CAS: 84-51-5; 2-Ethylanthracene-9,10-Dione

• 英文名称2-Ethylanthracene-9,10-Dione
• 中文名称2-乙基蒽醌
• IUPAC名称2-ethylanthracene-9,10-dione
• 其它别名2-乙基; 2乙基蒽醌; 2-Ethylanthraquinone
• CAS编号84-51-5
• MFCD编号:MFCD00001237
• EINECS号:201-535-4
• FDA UNII编号:59YJ81QZKD
• 分子式:C16H12O2
• 分子量:236.27
• 产品CID: 1833814
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: SJEBAWHUJDUKQK-UHFFFAOYSA-N
• InChI=1S/C16H12O2/c1-2-10-7-8-13-14(9-10)16(18)12-6-4-3-5-11(12)15(13)17/h3-9H,2H2,1H3…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数1.0

物理性质

• 熔点108-111°C
• 沸点180-190°C at 760 mmHg
• 闪点>210°C
• 密度1.2±0.1 g/cm3
• PSA:34.14
• LogP:3.0244
• 折射率1.629
• 蒸汽压0.0±1.0 mmHg at 25°C
• 溶解性0.00025G/l
• 敏感性Stable. Combustible. Incompatible with strong oxidizing agents.
• 外观形态淡黄色至琥珀色至深绿色粉末至晶体
• 储存条件存储低于 +30°C.
• 产品应用制造双氧水,染料中间体,光固化树脂催化剂,光降解膜,涂料和光敏聚合引发剂.质量指标 指标名称 规 格 外观 淡黄色片状固体 淡黄色片状固体 含量 ≥98.5 ≥99.0氯ppm ≤50 ≤40硫ppm ≤10 ≤5铁ppm ≤5 ≤4苯不溶物 ≤0.05 ≤0.02 熔点 °C 108-111 109-111
• 性质描述该品为淡黄色片状晶体.熔点107-111°C.

MSDS等安全信息

• GHS象形图
• GHS符号GHS08 & GHS09;
  注释: Health hazard & Environment
• 危险类别特定目标器官毒性-重复接触 类别2
  水生急性毒性 类别1
  水生慢性毒性 类别1
  致癌性 类别1B
  水生慢性毒性 类别4
• 警示词Warning(警告)
• 危险描述H373 |长期或反复接触可能损害器官.
  H400 |对水生生物毒性极大.
  H410 |对水生生物毒性极大并具有长期持续影响.
  H350 |可能致癌.
  H413 |可能对水生生物造成长期有害影响.
• 防范说明P260-P273-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xn,N
• 包装等级Ⅲ
• 安全声明24/25-36-26-61-60-37
• 危险类别码22-36/37/38-50/53-48/22
• WGK Germany1

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 2-Ethylanthraquinone 主要起始原料 2-(4-Ethylbenzoyl)Benzoic Acid
• 1151-14-0 = 84-51-5
  反应条件:1.1 1.5 H,260 - 280 °C
  标题:A Green Synthesis Of 2-Ethylanthraquinone From 2-(4'-Ethylbenzoyl)Benzoic Acid Over H-Beta Zeolite
  作者:Xu,Renshun; Et Al
  参考文献:Catalysis Letters 日期:2006 卷标:107(3-4) 页码:149-154]
  
  26708-04-3 = 84-51-5
  反应条件:1.1 Reagents: N-Bromosuccinimide,Sulfuric Acid Solvents: Tetrahydrofuran,Water1.2 Reagents: Sodium Bicarbonate1.3 Solvents: Ethyl Acetate
  标题:Facile Oxidation Of Fused 1,4-Dimethoxybenzenes To 1,4-Quinones Using Nbs: Fine-Tuned Control Over Bromination And Oxidation Reactions
  作者:Kim,Dong Wook; Et Al
  参考文献:Organic Letters 日期:2001 卷标:3(3) 页码:445-447]
  
  = 84-51-5
  反应条件:1.1 Catalysts: Silica (Sulfuric Acid Catalyst),Sulfuric Acid (Silica Catalyst) Solvents: Tetrahydrofuran; 65 Min,90 - 100 °C
  标题:Facile And Efficient One-Pot Synthesis Of Anthraquinones From Benzene Derivatives Catalyzed By Silica Sulfuric Acid
  作者:Naeimi,Hossein; Et Al
  参考文献:Polycyclic Aromatic Compounds 日期:2014 卷标:34(5) 页码:504-517]
  
  = 84-51-5
  反应条件:1.1 Catalysts: Citric Acid
  标题:Dehydration Of 2-(4'-Ethylbenzoyl)Benzoic Acid To 2-Ethylanthraquinone Over H-β Zeolite Impregnated With Citric Acid
  作者:Zhai,Lingjuan; Et Al
  参考文献:Cuihua Xuebao 日期:2008 卷标:29(8) 页码:701-704]
  
  839-73-6 = 84-51-5
  反应条件:1.1 Reagents: Oxygen Solvents: Mesitylene,Trioctyl Phosphate,Water; Rt
  标题:Pd/mgal-Ldh Nanocatalyst With Vacancy-Rich Sandwich Structure: Insight Into Interfacial Effect For Selective Hydrogenation
  作者:Miao,Chenglin; Et Al
  参考文献:Journal Of Catalysis 日期:2019 卷标:370 页码:107-117]
  
  839-73-6 = 84-51-5
  反应条件:1.1 Catalysts: Palladium Solvents: 1-Decanol; Overnight,Rt; 60 °C1.2 Reagents: Oxygen Solvents: 1-Decanol; 30 Min,Rt
  标题:Activation Of O2 By Organosilicon Reagents Yields Quantitative Amounts Of H2O2 Or (Me3Si)2O2 For Efficient O-Transfer Reactions
  作者:Yamamoto,Keishi; Et Al
  参考文献:Helvetica Chimica Acta 日期:2018 卷标:101(12)]
  
  15547-17-8 = 84-51-5 + 68279-54-9
  反应条件:1.1 Catalysts: Calcium Oxide,Manganese Oxide (Mno2),Alumina; 48 H,Rt
  标题:Catalytic Regeneration Of Ethylanthraquinone Working Solution By Cao And Mno2 Double Modified γ-Al2O3 Catalyst
  作者:Cheng,Yi; Et Al
  参考文献:Huaxue Fanying Gongcheng Yu Gongyi 日期:2018 卷标:34(5) 页码:431-439]
  
  1151-14-0 = 84-51-5
  反应条件:1.1 Catalysts: Citric Acid; 40 - 50 Min,256 - 258 °C
  标题:A Highly Effective Method For The Synthesis Of 2-Ethylanthraquinone
  作者:Xu,Ren-Shun; Et Al
  参考文献:Yingyong Huaxue 日期:2006 卷标:23(7) 页码:812-814]
  
  26708-04-3 = 84-51-5
  反应条件:1.1 Reagents: Bis(Trifluoroacetoxy)Iodobenzene Solvents: Methanol,Water
  标题:Novel And Efficient Synthesis Of P-Quinones In Water Via Oxidative Demethylation Of Phenol Ethers Using Hypervalent Iodine(Iii) Reagents
  作者:Tohma,H.; Et Al
  参考文献:Tetrahedron Letters 日期:2001 卷标:42(39) 页码:6899-6902]
  
  26708-04-3 = 84-51-5
  反应条件:1.1 Reagents: Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4) Catalysts: 4-Iodophenoxyacetic Acid Solvents: 2,2,2-Trifluoroethanol,Water; 2.0 H,Rt
  标题:Hypervalent Iodine Oxidation Of Phenol Derivatives Using A Catalytic Amount Of 4-Iodophenoxyacetic Acid And Oxone As A Co-Oxidant
  作者:Yakura,Takayuki; Et Al
  参考文献:Tetrahedron 日期:2010 卷标:66(31) 页码:5833-5840]
  
  62167-65-1 = 84-51-5
  反应条件:1.1 Reagents: Nitrous Oxide Catalysts: (Oc-6-12)-Dioxo[5,10,15,20-Tetrakis(2,4,6-Trimethylphenyl)-21H,23H-Porphinato(2-... Solvents: Benzene; 20 H,10 Atm,200 °C
  标题:Nitrous Oxide Oxidation Catalyzed By Ruthenium Porphyrin Complex
  作者:Tanaka,Hirotaka; Et Al
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:2004 卷标:77(10) 页码:1905-1914]
  
  62167-65-1 = 84-51-5
  反应条件:1.1 Reagents: Nitrous Oxide Catalysts: (Oc-6-12)-Dioxo[5,10,15,20-Tetrakis(2,4,6-Trimethylphenyl)-21H,23H-Porphinato(2-... Solvents: Benzene
  标题:Selective Nitrous Oxide Oxidation For C-H Oxidation And Aromatization Of 9,10-Dihydroanthracene Derivatives
  作者:Hashimoto,Kentaro; Et Al
  参考文献:Chemistry Letters 日期:2002 卷标:(6) 页码:582-583]
  
  15547-17-8 = 84-51-5
  反应条件:1.1 Reagents: Oxygen
  标题:Solvents For Hydrogen Peroxide Preparation By The Anthraquinone Process
  参考文献:European Patent Organization]
  
  839-73-6 = 84-51-5
  反应条件:1.1 Reagents: Oxygen; 15 - 20 Min,Rt
  标题:Role Of Phosphorus In The Formation Of Selective Palladium Catalysts For Hydrogenation Of Alkylanthraquinones
  作者:Belykh,Lyudmila B.; Et Al
  参考文献:Applied Catalysis 日期:2020 卷标:589]
  
  1296785-63-1 = 84-51-5 + 100-09-4
  反应条件:1.1 Solvents: Methanol,Water
  标题:The Solvent Effect On The Photodeprotection Of Anthraquinone Protected Carboxylic Acid Unravelled By Time-Resolved Spectroscopic Studies
  作者:Guo,Yan; Et Al
  参考文献:Physical Chemistry Chemical Physics 日期:2019 卷标:21(27) 页码:14598-14604

海关参考信息

• 2902600000-乙苯
  2912110000-甲醛
  2912210000-苯甲醛
  2914610000-蒽醌
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管