CAS: 81090-53-1; 4,4'-Dibromotriphenylamine

• 英文名称4,4'-Dibromotriphenylamine
• 中文名称4,4'-二溴三苯胺
• IUPAC名称4-bromo-N-(4-bromophenyl)-N-phenylaniline
• 其它别名N,N-双(对溴苯基)苯胺; N,N-Bis(P-Bromophenyl)Aniline (Purified By Sublimation)
• CAS编号81090-53-1
• MFCD编号:MFCD00060104
• EINECS号:626-530-8
• 分子式:C18H13Br2N
• 分子量:403.12
• 产品CID: 1805252
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: KIGVOJUDEQXKII-UHFFFAOYSA-N
• InChI=1S/C18H13Br2N/c19-14-6-10-17(11-7-14)21(16-4-2-1-3-5-16)18-12-8-15(20)9-13-18/h1-13H…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数3.0

物理性质

• 熔点85 °C
• 沸点470.7±30.0 °C at 760 mmHg
• 闪点>110°C
• 密度1.6±0.1 g/cm3
• PSA:3.24
• LogP:6.6814
• 折射率1.679
• 蒸汽压0.0±1.2 mmHg at 25°C
• 储存条件Store at room temperature

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  皮肤致敏 类别1
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H317 |可能引起皮肤过敏反应.
• 防范说明P261-P264-P270-P271-P272-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xn: Harmful;
• 安全声明26-36/37/39
• 危险类别码R22,R36/37/38,R43
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 603-34-9 = 81090-53-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide; 3 H,Rt
  标题:Highly Emissive Whole Rainbow Fluorophores Consisting Of 1,4-Bis(2-Phenylethynyl)Benzene Core Skeleton: Design,Synthesis,And Light-Emitting Characteristics
  作者:Yamaguchi,Yoshihiro; Et Al
  参考文献:Journal Of Physical Chemistry A 日期:2015 卷标:119(32) 页码:8630-8642]
  
  603-34-9 = 81090-53-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide; 2 D,Rt
  标题:Synthesis,Photophysical,And Electrochromic Properties Of New Triarylamino-Containing Polyphenylquinoxalines
  作者:Keshtov,M. L.; Et Al
  参考文献:Polymer Science 日期:2011 卷标:53(5-6) 页码:257-266]
  
  637-88-7 + 16292-17-4 = 81090-53-1
  反应条件:1.1 Solvents: Toluene; 9 H,Reflux
  标题:Tetrazine-Triphenylamine Dyads: Influence Of The Nature Of The Linker On Their Properties
  作者:Quinton,Cassandre; Et Al
  参考文献:Electrochimica Acta 日期:2013 卷标:110 页码:693-701]
  
  637-88-7 + 16292-17-4 = 81090-53-1
  反应条件:1.1 Catalysts: P-Toluenesulfonic Acid Solvents: Toluene
  标题:Condensation Of 1,4-Cyclohexanediones And Secondary Aromatic Amines. Ii. N-Phenylation Of Diarylamines
  作者:Haga,Kazuo; Et Al
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1986 卷标:59(3) 页码:803-7]
  
  603-34-9 = 81090-53-1 + 4316-58-9
  反应条件:1.1 Reagents: Tetrabutylammonium Bromide Solvents: Methanol,Dichloromethane
  标题:Cooperative Enhancement Of Two-Photon Absorption In Multi-Branched Structures
  作者:Chung,Sung-Jae; Et Al
  参考文献:Journal Of Physical Chemistry B 日期:1999 卷标:103(49) 页码:10741-10745]
  
  589-87-7 = 81090-53-1
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Chromium Copper Oxide (Cr2Cu2O5) Solvents: Toluene; 7 H,Reflux
  标题:C-N Cross-Coupling Reaction Catalysed By Reusable Cucr2O4 Nanoparticles Under Ligand-Free Conditions: A Highly Efficient Synthesis Of Triarylamines
  作者:Safaei-Ghomi,Javad; Et Al
  参考文献:Rsc Advances 日期:2015 卷标:5(37) 页码:28879-28884]
  
  591-50-4 + 16292-17-4 = 81090-53-1
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Toluene; 24 H,Rt -> 120 °C
  标题:Synthesis Of Aie-Active Materials With Their Applications For Antibacterial Activity,Specific Imaging Of Mitochondrion And Image-Guided Photodynamic Therapy
  作者:Yang,Zengming; Et Al
  参考文献:Acs Applied Bio Materials 日期:2020 卷标:3(2) 页码:1187-1196]
  
  591-50-4 + 16292-17-4 = 81090-53-1
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Toluene; 3 H,Rt -> 120 °C
  标题:Two Aggregation-Induced Emission (Aie)-Active Reaction-Type Probes: For Real-Time Detecting And Imaging Of Superoxide Anions
  作者:Ma,Hengchang; Et Al
  参考文献:Analyst (Cambridge 日期:2019 卷标:144(2) 页码:536-542]
  
  591-50-4 + 16292-17-4 = 81090-53-1
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Tetrahydrofuran; 3 H,Rt -> 120 °C; 120 °C -> 75 °C
  标题:Aggregation-Induced Emission (Aie)-Active Fluorescent Probes With Multiple Binding Sites Toward Atp Sensing And Live Cell Imaging
  作者:Ma,Hengchang; Et Al
  参考文献:Journal Of Materials Chemistry B: Materials For Biology And Medicine 日期:2017 卷标:5(43) 页码:8525-8531]
  
  606-87-1 = 81090-53-1
  反应条件:1.1 Reagents: Bromine Solvents: Chloroform1.2 Reagents: Potassium Hydroxide Solvents: Ethanol2.1 Catalysts: P-Toluenesulfonic Acid Solvents: Toluene
  标题:Condensation Of 1,4-Cyclohexanediones And Secondary Aromatic Amines. Ii. N-Phenylation Of Diarylamines
  作者:Haga,Kazuo; Et Al
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1986 卷标:59(3) 页码:803-7]
  
  98-88-4 = 81090-53-1
  反应条件:1.1 -2.1 Reagents: Bromine Solvents: Chloroform2.2 Reagents: Potassium Hydroxide Solvents: Ethanol3.1 Catalysts: P-Toluenesulfonic Acid Solvents: Toluene
  标题:Condensation Of 1,4-Cyclohexanediones And Secondary Aromatic Amines. Ii. N-Phenylation Of Diarylamines
  作者:Haga,Kazuo; Et Al
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1986 卷标:59(3) 页码:803-7

海关参考信息

• 2921440000-二苯胺
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
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专利信息

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管