CAS: 57486-68-7; Methyl 2-Chlorophenylacetate

上下游产品

邻氯苯乙酸 2'-Chloro-Benzeneacetic Acid 2444-36-2
苯乙酸甲酯 Benzeneacetic Acid Methyl Ester 101-41-7
2-(2-氯苯基)乙酰胺 2-(2-Chlorophenyl)Acetamide 10268-06-1

苯乙酸甲酯置于sodium Persulfate,N-氯代丁二酰亚胺,三氟甲磺酸,Palladium Diacetate体系中,用 1,2-二氯乙烷 作为反应溶剂,化学反应 2.0H,以66%的收率获得产物2-氯苯乙酸甲酯
参考文献:区域和化学选择性c 弱配位的h氯化/缺电子芳烃的溴化和相对方向基团能力的研究
标题:区域和化学选择性c 弱配位的h氯化/缺电子芳烃的溴化和相对方向基团能力的研究
摘要:都是相对的:已经开发了一种实用而有效的pd Ii催化的区域和化学选择性氯化/溴化反应,可轻松合成各种芳族氯化物.该反应显示出优异的反应活性,非常好的官能团耐受性和高收率.进行了一项初步研究,以评估各种功能的相对指导能力.
DOI:10.1002/anie.201300176

专利信息

专利号:US-4426536-A
优先权日:1982-06-14
标 题:Synthesis of phenylacetic acid esters
发明人：ROBEY ROGER L
权利人:LILLY CO ELI
摘要:Esters of phenylacetic acids are prepared in a single step by hydrolysis of 2,2,2-trichloro-1-phenylethanes in inorganic basic media.

专利号:CN-110862372-B
优先权日:2019-12-03
标题:Synthesis of clopidogrel intermediate (S)-2-(2-thienylethylamino)-(2-chlorophenyl)-acetic acid methyl ester

专利号:WO-0002864-A1
优先权日:1998-07-10
标题:Precusors for pna-monomers
发明人：MARTENS JUERGEN; MAISON WOLFGANG; SCHLEMMINGER IMRE; WESTERHOFF OLE; GROEGER HARALD
权利人:MARTENS JUERGEN; MAISON WOLFGANG; SCHLEMMINGER IMRE; WESTERHOFF OLE; GROEGER HARALD
摘要:The invention is directed to compounds of formula (I) wherein A, B, D, E, X and Y are defined in the description. These compounds are useful precursors for the synthesis of monomers for Peptide Nucleic Acids (PNA).

专利号:US-2021093624-A1
优先权日:2019-09-26
标题:Chemical Synthesis of Clopidogrel Active Metabolites and Disulfide Conjugate Prodrugs

专利号:EP-0098058-A1
优先权日:1982-06-14
标 题 :Synthesis of phenylacetic acid esters

专利号:US-7153969-B2
优先权日:1997-10-06
标 题:Hydroxyacetic ester derivatives, preparation method and use as synthesis intermediates
发明人：BOUSQUET ANDRE; MUSOLINO ANDREE
权利人:SANOFI AVENTIS
摘要:Methyl (R)-2-(R 1 OSO 2 )-2-(2-chlorophenyl)acetates useful as intermediates in the preparation of methyl (S)-2(2-chlorophenyl)-2-(4,5,6,7-tetrahydrothieno[3,2-c]-5-pyridyl)acetate.