CAS: 92666-21-2; (E)-1-Benzyloxy-2-Methoxy-4-(1-Propenyl)Benzene

该化合物是一种有机化合物,其结构复杂,包括一个由甲基氧和苯氧组替代的苯环,以及一个丙烯基组.该化合物是更大的芳香化合物类别的一部分,以其稳定性和独特的反应性而闻名,因为它在苯环中的非本地化电子具有稳定性和独特的反应性.甲基氧基组的存在增强了其在有机溶剂中的溶解性,并能够影响其在电子生物替代反应中的再活动.prepenyl 组引入了一种双联,可以参与多种化学反应,例如聚合或添加反应.此外,该化合物可能具有有趣的生物特性,使其成为医药化学的一个对象.其在化学反应中的具体应用和行为将取决于现有功能组及其与其他分子的相互作用.

英文名称(E)-1-Benzyloxy-2-Methoxy-4-(1-Propenyl)Benzene
中文名称(E)-1-苄氧基-2-甲氧基-4-(1-丙烯基)苯
IUPAC名称(E)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene
其它别名Benzene,2-methoxy-1-(phenylmethoxy)-4-(1-propenyl)-, (E)- (9CI)
CAS编号92666-21-2
MFCD编号:MFCD00026985
分子式:C17H18O2分子量:254.33
产品CID: 1965410
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
InChIKey: YKSSSKBJDZDZTD-XVNBXDOJSA-N
InChI=1S/C17H18O2/c1-3-7-14-10-11-16(17(12-14)18-2)19-13-15-8-5-4-6-9-15/h3-12H,13H2,1-2H3/b7-3+
计算化学: 氢键受体数2.0氢键供体数*可旋转键数5.0

相似化合物

120-11-6 24807-37-2 55708-65-1

MSDS等安全信息

警示词Warning
危险描述H302-H315-
防范说明P264-P270-P280-P302+P352-P330-P362+P364-P501
安全声明H303+H316
WGK Germany3

上下游产品

合成工艺路线路线简述

57371-42-3 = 92666-21-2
反应条件:1.1 Catalysts: Nickel,Bis[1,3-Bis[2,6-Bis(1-Methylethyl)Phenyl]-1,3-Dihydro-2H-Imidazol-2-Ylid... Solvents: Chlorobenzene; 3 H,Rt
标题:E-Olefins Through Intramolecular Radical Relocation
作者:Kapat,Ajoy; Sperger,Theresa; Guven,Sinem; Schoenebeck,Franziska
参考文献:Science (Washington 日期:2019 卷标:363(6425) 页码:391-396]

57371-42-3 = 92666-21-2
反应条件:1.1 Reagents: Lithium Tert-Butoxide,2-(Dimethylphenylsilyl)-4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane Catalysts: Ferrous Acetate Solvents: Toluene; 24 H,100 °C
标题:Methods Of Borylation And Uses Thereof
参考文献:World Intellectual Property Organization]

= 92666-21-2 [标题:Reaction Conditions
标题:First Green Protocols For The Large-Scale Preparation Of γ-Diisoeugenol And Related Dihydro(1H)Indenes Via Formal [3+2] Cycloaddition Reactions
作者:Kouznetsov,Vladimir V.; Merchan Arenas,Diego R.
参考文献:Tetrahedron Letters 日期:2009 卷标:50(14) 页码:1546-1549]

57371-42-3 = 92666-21-2 + 128839-47-4
反应条件:1.1 Catalysts: Tricyclohexylphosphine,Palladium,Hexakis[μ-(Acetato-Ko:Ko′)]Tri-,Cyclo,Bis(Pinacolato)Diborane Solvents: Toluene; 12 H,80 °C
标题:Pd-Boron-Catalyzed One Carbon Isomerization Of Olefins: Water Assisted Process At Room Temperature
作者:Ojha,Devi Prasan; Gadde,Karthik; Prabhu,Kandikere Ramaiah
参考文献:Journal Of Organic Chemistry 日期:2017 卷标:82(9) 页码:4859-4865]

56-93-9 + 97-53-0 = 92666-21-2 + 93-15-2 + 57371-42-3
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Diglyme; 4 H,150 - 155 °C
标题:Synthesis Of Aryl Alkyl Ethers By Alkylation Of Phenols With Quaternary Ammonium Salts
作者:Maras,Nenad; Polanc,Slovenko; Kocevar,Marijan
参考文献:Acta Chimica Slovenica 日期:2010 卷标:57(1) 页码:29-36]

57371-42-3 = 92666-21-2
反应条件:1.1 Catalysts: Lithium Tert-Butoxide,Ferrous Acetate,2-(Dimethylphenylsilyl)-4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane Solvents: Toluene; 24 H,100 °C
标题:Iron-Catalyzed Tunable And Site-Selective Olefin Transposition
作者:Yu,Xiaolong; Zhao,Haonan; Li,Ping; Koh,Ming Joo
参考文献:Journal Of The American Chemical Society 日期:2020 卷标:142(42) 页码:18223-18230]

57371-42-3 = 92666-21-2
反应条件:1.1 Catalysts: Nickel,Bis[1,3-Bis[2,6-Bis(1-Methylethyl)Phenyl]-1,3-Dihydro-2H-Imidazol-2-Ylid... Solvents: Chlorobenzene; 3 H,Rt
标题:Ni(I)-Catalyzed Isomerization Of Alkenes
参考文献:World Intellectual Property Organization]

2426-87-1 + 1530-32-1 = 92666-21-2 + 128839-47-4
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane
标题:Palladium-Assisted (Z)-(E) Isomerization Of Styrenes
作者:Giles,Robin G. F.; Son,Vanessa R. Lee; Sargent,Melvyn V.
参考文献:Australian Journal Of Chemistry 日期:1990 卷标:43(4) 页码:777-81]

5932-68-3 = 92666-21-2
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 2 H,Rt1.2 45 Min,Rt; 12 H,60 °C
标题:Counterattack Mode Differential Acetylative Deprotection Of Phenylmethyl Ethers: Applications To Solid Phase Organic Reactions
作者:Chakraborti,Asit K.; Chankeshwara,Sunay V.
参考文献:Journal Of Organic Chemistry 日期:2009 卷标:74(3) 页码:1367-1370]

= 92666-21-2 [标题:Reaction Conditions
标题:Studies On Chromium Trioxide-Based Oxidative Coupling Reagents And Synthesis Of Lignan-Cagayanone
作者:Kuo,Yueh Hsiung; Lin,Sheng Tsair
参考文献:Chemical & Pharmaceutical Bulletin 日期:1993 卷标:41(9) 页码:1507-12]

= 92666-21-2 [标题:Reaction Conditions
标题:Trans-Isoeugenol And Its Derivatives
参考文献:Japan]

57371-42-3 = 92666-21-2 + 128839-47-4
反应条件:1.1 Catalysts: Potassium Triethylborohydride,2835525-51-2 Solvents: Tetrahydrofuran; 10 Min,Rt1.2 Solvents: Tetrahydrofuran; 24 H,60 °C
标题:Switching Between Hydrogenation And Olefin Transposition Catalysis Via Silencing Nh Cooperativity In Mn(I) Pincer Complexes
作者:Yang,Wenjun; Chernyshov,Ivan Yu.; Weber,Manuela; Pidko,Evgeny A.; Filonenko,Georgy A.
参考文献:Acs Catalysis 日期:2022 卷标:12(17) 页码:10818-10825]

57371-42-3 = 92666-21-2 + 128839-47-4
反应条件:1.1 Reagents: Diethyl Phosphite,Zinc Catalysts: 6,6′-Dimethyl-2,2′-Bipyridine,Nickel Dichloride Solvents: Dimethylacetamide; 24 H,35 °C
标题:Method For Synthesizing E-Type Methylstyrene Compound
参考文献:China

📜4-丙烯基-2-甲氧基苯苄置于iron(II) Acetate,(二甲基苯硅烷基)硼酸频那醇酯,Lithium Tert-Butoxide体系中,用甲苯作为反应溶剂,化学反应 24.0H,以95%的收率获得产物1-苄氧基-2-甲氧基-4-丙烯基苯
参考文献:铁催化的可调和位点选择性烯烃转位
标题:铁催化的可调和位点选择性烯烃转位
摘要:Cc 双键的催化异构化是必不可少的化学转化,用于提供更高价值的类似物,在化学工业中具有重要用途.尽管在该领域取得了进展,但仍然迫切需要一种通用催化解决方案,能够精确控制环状和非环状体系中的 C=c 键迁移位置,以提供二取代和三取代烯烃.在这里,我们展示了催化量的合适的地球丰富的铁基络合物,碱和硼基化合物促进有效和可控的烯烃转位.机理研究表明,这些过程可能涉及原位形成铁氢化物物种,该物种通过顺序烯烃插入/β-氢化物消除促进烯烃异构化.通过这个策略,
DOI:10.1021/jacs.0C08631