CAS: 1626-24-0; Triphenylchlorogermane

该化合物是一种有机金属化合物,其特点是将原子捆绑在三个苯基组和一个氯原子之间,其特点是分子重量和独特结构相对较高,其中包括一个中央原子,该原子因其四个替代成分而具有四合形几何特征.氯三联苯杂物一般是无色的,可粉黄的黄色液体或固体,取决于温度和纯度.它以其再活动性为名,特别是在核分裂替代反应中,氯原子可以被各种核分裂剂所取代.该化合物对各个领域都感兴趣,包括材料科学和有机金属化学,因为它可能被用于含有材料的合成,以及作为其他化合物的前体.然而,与许多有机金属化合物一样,它在处理时,应注意潜在的毒性和与水分或空气的再活动.

结构式图片

相似化合物

1048-05-1 1613-66-7 2816-43-5

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号112712-64-8 三(1,2-苯二醇基-O,O')锗酸二钾 | CAS号1048-05-1 四苯基锗 | CAS号10038-98-9 氯化锗 | CAS号3839-32-5 lithium,triphen... | CAS号24973-59-9 2,4,6-三叔丁若亚硝基苯 | CAS号6430-25-7 acetyltriphenyl... | CAS号2816-43-5 三苯基氢化锗 | CAS号75-36-5 乙酰氯 | CAS号486-25-9 9-芴酮 | CAS号7647-01-0 盐酸 | CAS号18689-08-2 triphenyl(prop-... | CAS号604-53-5 1,1'-联萘 | CAS号605-02-7 1-苯基萘 | CAS号92-91-1 4-联苯乙酮 | CAS号787-69-9 4,4'-二乙酰联苯 | CAS号2816-39-9 六苯基二锗(IV) | CAS号2816-43-5 三苯基氢化锗 | CAS号2181-40-0 六苯基二锗杂噁烷 | CAS号791-29-7 三苯基甲基硅烷

合成工艺路线路线简述

  • 合成目标产物 Triphenylgermanium Chloride 主要起始原料 Chlorodiphenylmethylsilane And Germanium(Iv) Chloride
  • (文献来源)合成步骤主要原料 Chlorodiphenylmethylsilane 和 Germanium(Iv) Chloride
📜Aminotriphenylgermane 以 乙醚,氨 用作溶剂,化学反应生成三苯基氯化锗
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Ge: Mvol.,20,Page 53-57
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Ge: Mvol.,20,Page 53-57

海关参考信息

专利信息


专利号:US-4565896-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
发明人:KNIFTON JOHN F; DURANLEAU ROGER G
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

专利号:US-4609768-A
优先权日:1984-10-22
标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

专利号:US-4568780-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
发明人:KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.

专利号:US-2025084108-A1
优先权日:2021-12-30
标题:Silylating grafting agents, polymers grafted therewith and methods of synthesis
发明人:TAMANG SEM; CHISHOLM BRET J
权利人:BRIDGESTONE CORP
摘要:Silylating grafting agents and methods for synthesizing the same. The grafting agents are used to produce functionalized polydiene polymers by modifying the backbone of the polymer. Methods for functionalizing a polydiene post-polymerization using hydrosilylation are described. Hydrosilylation provides an advantage of incorporating multiple functional groups on the backbone of the polymer which lead to improved properties, such as rolling resistance, wet traction and polymer filler interaction.

专利号:US-4409405-A
优先权日:1982-05-13
标题:Production of ethanol from methanol and synthesis gas
发明人:LIN JIANG-JEN; KNIFTON JOHN F
权利人:TEXACO INC
摘要:Ethanol is formed by contacting a mixture of carbon monoxide, hydrogen and methanol with a catalyst comprising a cobalt-containing compound and a germanium-containing compound, such as dicobalt octacarbonyl and triphenylgermanium hydride in the presence of an inert, oxygenated hydrocarbon solvent at a temperature of about 50 DEG to about 350 DEG C. and at a pressure of about 500 psig or greater.

专利号:WO-2023130006-A1
优先权日:2021-12-30
标题:Silylating grafting agents, polymers grafted therewith and methods of synthesis

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 36.
摘要:Marschner, C., Science of Synthesis Knowledge Updates, (2020) 3, 115.
摘要:Weinert, C. S., Science of Synthesis Knowledge Updates, (2020) 3, 131.
摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 72.
摘要:Ielo, L.; Pace, V., Science of Synthesis: Knowledge Updates, (2025) 2.
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