CAS: 299-84-3; Fenchlorphos

该化合物是一种有机磷化合物,历史上一直用作杀虫剂和杀螨剂,其化学结构中含有一种磷酸盐组,它与三氯联苯协会结合,有助于其针对害虫的广泛活动;敌百虫展示接触和胃动作,使其在农业和兽医应用中有效控制节肢动物;该化合物以其在正常环境条件下的相对稳定的配方闻名,尽管它在碱性介质中进行水解降解;由于其作为胆碱酶抑制剂的行动模式,适当的处理和遵守规章是必要的;由于对环境和毒理学的关切,其在许多区域的使用已经减少,但在具体的虫害管理环境中仍然引起兴趣.

结构式图片

物理性质

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

dimethyl chlorothiophosphate 2,4,5-trichlorophenol O-(2,4,5-trichloro-phenyl) esterthiophosphorodichloridic acid O-(2,4,5-trichloro-phenyl) ester -phosphitDimethyl-2,4,5-trichlor-phenyl-phosphit-thiophosphatTripropyl-methyl-phosphonium S-methyl-O-2,4,5-trichlor-phenyl-thiophosphat -thiophosphatTributyl-methyl-phosphonium S-methyl-O-2,4,5-trichlor-phenyl-thiophosphat -thiophosphorsaeureO-Methyl-O-2,4,5-trichlor-phenyl-thiophosphorsaeure -thiophosphatTriaethyl-methyl-phosphonium S-methyl-O-2,4,5-trichlor-phenyl-thiophosphat

合成工艺路线路线简述

  • 合成目标产物 Fenchlorphos 主要起始原料 2,4,5-Trichlorophenol
  • (文献来源)合成步骤主要原料 2,4,5-Trichlorophenol
📜2,4,5-三氯苯酚置于sulfur体系中,化学反应生成皮蝇磷
参考文献:Petrov,K.A. Et Al.,Journal Of General Chemistry Of The Ussr,1962,Vol. 32,P. 909-911
标题:Petrov,K.A. Et Al.,Journal Of General Chemistry Of The Ussr,1962,Vol. 32,P. 909-911

海关参考信息

专利信息


专利号:US-6129134-A
优先权日:1999-03-11
标 题 :Synthesis of metal matrix composite
发明人:DIVECHA AMARNATH P
权利人:US NAVY
摘要:Reinforcing particles within a flux are dispersed through a metal matrix osited into a crucible purged of air by infeed of argon gas during heating of the matrix to a melted state for completing particle dispersion by agitation before remelting thereof after solidification. The remelted matrix with the particles fully dispersed therein is then allowed to undergo sedimentation increasing particle concentration along a flat surface portion of the final product having increased wear resistance thereat.

专利号:US-7829654-B2
优先权日:2004-05-11
标 题 :Method for producing elastomeric copolyesters
发明人:KAEMPF RUDOLF
权利人:LURGI ZIMMER GMBH
摘要:A process for continuous or discontinuous synthesis of elastomeric copolyesters from polybutylene terephthalate (PBT) and polyoxytetramethylene glycol is described in which the tetrahydrofuran (THF) obtained as a byproduct in synthesis of polybutylene terephthalate from 1,4-butanediol is rectified and then reacted by ring-opening polymerization to form polyoxytetramethylene glycol which condenses with the free or esterified carboxyl groups of PBT to form the copolyester, whereby chain termination and catalyst deactivation are accomplished by adding 1,4-butanediol without separating the catalyst.

专利号:US-7427711-B2
优先权日:2004-08-19
标 题:Particle based touch interaction for the creation of media streams
发明人:O'MODHRAIN MAURA SILE; ESSL GEORG
权利人:O'MODHRAIN MAURA SILE; ESSL GEORG
摘要:Methods and apparatus for manipulating physical objects to produce sounds that are correlated with the feel of the objects being manipulated. Example devices called the PebbleBox, CrumbleBag and ScrubberGlove each use the manipulation of physical objects of arbitrary material as the basis for interacting with granular sound synthesis models. The sounds made by the objects as they are manipulated produce sound signal events that are detected and used to trigger and control the reproduction of stored sound samples in real time.

专利号:WO-2021074309-A1
优先权日:2019-10-16
标 题:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; SEN INDIRA; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-3,4-dihydroisoquinoline derivative of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale) when spayed on plants), as well as comparative data against three prior art compounds (e.g. pages 52 to 85; formulation examples; examples A1 to A3; table E; compounds E.01 to E.187; biological examples). Exemplary compounds are e.g.: 5-bromo-1-(8-fluoro-3-quinolyl)spiro[4H-isoquinoline-3,1'- cyclopropane] (example A1) 5-bromo-1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline (example A2) 1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline-5-carbonitrile (example A3)

专利号:WO-2021074311-A1
优先权日:2019-10-16
标题:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola, Monographella nivalis, Fusarium culmorum and/or Gibberella zeae when spayed on plants) (e.g. pages 47 to 55; examples A1 and A2; compounds E.01 to E.17; table E). An exemplary compounds is e.g.: 3-(5-bromo-3,3-dimethyl-2,4-dihydro-1 H-isoquinolin-1-yl)-8-fluoro- quinoline (example A1)

专利号:US-4776971-A
优先权日:1985-05-29
标 题:Gallium arsenide single crystals with low dislocation density and high purity
发明人:MATTERA ADRIANO; FORNARI ROBERTO; MAGNANINI RENATO; PAORICI CARLO; ZANOTTI LUCIO; ZUCCALLI GIOVANNI
权利人:MONTEDISON SPA; CONSIGLIO NAZIONALE RICERCHE
摘要:Undoped GaAs single crystals with low dislocation density, low impurity content, 0.20-1 Kg in weight and constant diameter of 1''-2'' (inches), said single crystals being obtained with LEC technology at low or high pressure with synthesis of the polycrystal in situ and subsequent growth of the single crystal.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献


1: Nalipay MJN, King RB, Cai Y. Autonomy is equally important across East and West: Testing the cross-cultural universality of self-determination theory. J Adolesc. 2020 Jan;78:67-72. doi: 10.1016/j.adolescence.2019.12.009. Epub 2019 Dec 14.
70:105-122. doi: 10.1016/j.jsp.2018.08.001. Epub 2018 Sep 13.
155:162-170. doi: 10.1016/j.ecoenv.2018.02.063. Epub 2018 Mar 6. 13(1):e0190821. doi: 10.1371/journal.pone.0190821.

合成参考文献


摘要:World Review of Pest Control., 9(119), 1970
摘要:Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel, Perkow, W., Berlin, Verlag Paul Parey, 1971-1976, -(-), 1971/1976
摘要:Veterinariya. Veterinary Science., 51(8)(101), 1974
摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 52(11)(24), 1987
摘要:Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen, 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971, -(26), 1971
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