CAS: 115-28-6; 1,4,5,6,7,7-Hexachlorobicyclo[2.2.1]Hept-5-Ene-2,3-Dicarboxylic Acid

该化合物是一种氯化双环化合物,其内含诺本内核,具有两种碳本酸功能,其高度功能化的结构,包括六个氯替代体,使其成为有机合成的多功能中间体,特别是迪尔斯-阿尔德反应和阻燃剂或聚合变异剂的配制.该化合物的硬双环框架和电吸附组加强了其在循环和交叉相交过程中的再活动.其稳定性和高卤素含量还有助于需要热抗性或卤化添加剂的应用.双箱酸组进一步为量化化学修改提供了衍生.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-8815351-B2
    优先权日:2005-09-15
    标 题:Method for attachment of silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds
    发明人:OWENS JEFFREY R
    权利人:OWENS JEFFREY R; US AIR FORCE
    摘要:A method for attaching silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds is described. Attaching silicon-containing compounds to a surface comprises providing a silicon-containing compound having two or more leaving groups, and a first functional compound comprising at least one nucleophilic group, contacting the silicon-containing compound and the functional compound with a surface of a substrate having nucleophilic sites and exposing the silicon-containing compound, the functional compound and the surface of the substrate to microwave radiation.

    专利号:US-12263464-B2
    优先权日:2018-03-14
    标题 :Method for in-situ synthesis of metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolite imidazolate frameworks (ZIFs), and applications thereof
    发明人:PAHWA DEEPAK; PAHWA VARUN; CHOUDHARY ANIL KUMAR; SONIA; JHA VIVEK KUMAR; CHAUHAN ANJALI; YADAV ANNU
    权利人:DESICCANT ROTORS INTERNATIONAL PRIVATE LTD
    摘要:The present invention relates to a method for the in situ synthesis of of MOFs (metal organic frameworks), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), onto and within different types of porous substrates, and their applications. The present invention provides a unique and easy to utilize method by which a number of MOFs, COFs and ZIFs can be synthesized directly onto and within a porous substrate with high performance efficiency ensuring higher grammage in formation of adsorbent product onto and within the substrate.

    专利号:US-2022089618-A1
    优先权日:2019-01-29
    标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks
    发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M
    权利人:EXXONMOBIL RES & ENG CO
    摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.

    专利号:US-10737239-B2
    优先权日:2015-11-27
    标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks
    发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich
    权利人:BASF SE
    摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.

    专利号:US-9951095-B2
    优先权日:2014-05-16
    标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
    发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
    权利人:TEXAS A & M UNIV SYS
    摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

    专利号:US-2010093880-A1
    优先权日:2006-12-20
    标 题:Recycling cleavage of polyurethanes
    发明人:BERGFELD MANFRED; KIEFFER ANDREAS
    权利人:BERGFELD MANFRED; KIEFFER ANDREAS
    摘要:A process is described for splitting polyurethanes and polyurethaneureas, in which the polymer is first reacted with gaseous or liquid secondary aliphatic or cycloaliphatic amines, the secondary urea formed, after removal with hydrogen chloride, is split to the isocyanate, and the polyols or polyamines also formed in the reaction are worked up and purified. It is possible by the process according to the invention to work up polyurethanes, polyurethaneureas, etc., of any origin, and to break them down into the starting materials, specifically the isocyanates, polyols or polyamines, to form starting materials in very high quality, which can be reused for the synthesis of any polyurethanes or polyureas. The invention further provides for the preparation of secondary bis-ureas from polyurethanes or polyurethaneureas or/and ureas.
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    主要参考文献


    1: National Toxicology Program. Chlorendic acid. Rep Carcinog. 2011;12:94-5. Review. Update in: Rep Carcinog. 2004;11:III50-1. doi: 10.1016/j.chemosphere.2015.10.114. Epub 2015 Nov 14. doi: 10.1093/toxsci/kfs170. Epub 2012 May 12. Review.
    18: Neveu MJ, Hully JR, Paul DL, Pitot HC. Reversible alteration in the expression of the gap junctional protein connexin 32 during tumor promotion in rat liver and its role during cell proliferation. Cancer Commun. 1990;2(1):21-31.

    合成参考文献


    摘要:Chemicals Inspection and Testing Institute; Biodegradation and Bioaccumulation Data of Existing Chemicals Based on the CSCL Japan. Japan Chemical Industry Ecology - Toxicology and Information Center. ISBN 4-89074-101-1, p. 4-40 (1992)
    摘要:Hendrix PF et al; Chemosphere 12 (7-8): 1083 (1983)
    摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
    摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
    摘要:DHHS/National Toxicology Program; Eleventh Report on Carcinogens: Chlorendic Acid (115-28-6) (January 2005).
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