CAS: 325129-69-9; 2,2'-(9,9-Dimethyl-9H-Fluorene-2,7-Diyl)Bis(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane)

该化合物是复杂的有机化合物,具有独特的结构特征,包括二氧罗兰环和氟乙烯脊柱.二氧罗朗运动的存在表明有机合成和材料科学中的潜在应用,特别是在开发可用作中间体或催化剂的含有钴的化合物方面.氟化物单位有助于化合物的电子特性,有可能增强其光物理特性,使之适合有机电子或光电学的应用.四甲基聚四甲基子组群提供了阻塞性,可能影响化合物的再活动性和溶性.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

9,9-dimethyl-9H-fluorene bis(pinacol)diborane

合成工艺路线路线简述

    📜2,7-二溴-9,9-二甲基芴,联硼酸频那醇酯置于1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物,Potassium Acetate体系中,用 1,4-二氧六环 作为反应溶剂,以77 %的收率获得产物9,9-二甲基芴-2,7-二硼酸频哪酯
    参考文献:通过氧化偶联方法进行边缘修饰的多环芳烃
    标题:通过氧化偶联方法进行边缘修饰的多环芳烃
    摘要:形成了烷氧基高度边缘修饰的多环芳烃(pah).酚的氧化交叉偶联构建框架,无需传统方法所需的预官能化.此外,相对于类似尺寸的系统,可以实现更小的光学间隙.
    DOI:10.1002/chem.202203405

    海关参考信息

    专利信息


    专利号:US-2014187716-A1
    优先权日:2011-07-15
    标 题:Process for the synthesis of conjugated polymers
    发明人:JONES DAVID JOHN; WONG WING HO WALLACE; HOLMES ANDREW BRUCE; SEYLER HELGA
    权利人:JONES DAVID JOHN; WONG WING HO WALLACE; HOLMES ANDREW BRUCE; SEYLER HELGA; UNIV MELBOURNE
    摘要:Processes for the continuous production of conjugated polymers are disclosed. The processes provide excellent control over reaction parameters and are highly reproducible. The conjugated polymers find use in heterojunction devices.

    专利号:US-2014230902-A1
    优先权日:2011-11-30
    标 题:Co-polymer of 2,7-fluorene and bithiazole, method for preparing same and solar battery containing same
    发明人:ZHOU MINGJIE; WANG PING; ZHANG ZHENHUA; HUANG HUI
    权利人:ZHOU MINGJIE; WANG PING; ZHANG ZHENHUA; HUANG HUI
    摘要:Provided are a co-polymer of formula (I) of 2,7-fluorene and bithiazole, a method for preparing same, and a solar battery containing same. The structural formula of the copolymer of 2,7-fluorene and bithiazole is as shown by formula (I), wherein both R 1 and R 2 are C 1 -C 20 alkyl groups, and n is an integer of 10-100. The co-polymer of the present invention has a novel structure, a good dissolving property, an excellent film-forming property, and a high power conversion efficiency, and can be used as the material for a solar battery. Also provided are the method for preparing the co-polymer and the solar battery containing same. The preparation method uses raw materials widely available and has a simple synthesis route.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献

    参考DOI号:10.1016/j.chempr.2020.02.004
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