CAS: 10323-39-4; 4-Bromo-2-Tert-Butylphenol

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CAS号106-41-2 对溴苯酚 | CAS号115-11-7 2-甲基丙烯 | CAS号88-18-6 邻叔丁基苯酚 | CAS号591-20-8 3-溴苯酚 | CAS号75-65-0 叔丁醇 | CAS号88-18-6 邻叔丁基苯酚 | CAS号153759-58-1 2-羟基-3-叔丁基-5-溴苯甲醛 | CAS号14804-34-3 LABOTEST-BB LT0... | CAS号1188335-77-4 2-(tert-butyl)-... | CAS号66737-88-0 3-叔丁基-4-羟基苯甲酸 | CAS号39778-63-7 3-叔丁基-4-羟基苯甲酸甲酯

📜2-叔丁基苯酚置于ammonium Metavanadate,Aluminum Tri-Bromide,氧气体系中,用 乙醚 用作溶剂,化学反应 8.0H,以99%的收率获得4-溴-2-叔丁基苯酚
参考文献:布朗斯台德酸或路易斯酸促进的钒催化氧化溴化反应
标题:布朗斯台德酸或路易斯酸促进的钒催化氧化溴化反应
摘要:芳烃的氧化溴化反应是在分子氧下,在溴化物盐和布朗斯台德酸或路易斯酸存在下,由钒催化剂诱导的,与传统的溴化溴化方法相比,该方法提供了一种环保的溴化方法.这种催化反应可以适用于烯烃和炔烃的溴化,得到相应的vic-溴化物.已证明使用卤化铝代替布朗斯台德酸作为路易斯酸可为氧化溴化提供更实用的方法.从酮中获得α-溴化产物.发现albr 3既是溴化物源又是路易斯酸,可以顺利地诱导溴化.511 H NMR实验表明,这种催化溴化反应可能取决于分子氧下钒催化剂的氧化还原循环.
Doi:10.1016/j.Tet.2010.06.042

专利信息

专利号:US-10647688-B2
优先权日:2014-12-19
标题:Compounds, synthesis method thereof and use of same in medicine and in cosmetics
发明人：PORTAL THIBAUD
权利人:GALDERMA RES & DEV
摘要:Novel compounds, synthesis methods and use of the same in medicine and in cosmetics are disclosed. Also disclosed, are novel compounds and ligands that modulate RARs.

专利号:JP-2020196765-A
优先权日:2014-12-19
标 题 :New compounds, methods of their synthesis, and their use in pharmaceuticals and cosmetics

专利号:CA-2971020-A1
优先权日:2014-12-19
标题:Novel compounds, synthesis method thereof and use of same in medicine and in cosmetics

专利号:US-9856241-B2
优先权日:2013-07-03
标 题:Substituted benzofuranyl and benzoxazolyl compounds and uses thereof
发明人：BALOGLU ERKAN; SHACHAM SHARON; SENAPEDIS WILLIAM; MCCAULEY DILARA; LANDESMAN YOSEF; GOLAN GALI; KALID ORI; SHECHTER SHARON
权利人:KARYOPHARM THERAPEUTICS INC
摘要:The invention generally relates to substituted benzofuranyl and substituted benzoxazolyl compounds, and more particularly to a compound represented by Structural Formula (A): or a pharmaceutically acceptable salt thereof, wherein the variables are as defined and described herein. The invention also includes the synthesis and use of a compound of Structural Formula (A), or a pharmaceutically acceptable salt or composition thereof, e.g., in the treatment of cancer (e.g., mantle cell lymphoma), and other diseases and disorders.

专利号:JP-6797800-B2
优先权日:2014-12-19
标题 :New compounds, methods of their synthesis, and their use in pharmaceuticals and cosmetics

专利号:EP-3233806-A1
优先权日:2014-12-19
标 题:Novel compounds, synthesis method thereof and use of same in medicine and in cosmetics