CAS: 112400-86-9; 1-Butyl-4-Methylpyridinium Chloride

该化合物是一种属于基于基盐类的离子液体,在1位置上有一个丁基链,在环的4位置上有一个甲基组,有助于其独特的物理化学特性.该化合物在极地溶剂中具有高度的热稳定性,低挥发性和高溶性,适合用于催化,电化学和材料合成.其离子性质允许金枪鱼的极性和再活动,使其能够在有机转化中用作绿色溶剂或反应媒介.氯化电离子进一步增强了其在协调化学方面的效用,并通过离子交换作为其他离子液体的前体.

结构式图片

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65350-59-6 343952-33-0 401788-99-6

欧盟法规

ECHA物质C&L通报

上下游产品

picoline n-Butyl chloridemethylene chloride 1-butyl-4-methylpyridinium trifluoromethylsulfonate 4-methyl-N-butylpyridinium tetrafluoroborate 1-butyl-4-[2-(4-dimethylaminophenyl)ethenyl]pyridinium chloride

合成工艺路线路线简述

    📜4-甲基吡啶,氯丁烷 以 甲苯 用作溶剂,化学反应 10.0H,反应生成1-丁基-4-甲基氯化吡啶鎓
    参考文献:Effects Of Halide Anions To Absorb So2In Ionic Liquids
    标题:Effects Of Halide Anions To Absorb So2In Ionic Liquids
    摘要:制备了含有卤化物阴离子的离子液体,并研究了卤化物阴离子对离子液体$so_2$溶解度的影响.研究表明,离子液体的$so_2$溶解度在$so_2$/ils 摩尔比 1.91~2.22 之间.$so_2$ 在不同卤化物阴离子的离子液体中的溶解度遵循 Br > Cl > I 的顺序.通过对 $so_2$ 和 [emim]X(其中 X = Cl,Br 和 I)之间相互作用的理论研究,提出了卤化物的主要相互作用发生在咪唑鎓的 $c_2$-H 和 $so_2$ 的 S 上.实验结果进一步表明,$50^{\circ}C$的吸收和$140^{\circ}C$的解吸是可逆的.傅立叶变换红外研究证实了 $so_2$ 吸收的可逆性.
    Doi:10.5012/bkcs.2010.31.7.1937

    海关参考信息

    专利信息


    专利号:US-2010191010-A1
    优先权日:2007-07-02
    标题 :Process for the synthesis of carbamates using co2
    发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
    权利人:HUNTSMAN INT LLC
    摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

    专利号:US-11884855-B2
    优先权日:2019-07-08
    标 题 :Synthesis of europium halide perovskites in solution phase
    发明人:YANG PEIDONG; HUANG JIANMEI; LEI TENG
    权利人:UNIV CALIFORNIA
    摘要:A solution phase synthesis process for preparing a rare earth perovskite, the process includes reacting an alkali metal material with a first surfactant ligand in the presence of a first solvent to obtain a first precursor complex solution; reacting a rare earth metal halide with a second surfactant ligand in the presence of a second solvent to obtain a second precursor complex solution; and reacting the first precursor complex solution with the second precursor complex solution in the presence of a third surfactant ligand and a third solvent to obtain the rare earth perovskite; wherein: the rare earth perovskite is in the form of nanocrystals; and the first solvent and third solvent comprise a non-coordinating solvent.

    专利号:WO-2024013423-A1
    优先权日:2022-07-14
    标题:Method for polyurethane depolymerization
    发明人:LOZANO RODRÃ?GUEZ PEDRO; VILLA AROCA ROCÃ?O; SALAS VIDAL REBECA; GARCÃ?A-VERDUGO CEPEDA EDUARDO; MACIÃ? DELGADO MARÃ?A
    权利人:UNIV MURCIA; UNIV JAUME I; ASOC EMPRESARIAL CENTRO TECNOLOGICO DEL MUEBLE Y LA MADERA DE LA REGION DE MURCIA
    摘要:The present invention relates to a method for the depolymerization of a polyurethane mass, preferably thermoset polyurethane. The method comprises four main steps: i) mixing the polyurethane mass with a depolymerization reaction medium comprising an ionic liquid in a proportion equal to or greater than 50% w/w with respect to the total weight of said medium, a superbase as a catalyst, and a nucleophilic agent in a proportion equal to or less than 15% w/w with respect to the total weight of said medium, subjecting said mixture to a temperature between 50-100°C for between 2 minutes and 10 hours; ii) adding a mass of a protic molecular solvent in an amount between 4 and 40 times the weight of the depolymerization reaction medium; iii) subjecting the mixture from step ii) to a temperature between 20-60°C for at least 1 hour; and iv) separating the fractions obtained in step iii), namely, a semisolid fraction comprising at least a polyol mass for reuse in the synthesis of a new polyurethane, and a single-phase liquid fraction comprising at least the ionic liquid and the basic catalyst, for their reuse in a new process for polyurethane depolymerization.

    专利号:US-2022259497-A1
    优先权日:2019-07-08
    标 题 :Synthesis of europium halide perovskites in solution phase

    专利号:WO-2021007060-A1
    优先权日:2019-07-08
    标题:Synthesis of europium halide perovskites in solution phase

    专利号:EP-2173705-A1
    优先权日:2007-07-02
    标 题:Process for the synthesis of carbamates using co2

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.2478/s11532-010-0132-x
    摘要:Pajuste K, Plotniece A, Kore K, Intenberga L, Cekavicus B, Kaldre D, Duburs G, Sobolev A. Use of pyridinium ionic liquids as catalysts for the synthesis of 3,5-bis(dodecyloxycarbonyl)-1,4-dihydropyridine derivative. 2010 Dec 16;9(1):143–8. doi: 10.2478/s11532-010-0132-x.
    参考文献:10.1007/978-981-95-2947-6_10
    摘要:Joseph A, Mathew S. Ionic Liquid-Based Redox Flow Batteries. 2026. In: Handbook of Energy Materials.
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