CAS: 7632-51-1; Vanadium(Iv) Chloride

该化合物是无机化合物,其特点是其黑色和黑色的暗色外观及其在合成基材料中作为前体的作用;它是共价化合物,其四面分子几何学显示,在+4氧化状态下,有;VCl4因其反应性而闻名,特别是水,水解作用,该化合物形成氧化物和盐酸;该化合物一般在空气中处理,因为它对湿气和空气敏感;它在有机合成中具有应用性,特别是在生产氧化物方面,并在各种化学反应中作为催化剂;此外,可被用于其他化合物的准备和材料科学领域;在与VCl4合作时,安全防范至关重要,因为接触时它具有腐蚀性和毒性;建议在冷干燥的地方适当储存,使用个人防护设备来减轻健康风险.

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REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

vanadium sodium chloride chlorine sulfurthionyl chloride vanadium(III) chloride bismuth antimony

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    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-2007074541-A1
    优先权日:2003-10-10
    标 题:Synthesis of germanium sulphide and related compounds
    发明人:BADDING JOHN V; HEWAK DANIEL W; HUANG CHUNG-CHE
    权利人:UNIV SOUTHAMPTON
    摘要:The invention relates to synthesis of germanium sulphide glasses and optical devices formed therefrom. In a chemical vapour deposition process, germanium tetrachloride is reacted with hydrogen sulphide at temperatures in the range 450-700° C. to form germanium sulphide. Lower temperatures within this range of 450-550° C. directly produce a glass, whereas higher temperatures within the range of 600-700° C. produce a crystalline powder which can then be reduced to a glass by subsequent melting and annealing. The reaction is preferably carried out at atmospheric pressure or slightly higher. Thin films and bulk glasses suitable for optical waveguides can be formed directly in one processing step as can powders and microspheres. The materials synthesised are of a high purity with low oxide impurities and only trace levels of transition metal ions.

    专利号:US-5166110-A
    优先权日:1989-12-22
    标 题 :Process for the synthesis of ziegler-type catalytic solids or solid constituents of the same
    发明人:BRUN CLAUDE
    权利人:ATOCHEM ELF SA
    摘要:A process is provided for the synthesis of a solid Ziegler catalyst or of a transition metal solid constituent thereof, which entails preparing the solid catalyst or constituent thereof as a suspension in an inert liquid medium by contacting precursors or ingredients of the catalyst or of the constituent in the inert liquid medium in one or more steps, and drying the suspension, and collecting the catalyst or constituent thereof; and wherein the process is conducted in a single multi-function reactor having a longitudinal axis and which can pivot around an axis which intersects perpendicularly with this axis.

    专利号:US-11607677-B2
    优先权日:2017-10-30
    标 题:Homogeneous and reusable superacid polymer catalyst useful for the synthesis of 5-hydroxymethylfurfural from glucose
    发明人:ALBA RUBIO ANA C; COLEMAN MARIA R; KALIDINDI SUBHASH; JOSHI ANUP S; OMODOLOR IBEH S
    权利人:UNIV TOLEDO; TJIE UNIV OF TOLEDO
    摘要:A superacid polymeric catalyst having both Lewis acidity and Brønsted acidity is described, along with methods of making and methods of using the same.

    专利号:US-5914388-A
    优先权日:1995-04-26
    标题:Synthesis polyphosphazenes with controlled molecular weight and polydisperity
    发明人:ALLCOCK HARRY R; MORRISSEY CHRISTOPHER T; MANNERS IAN; HONEYMAN CHARLES H; NELSON JAMES M; CRANE CHESTER A; REEVES SCOTT D; PRIMROSE A PAUL; HARTLE THOMAS J; PRANGE R
    权利人:PENN STATE RES FOUND
    摘要:A process for the preparation of polyphosphazenes is provided that includes the cationic solution polymerization reaction of a phosphoranimine, using a main group or transition metal halide, or other appropriate halide salt, including a linear phosphazene salt of any chain length, or a preformed non-phosphazene polymer containing a main or transition metal chloride, as an initiator. In a preferred embodiment, triarmed-star polyphosphazenes having the formula N{RN(H)R'2P-(N=PR'2)n}3 are prepared via this method. Also, a methods for synthesis of the monomer Cl3P=NSiMe3 and cyclic trimer N3P3X6 from the reactants N(SiR3)3 and PX5 are also described.
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    合成参考文献


    摘要:Kaminsky, W., Science of Synthesis, (2009) 48, 712.
    摘要:Daubert TE, Danner RP; Physical and Thermodynamic Properties of Pure Chemicals: Data Compilation. Design Institute for Physical Property Data, American Institute of Chemical Engineers. Hemisphere Pub Corp, New York, NY (1992)
    摘要:Bauer G et al; Vanadium and Vanadium Compounds. Ullmann's Encyclopedia of Industrial Chemistry 7th ed. (1999-2016). NY, NY: John Wiley & Sons. Online Posting Date: June 15, 2000
    摘要:USEPA/Office of Water; Federal-State Toxicology and Risk Analysis Committee (FSTRAC). Summary of State and Federal Drinking Water Standards and Guidelines (11/93) To Present
    摘要:NIOSH; Criteria Document: Vanadium p.102 (1977) DHEW Pub. NIOSH 77-222
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