CAS: 2244-21-5; Troclosene Potassium
该化合物是一种化学化合物,通常用作消毒剂和消毒剂和消毒剂,特别是在游泳池和水处理应用中;似乎是白色晶状粉,以其强烈氧化特性著称;该化合物在水中高度溶解,便于在各种水溶液中使用;溶解时释放氯,从而有效杀死细菌,病毒和藻类;此外,二氯硝酸钾在正常条件下稳定,但应该从热和不相容的材料中储存,以防止分解;必须谨慎处理该物质,因为它可能刺激皮肤,眼睛和呼吸系统;在环境影响方面,一般认为该物质对水生生物毒性较低,但仍需采取预防措施,防止过度释放到水体中;
- 英文名称Troclosene Potassium
- 中文名称曲氯新钾
- IUPAC名称1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3-dichloro-, potassium salt
- 其它别名1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3-dichloro-, potassium salt (9CI); s-Triazine-2,4,6(1H,3H,5H)-trione,1,3-dichloro-, potassium salt (8CI); s-Triazine-2,4,6(1H,3H,5H)-trione,dichloro-, potassium deriv. (7CI); ACL 59; Dichloro-s-triazine-2,4,6(1H,3H,5H)-trione potassium; Dichlorois°Cyanuric acidpotassium salt; Fluonon; Laitonon; Ne°Chlor 59; Potassium dichlor°Cyanurate; Potassium dichlorois°Cyanurate; Tr°Closene potassium
- CAS编号2244-21-5
- MFCD编号:MFCD00865980
- EINECS号:218-828-8
- FDA UNII编号:8A85D111P0
- 分子式:C3Cl2KN3O3分子量:236.055
- 产品CID: 1160752
- 同类组份化合物CAS2244-21-5 (potassium)2782-57-2 (free base)
- 产品分类有机原料 → 有机杂环化合物 → 三嗪类
物理性质
- 熔点250 °C
- 沸点306.7 °C at 760mmHg
- 闪点139.3 °C
- 密度0.96 at 20 °C (solid)
- PSA:66.0
- LogP:-1.5121
- 溶解性10 to 50 mg/mL at 63° F (NTP, 1992)
- 敏感性Contact with ammonium compounds or hydrated salts can cause a very vigorous reaction. Prolonged exposure to heat /fire may result in the vigorous decomposition of the material with the rupture of its containers, it will accelerate the burning of combustible materials. Chlorine plus alcohols would yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M. 1991].
- 外观形态白色,微吸湿性,晶体
- 储存条件Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
- 产品应用该化合物是假牙净化器,废水处理和医院的致感染剂.
MSDS等安全信息
- 危险类别Dust causes sneezing and coughing; is moderately irritating to the eyes and causes itching and redness of skin. Ingestion causes burns of mouth and stomach. (USCG, 1999)
- 警示词Danger
- 危险描述H272: May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]
H302: Harmful if swallowed [Warning Acute toxicity, oral]
H315: Causes skin irritation [Warning Skin corrosion/irritation]
H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]
H332: Harmful if inhaled [Warning Acute toxicity, inhalation]
H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard] - 防范说明P210, P220, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P330, P332+P317, P362+P364, P370+P378, P391, P403+P233, P405, and P501
- 危险等级5.1
- UN编号2465.0
- 包装等级II
- 危险类别码A strong oxidizer; Poses dangerous fire risk on contact with organic substances; [Hawley] A skin, eye, nose, and throat irritant; [HSDB] A strong oxidizing agent; May react with water producing chlorine gas; A moderate eye irritant; [CAMEO] A skin and eye irritant (heavy exposures may cause corrosive injury); Inhalation of very high concentrations may cause pulmonary edema; [CHEMINFO] An eye and respiratory tract irritant; [eChemPortal: ESIS] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis and pulmonary edema; Causes lacrimation and sneezing; [MSDSonline] See Sodium dichloroisocyanurate.
合成工艺路线路线简述
专利信息
专利号:US-2009198084-A1
优先权日:2006-05-02
标题:Process for the deprotection of protected amines
发明人：ALSTERS PAULUS LAMBERTUS; VERKADE JORGE MERIJN MATHIEU; QUAEDFLIEG PETER JAN LEONARD MARIO; RUTJES FLORIS PETRUS JOHANNES
权利人:ALSTERS PAULUS LAMBERTUS; VERKADE JORGE MERIJN MATHIEU; QUAEDFLIEG PETER JAN LEONARD MARIO; RUTJES FLORIS PETRUS JOHANNES
摘要:The present invention relates to a process for the deprotection of protected amine compounds, wherein the protected amine compound is contacted with an electrophilic oxidating agent that is optionally formed in situ, said electrophilic oxidating agent being selected from the group of I 2 , Br 2 , Cl 2 and compounds comprising a halogen atom having a formal oxidation state of 1+, 3+, 5+ or 7+, provided that the electrophilic oxidating agent is not iodobenzene diacetate. The process can be conveniently employed in the synthesis of 1,3-amino alcohols, β-amino acids and heterocyclic compounds, in particular β-amino acids.
专利号:US-9907753-B2
优先权日:2010-03-19
标 题 :Lipid vesicle compositions and methods of use
发明人：IRVINE DARRELL J; MOON JAEHYUN
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:The invention provides delivery systems comprised of stabilized multilamellar vesicles, as well as compositions, methods of synthesis, and methods of use thereof. The stabilized multilamellar vesicles may comprise prophylactic, therapeutic and/or diagnostic agents.
专利号:US-2014315720-A1
优先权日:2012-10-24
标 题 :Polysaccharide ester microspheres and methods and articles relating thereto
发明人：FALLON DENIS G; GARRETT THOMAS S; KIZER LAWTON E; ZAZZARA KAREN L; COMBS MICHAEL T; JOHNSON RICHARD K; DEHART GARY
权利人:CELANESE ACETATE LLC
摘要:A method for producing a polysaccharide ester microsphere may include forming a polysaccharide ester product from a polysaccharide synthesis, wherein the polysaccharide ester product comprises a polysaccharide ester and a solvent; diluting the polysaccharide ester product, thereby yielding a polysaccharide ester dope; and forming a plurality of polysaccharide ester microspheres from the polysaccharide ester dope. Suitable polysaccharides may include, but are not limited to, starch, cellulose, hemicellulose, algenates, chitosan, and any combination thereof. Esters thereof may be organic esters (e.g., acetate and the like), inorganic esters (e.g., sulfonates and the like), or combinations thereof. Further, the solids conent of the polysaccharide ester dope, in some instances, may be greater than about 16 wt %.
专利号:CN-101208345-B
优先权日:2005-05-25
标 题 :(S) -N-methylnaltrexone, method of synthesis and pharmaceutical use thereof
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Joshi LT, Welsch A, Hawkins J, Baillie L. The effect of hospital biocide sodium dichloroisocyanurate on the viability and properties of Clostridium difficile spores. Lett Appl Microbiol. 2017 Sep;65(3):199-205. doi: 10.1111/lam.12768. Epub 2017 Aug 6. doi: 10.1016/j.ijfoodmicro.2016.06.026. Epub 2016 Jun 23. doi: 10.1371/journal.pone.0156136. eCollection 2016.
5: Maffei DF, Sant'Ana AS, Monteiro G, Schaffner DW, Franco BD. Assessing the effect of sodium dichloroisocyanurate concentration on transfer of Salmonella enterica serotype Typhimurium in wash water for production of minimally processed iceberg lettuce (Lactuca sativa L.). Lett Appl Microbiol. 2016 Jun;62(6):444-51. doi: 10.1111/lam.12577. doi: 10.1007/s00284-016-1040-x. Epub 2016 Apr 16. doi: 10.1016/j.ajic.2016.01.044. Epub 2016 Mar 31. doi: 10.3382/ps/pew058. Epub 2016 Mar 4. doi: 10.1007/s10661-016-5147-0. Epub 2016 Feb 9. doi: 10.1016/j.anaerobe.2015.12.006. Epub 2015 Dec 18. doi: 10.1177/0885328215613666. Epub 2015 Nov 3. doi: 10.1080/09603123.2015.1089532. Epub 2015 Sep 25. doi: 10.1155/2015/412530. Epub 2015 Aug 3.
14: Jeong RD, Chu EH, Shin EJ, Lee ES, Kwak YS, Park HJ. Antifungal effect of gamma irradiation and sodium dichloroisocyanurate against Penicillium expansum on pears. Lett Appl Microbiol. 2015 Nov;61(5):437-45. doi: 10.1111/lam.12466. Epub 2015 Sep 24. doi: 10.4315/0362-028X.JFP-14-151. doi: 10.1093/jxb/eru167. Epub 2014 Apr 17.
合成参考文献
摘要:Toxicology of Drugs and Chemicals, Deichmann, W.B., New York, Academic Press, Inc., 1969, -(167), 1969
摘要:Yakkyoku. Pharmacy., 31(959), 1980
摘要:Monsanto Co. Toxicity Information., -(-), 1972
摘要:IATA. Dangerous Goods Regulations. 38th ed. Montreal, Canada and Geneva, Switzerland: International Air Transport Association, Dangerous Goods Board, January, 1997., p. 136
摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118
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