CAS: 7309-58-2; (S,E)-9-Hydroxy-10-Octadecen-12-Ynoic Acid

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      专利号:US-7176336-B2
      优先权日:2003-10-09
      标题 :Process for the synthesis of unsaturated alcohols
      发明人:MAUGHON BOB R; BURDETT KENNETH A; LYSENKO ZENON
      权利人:DOW GLOBAL TECHNOLOGIES INC
      摘要:A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.

      专利号:CA-2541263-A1
      优先权日:2003-10-09
      标 题:An improved process for the synthesis of unsaturated alcohols

      专利号:US-2005080301-A1
      优先权日:2003-10-09
      标 题:Process for the synthesis of unsaturated alcohols

      专利号:WO-2005040077-A2
      优先权日:2003-10-09
      标题 :An improved process for the synthesis of unsaturated alcohols

      专利号:JP-2007508300-A
      优先权日:2003-10-09
      标 题 :Improved synthesis of unsaturated alcohols.

      专利号:JP-4779121-B2
      优先权日:2003-10-09
      标题 :Improved synthesis of unsaturated alcohols.

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