CAS: 35578-47-3; 4,4'-Dibromobenzil

该化合物是一种高纯度有机化合物,主要用作先进材料,药品和特殊化学品的合成中间体,其二溴化结构使它成为诸如铃木和Heck反应等交叉反应的宝贵前体,从而能够形成复杂的芳香系统;该化合物具有极强的稳定性和明确界定的回活动性,确保合成应用的一贯性;其晶体形式便于在实验室环境中进行处理和精确测量. 4,4'-二溴苯基在液体晶体,聚合物和光电子材料的开发中特别有用,在这种材料的受控功能化至关重要. 它符合研究和工业用途的严格纯度标准,对要求严格的化学工艺来说,它符合严格的纯度标准.

结构式图片

欧盟法规

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上下游产品

CAS号4254-18-6 1,2-bis(4-bromo... | CAS号1122-91-4 对溴苯甲醛 | CAS号37580-82-8 meso-1,2-bis(4-... | CAS号313225-01-3 1H-1,2,3-benzot... | CAS号2789-89-1 二(4-溴苯基)乙炔 | CAS号6048-21-1 4-溴苯甲酰氰 | CAS号201230-82-2 carbon monoxide | CAS号65826-67-7 bis(4-bromophen... | CAS号589-87-7 对溴碘苯 | CAS号19802-70-1 2,3-bis(4-bromo... | CAS号189619-30-5 1,2-bis[4-[2-tr... | CAS号24133-54-8 1,2-Ethanediol,... | CAS号213776-05-7 (R,R)-(+)-1,2-b... | CAS号384331-54-8 (1S,2S)-1,2-bis... | CAS号1603-61-8 Benzene,(2-cycl... | CAS号3321-50-4 1,2-二环己基乙烷 | CAS号103-29-7 1, 2-二苯乙烷 | CAS号330441-57-1 6-[2,3-bis(4-br... | CAS号30738-49-9 DIBROMOBENZILIC ACID

合成工艺路线路线简述

    📜4-溴苯甲酰腈置于indium体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 12.0H,以62%的收率获得产物4,4'-二溴联苯酰
    参考文献:铟介导的酰基氰的还原偶联:1,2-二酮的便捷合成
    标题:铟介导的酰基氰的还原偶联:1,2-二酮的便捷合成
    摘要:在中性和温和条件下,铟介导的酰基氰的还原偶联以中等至非常好的产率提供了相应的1,2-二酮.
    DOI:10.1016/s0040-4039(00)01411-8

    海关参考信息

    专利信息


    专利号:US-10577325-B2
    优先权日:2017-03-28
    标 题 :Method for preparing a series of carbazole derivatives and use thereof in organic light-emitting diodes
    发明人:CAO JIANHUA; WANG SHIBO; HUA RUIMAO
    权利人:SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD
    摘要:Disclosed are a method for preparing a series of carbazole derivatives and use thereof in organic light-emitting diodes. The structure of the material is as shown in Formula I. An organic electroluminescent device prepared by the material can have a significantly improved power efficiency and an external quantum efficiency for the device and an extended life for an orange light or red light device; moreover, the material has characteristics, for example, methods for the synthesis and purification of the material are simple and suitable for large-scale production, and is an ideal choice as a luminescent material for organic electroluminescent devices. The use of the organic electroluminescent diode material as a carrier transport material or as a luminescent material alone or as a host material in a light-emitting layer also falls within the scope of protection.

    专利号:CN-113512073-B
    优先权日:2021-03-12
    标题:Synthesis of undoped nickel-based metal-organic complex hole transport materials and their application in perovskite solar cells

    专利号:CN-113512073-A
    优先权日:2021-03-12
    标题 :Synthesis of Novel Undoped Nickel-Based Metal-Organic Complex Hole Transport Materials and Their Applications in Perovskite Solar Cells

    专利号:WO-2022052135-A1
    优先权日:2020-09-14
    标 题 :Chiral thermally activated delayed fluorescence material and preparation method therefor
    发明人:TANG JIANXIN; XIE FENGMING; LI YANQING; ZHOU JINGXIONG; ZENG XINYI
    权利人:UNIV SOOCHOW
    摘要:The present invention relates to a chiral thermally activated delayed fluorescence (TADF) material and a preparation method therefor. The chiral TADF material is R/S-18,21-bis(10H-phenoxazine-10-yl)-3,4,5,6,7,8,9,10-octahydrodibenz[a,c]dinaphtho[2',1':5,6;1',2':7,8][1,4]dioxin[2,3-i]phenazine or R/S-16,17-bis(4-(10H-phenoxazine-10-yl)phenyl)-3,4,5,6,7,8,9,10-octahydrodinaphtho[2',1':5,6;1',2':7,8][1,4]dioxane[2,3-g]quinoxaline. The provided compound has the characteristics of rigid large-plane twisted structure and significant intramolecular charge transfer (ICT) effect, and has the typical advantages such as TADF property, circular polarization (CPL) property, high photoluminescence quantum yield (PLQY), and good thermal stability. Moreover, the chiral TADF material has few synthesis and preparation steps, readily available raw materials, simple synthesis and purification processes, and high yield, and can be synthesized and prepared on a large scale.

    专利号:CN-117510478-A
    优先权日:2023-12-01
    标 题 :Design, synthesis and application of organic photocatalysts based on pyrazine and quinoxaline skeletons

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Dong Wook Chang, Et Al. Novel Quinoxaline-Based Organic Sensitizers For Dye-Sensitized Solar Cells. Org Lett. 2011 Aug 5;13(15):3880-3.

    合成参考文献


    摘要:Schatz, J.; Seler, M., Science of Synthesis Knowledge Updates, (2011) 2, 373.
    摘要:Sato, N., Science of Synthesis Knowledge Updates, (2011) 4, 257.
    摘要:Zeitler, K., Science of Synthesis, (2019) , 307.
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