CAS: 124-25-4; Tetradecanal

该化合物是一种饱和长链甲醛,有14个碳柱,通常用作有机合成的关键中间体,特别是在香味,口味和特殊化学品的生产中.它的线性结构和甲状腺功能使它成为酒精,酸和其他衍生物合成的多功能构件.Tetradcanal在标准条件下表现出稳定性,并且可溶于有机溶剂,便于其在工业应用中的使用.它的一贯纯度和可预测的再活性提高了其对精密化学工艺,包括制药和农用化学制造的适宜性.

结构式图片

相似化合物

112-72-1 124-10-7 544-63-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

myristonitrile selenous acid ditetradecyl ester 1-Tetradecanol 2-hydroxypentadecanoic acid1,1-dimethoxytetradecane 2-pentadecanol (2E)-hexadecenoic acid 6,6'-diisopropyl-3,3'-dimethyl-2,2'-tetradecylidene-di-phenol

合成工艺路线路线简述

    📜十三烷醇置于盐酸,乳酸,二异丁基氢化铝,三乙胺体系中,用 正己烷,二甲基亚砜 用作溶剂,化学反应 28.0H,反应生成肉豆蔻醛
    参考文献:化学防御和自卫:士兵白蚁产生的接触杀虫剂的生化转化
    标题:化学防御和自卫:士兵白蚁产生的接触杀虫剂的生化转化
    摘要:犀白蚁(等翅目:犀白蚁)的高级属的士兵生产形式上衍生自脂肪酸的亲脂性接触杀虫剂.这些防御物质均具有负责毒性的反应性亲电子中心(乙烯基酮,硝基烯烃或β-酮醛).我们描述了其中两个物种的放射性标记的防御分泌物的合成及其在研究工人白蚁对底物的选择性脱毒中的用途.还讨论了白蚁士兵生物合成防御分泌物的初步研究.
    Doi:10.1016/0040-4020(82)80041-0

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    专利信息


    专利号:US-9643915-B2
    优先权日:2013-03-15
    标题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
    发明人:ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
    权利人:CERENIS THERAPEUTICS HOLDING SA
    摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

    专利号:US-9708354-B2
    优先权日:2013-03-15
    标 题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
    发明人:ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
    权利人:CERENIS THERAPEUTICS HOLDING SA
    摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

    专利号:WO-2023102600-A1
    优先权日:2021-12-06
    标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
    发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
    权利人:NEWSOUTH INNOVATIONS PTY LTD
    摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-10730904-B2
    优先权日:2012-11-14
    标 题:Method for liquid-phase synthesis of nucleic acid
    发明人:NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO
    权利人:TAKEDA PHARMACEUTICALS CO
    摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.

    专利号:US-2006211083-A1
    优先权日:2005-01-21
    标题:Products and processes for in vitro synthesis of biomolecules
    发明人:KATZEN FEDERICO; KUDLICKI WIESLAW; FLETCHER JULIA
    权利人:KATZEN FEDERICO; KUDLICKI WIESLAW; FLETCHER JULIA
    摘要:Provided herein are products and processes for efficiently synthesizing biomolecules in vitro using cell-free extracts derived from mammalian cells and insect cells. In an embodiment, provided is a process for preparing a cell-free extract from insect cells and mammalian cells that efficiently synthesizes post-translationally modified target proteins (e.g., glycosylated target proteins). In some embodiments, a ribonucleic acid is synthesized in vitro that comprises a cap, a 5′ untranslated region comprising an 18S rRNA binding ribonucleotide sequence, and a target ribonucleotide sequence. It has been determined that such ribonucleic acids result in efficient in vitro synthesis of a target protein using cell-free extracts derived from non-rabbit mammalian cells and insect cells.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1111/j.1365-2958.2011.07765.x
    摘要:Hankins JV, Madsen JA, Giles DK, Childers BM, Klose KE, Brodbelt JS, Trent MS. Elucidation of a novel Vibrio cholerae lipid A secondary hydroxy‐acyltransferase and its role in innate immune recognition. Molecular Microbiology. 2011 Jul 18;81(5):1313–29. doi: 10.1111/j.1365-2958.2011.07765.x.
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