface area for the ZSM-5 crystals.

    专利号:US-9266915-B2
    优先权日:2012-09-24
    标题 :Synthesis of open metal carbonyl clusters
    发明人:KATZ ALEXANDER S; KUPERMAN ALEXANDER; OKRUT ALEXANDER; RUNNEBAUM RON C; OUYANG XIAOYING
    权利人:CHEVRON USA INC; UNIV CALIFORNIA
    摘要:The present invention is directed to the synthesis of novel stable open metal clusters by selective oxidation of bound ligands. The synthesis comprises, for example, using an amine based oxidant for decarbonylation of specific carbonyl ligands. The synthesis can also comprise further removal of a bound amine group by an acid. The resulting metal cluster contains a coordinatively unsaturated site comprising a carbonyl vacancy. The resulting metal cluster can be used as a catalyst in a variety of chemical transformations.

    专利号:US-8084569-B2
    优先权日:2006-12-21
    标 题 :Process for the synthesis of diaminopyridines from glutarimidines
    发明人:MINTER AARON; STOKES BERLIN
    权利人:MINTER AARON; STOKES BERLIN; DU PONT
    摘要:A liquid-phase process is provided for the synthesis from glutarimidines of diaminopyridines and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.

    专利号:US-11718536-B2
    优先权日:2020-07-29
    标题 :Solvent-free synthesis of lanthanide oxide and mixed lanthanide oxide nanoparticles
    发明人:Treadwell LaRico Juan; BREGMAN AVI GABRIEL; RINGGOLD MARISSA
    权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC
    摘要:Lanthanide oxides and mixed lanthanide oxides can be produced using furnace or microwave assisted solid-state synthesis. The use of Ln-tri(methylsilyl)amide-based precursors yields spherical nanoparticles. The formation of spherical shaped nanoparticles is likely due to the preferential single-step decomposition of the Ln-TMS as well as the low activation energy to overcome decomposition. Reaction temperature, initial metal ion ratio, and reaction dwell time can be used to control the final nanoparticle size. The method enables solvent-free, high-yield synthesis of morphology-controlled lanthanide oxides.

    专利号:US-11059849-B2
    优先权日:2014-09-02
    标题 :Modified nucleotides for synthesis of nucleic acids, a kit containing such nucleotides and their use for the production of synthetic nucleic acid sequences or genes
    发明人:YBERT THOMAS; GARIEL SYLVAIN
    权利人:DNA SCRIPT
    摘要:A modified nucleotide, intended for the synthesis of long chain nucleic acids by enzymatic processes, comprising a “naturalâ€? nitrogenous base or a natural nitrogenous base analogue, a ribose or deoxyribose carbohydrate, and at least one phosphate group, characterized in that said nucleotide comprises at least one R group, termed the modifier group, carried by said nitrogenous base or analogue and/or by the oxygen in position 3′ of the ribose or deoxyribose molecule, making it possible to block the polymerization of said nucleotide and/or to allow the interaction of said nucleotide with another molecule, such as a protein, during the nucleic acid synthesis, R comprising at least one functional terminal group.

    专利号:US-2025023061-A1
    优先权日:2021-11-17
    标题 :Method for the synthesis of a metal catalyst surrounded with a carbon matrix
    发明人:CHATENET MARIAN; DOAN HUONG; SGARBI RICARDO
    权利人:INST POLYTECHNIQUE GRENOBLE; UNIV GRENOBLE ALPES; CENTRE NAT RECH SCIENT; UNIV SAVOIE MONT BLANC
    摘要:A method for a synthesis of a metal catalyst, including providing at least one metal complex including a metal ion and a non-chelating complexing agent having carbon, the complex having a decomposition temperature, and performing a pyrolysis of the complex at a temperature greater than or equal to a decomposition temperature of the complex, whereby inducing a formation of nanoparticles surrounded by a carbon matrix to form the catalyst. Thanks to the carbon matrix, the catalysts provided herein can be corrosion resistant, self-healing, more cost-effective, and can have higher catalytic activity. The synthesis of the catalyst and its properties can furthermore be improved compared to catalysts formed from a complex including a chelating.
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    主要参考文献

    [参考文献]: A Hosseini, Et Al. Antiapoptotic Effects Of Cerium Oxide And Yttrium Oxide Nanoparticles In Isolated Rat Pancreatic Islets. Hum Exp Toxicol. 2013 May;32(5):544-53.
    [参考文献]: Ajoy Kumar Pandey, Et Al. In Vitro Evaluation Of Osteoconductivity And Cellular Response Of Zirconia And Alumina Based Ceramics. Mater Sci Eng C Mater Biol Appl. 2013 Oct;33(7):3923-30.
    [参考文献]: Boxiong Shen, Et Al. A Comparative Study Of Mn/ceo2, Mn/zro2 And Mn/ce-Zro2 For Low Temperature Selective Catalytic Reduction Of No With Nh3 In The Presence Of So2 And H2O. J Environ Sci (China). 2013 Apr 1;25(4):791-800.
    [参考文献]: Ki Hyuk Kang, Et Al. Direct Synthesis Of Dimethyl Carbonate From Methanol And Carbon Dioxide Over Ceo2(X)-Zno(1-X) Nano-Catalysts. J Nanosci Nanotechnol. 2013 Dec;13(12):8116-20.
    [参考文献]: Michele Shepard, Et Al. Cutaneous Exposure Scenarios For Engineered Nanoparticles Used In Semiconductor Fabrication: A Preliminary Investigation Of Workplace Surface Contamination. Int J Occup Environ Health. 2014 Jul-Sep;20(3):247-57.

    合成参考文献


    参考文献:10.1007/s10661-011-2196-2
    摘要:Arisci S, Rogora M, Marchetto A, Dichiaro F. The role of forest type in the variability of DOC in atmospheric deposition at forest plots in Italy. Environmental Monitoring and Assessment. 2011 Jul 15;184(6):3415–25. doi: 10.1007/s10661-011-2196-2.
    参考文献:10.1021/es2007808
    摘要:Li H, Wu C, Li Y, Zhang J. CeO2–TiO2 Catalysts for Catalytic Oxidation of Elemental Mercury in Low-Rank Coal Combustion Flue Gas. Environ. Sci. Technol. 2011 Aug 02;45(17):7394–400. doi: 10.1021/es2007808.
    参考文献:10.3109/17435390.2011.600838
    摘要:Leppänen M, Lyyränen J, Järvelä M, Auvinen A, Jokiniemi J, Pimenoff J, Tuomi T. Exposure to CeO(2) nanoparticles during flame spray process. Nanotoxicology. 2012 Sep;6(6):643–51. doi: 10.3109/17435390.2011.600838.
    参考文献:10.1166/jnn.2011.3608
    摘要:Kepenekçi O, Emirdag-Eanes M, Demir MM. Effect of alkali metal hydroxides on the morphological development and optical properties of ceria nanocubes under hydrothermal conditions. J Nanosci Nanotechnol. 2011 Apr;11(4):3565–77. doi: 10.1166/jnn.2011.3608.
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