CAS: 114902-16-8; (2S,3R,4S,5S,6R)-6-((((2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-(Hydroxymethyl)-5-(((2S,3R,4R,5R,6S)-3,4,5-Trihydroxy-6-Methyltetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)Methyl)-3,4,5-Trihydroxytetrahydro-2H-Pyran-2-Yl (4As,6As,6Br,8Ar,10S,12Ar,12Br,14Bs)-10-(((2S,3R,4S,5S)-4,5-Dihydroxy-3-(((2S,3R,4R,5R,6S)-3,4,5-Trihydroxy-6-Methyltetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)-6A,6B,9,9,12A-Pentamethyl-2-Methylene-1,3,4,5,6,6A,6B,7,8,8A,9,10,11,12,12A,12B,13,14B-Octadecahydropicene-4A(2H)-Carboxylate
该化合物是主要源于Acanthopanax senticosus(Siberian gusen)根部的三叶杆状沙邦素化合物,具有显著的药理特性,包括抗炎,抗氧化剂和...
- 英文名称(2S,3R,4S,5S,6R)-6-((((2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-(Hydroxymethyl)-5-(((2S,3R,4R,5R,6S)-3,4,5-Trihydroxy-6-Methyltetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)Methyl)-3,4,5-Trihydroxytetrahydro-2H-Pyran-2-Yl (4As,6As,6Br,8Ar,10S,12Ar,12Br,14Bs)-10-(((2S,3R,4S,5S)-4,5-Dihydroxy-3-(((2S,3R,4R,5R,6S)-3,4,5-Trihydroxy-6-Methyltetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)-6A,6B,9,9,12A-Pentamethyl-2-Methylene-1,3,4,5,6,6A,6B,7,8,8A,9,10,11,12,12A,12B,13,14B-Octadecahydropicene-4A(2H)-Carboxylate
- 中文名称刺五加皂甙 B
- IUPAC名称(2S,3R,4S,5S,6R)-6-((((2R,3R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-(((2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)methyl)-3,4,5-trihydroxytetrahydro-2H-pyran-2-yl (4aS,6aS,6bR,8aR,10S,12aR,12bR,14bS)-10-(((2S,3R,4S,5S)-4,5-dihydroxy-3-(((2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-6a,6b,9,9,12a-pentamethyl-2-methylene-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydropicene-4a(2H)-carboxylate
- 其它别名Yemuoside Ym; Acanthopanax Senticosides B
- CAS编号114902-16-8
- MFCD编号:MFCD10566605
- 分子式:C58H92O25
- 分子量:1189.35
- 产品CID: 183164
- 产品分类生物化工 → 提取物 → 植物提取物
物理性质
MSDS等安全信息
- 警示词warning
- 危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
- 防范说明P264Thoroughly clean after treatmentP280Wear protective gloves/Wear protective clothing/Wear protective goggles/Wear a protective maskP305If it enters the eyesP351Rinse carefully with water for a few minutesP338Remove the contact lens(If any)And easy to operate,Continue flushingP337If eye irritation persistsP313Obtain medical advice/care
- 安全声明H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
上下游产品
2ciwujianoside C2L-arabinose L-Rhamnose D-glucose合成工艺路线路线简述
Ciwujianoside C2置于氢氧化钾体系中,化学反应 24.0H,以31 Mg的收率获得刺五加皂甙 B
参考文献:Shao,Chun-Jie; Kasai,Ryoji; Xu,Jing-Da,Chemical And Pharmaceutical Bulletin,1988,Vol. 36,# 2,P. 601-608
标题:Shao,Chun-Jie; Kasai,Ryoji; Xu,Jing-Da,Chemical And Pharmaceutical Bulletin,1988,Vol. 36,# 2,P. 601-608
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
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- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:CN-113281431-A
优先权日:2021-05-17
标题 :Synthesis method of deep eutectic solvent and method for extracting and purifying eleutheroside B
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主要参考文献
1: Dong WR, Gao X, Li CX, Song Y, Chai JH, Liang J. Detection and Characterization of the Metabolites of Ciwujianoside B in Rats Based on UPLC- Fusion Lumos Orbitrap Mass Spectrometry. J Anal Methods Chem. 2024 May 22;2024:3187511. doi: 10.1155/2024/3187511.
2: Li YR, Cao W, Guo J, Miao S, Ding GR, Li KC, Wang J, Guo GZ. Comparative investigations on the protective effects of rhodioside, ciwujianoside-B and astragaloside IV on radiation injuries of the hematopoietic system in mice. Phytother Res. 2011 May;25(5):644-53. doi: 10.1002/ptr.3313. Epub 2010 Oct 28. 11(5):1142. doi: 10.3390/nu11051142.
4: Liu Y, Wang Z, Wang C, Si H, Yu H, Li L, Fu S, Tan L, Li P, Liu J, Zhao Y. Comprehensive phytochemical analysis and sedative-hypnotic activity of two Acanthopanax species leaves. Food Funct. 2021 Mar 15;12(5):2292-2311. doi: 10.1039/d0fo02814b. 27(6):2849-2865. doi: 10.1007/s11030-022-10586-3. Epub 2022 Dec 28. 14(1):26330. doi: 10.1038/s41598-024-77574-5.
合成参考文献
参考文献:10.1248/cpb.36.601
摘要:SHAO C, KASAI R, XU J, TANAKA O. Saponins from leaves of Acanthopanax senticosus Harms., ciwujia: Structures of ciwujianosides B, C1, C2, C3, C4, D1, D2 and E. Chem. Pharm. Bull. 1988;36(2):601–8. doi: 10.1248/cpb.36.601.
参考文献:10.1016/j.phytochem.2005.02.016
摘要:Seo JW, Jeong JH, Shin CG, Lo SC, Han SS, Yu KW, Harada E, Han JY, Choi YE. Overexpression of squalene synthase in Eleutherococcus senticosus increases phytosterol and triterpene accumulation. Phytochemistry. 2005 Apr;66(8):869–77. doi: 10.1016/j.phytochem.2005.02.016.
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