- 英文名称2,4-Di-Tert-Butyl-6-(5-Chloro-2H-Benzo[d][1,2,3]Triazol-2-yl)Phenol
- 中文名称2,4-二叔丁基-6-(5-氯-2H-苯并[d][1,2,3]三唑-2-基)苯酚
- IUPAC名称2,4-di-tert-butyl-6-(5-chloro-2H-benzo[d][1,2,3]triazol-2-yl)phenol
- 其它别名2-(3,5-二叔丁基-2-羟苯基)-5-氯苯并三唑; 235二叔丁基2羟苯基5氯苯并三唑; Uv Absorber Uv-327
- CAS编号3864-99-1
- MFCD编号:MFCD00059706
- EINECS号:223-383-8
- FDA UNII编号:17TJE602RX
- 分子式:C20H24ClN3O
- 分子量:357.89
- 产品CID: 1398702
- 产品分类有机原料→分子砌块→芳杂环类化合物→其它芳杂环类化合物
物理性质
- 熔点150-153 °C
- 沸点469.2°C at 760 mmHg
- 闪点237.6±31.5 °C
- 密度1.2±0.1 g/cm3
- pKa:9.23±0.48(预测)
- PSA:50.94
- LogP:5.3745
- 折射率1.596
- 蒸汽压0.0±1.2 mmHg at 25°C
- 溶解性Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
- 敏感性常温常压下稳定,浅黄色粉末,能强烈地吸收300~400nm的紫外光
- 外观形态类白色至淡黄色固体
- 储存条件置于阴暗处,密封, 常温干燥保存
- 产品应用优良的光稳定剂,与抗氧剂并用有良好的协同作用.该品挥发性小,与树脂相溶性好,适用于聚丙烯,聚乙烯,聚甲醛及聚甲基丙烯酸甲酯等,特别适用于聚丙烯纤维.
- 性质描述淡黄色粉末.熔点157°C.溶于苯,甲苯,苯乙烯,甲基丙烯酸甲酯,环已烷和增塑剂,微溶于乙醇,酮,不溶于水.能强烈吸收300-400nm的紫外光.
欧盟法规
ECHA物质ECHA物质欧盟授权物质清单C&L通报REACH预注册欧盟候选物质清单上下游产品
CAS号78-92-2 仲丁醇 | CAS号94102-13-3 Phenol, 2-(5-ch... | CAS号52184-29-9 2-(2’-硝基-4’-氯苯偶... | CAS号82-05-3 苯并蒽酮 | CAS号75-07-0 乙醛 | CAS号84755-45-3 2-(6-chloro-1-o... | CAS号96-76-4 2,4-二叔丁基酚 | CAS号89-63-4 邻硝基对氯苯胺 | CAS号3846-71-7 紫外线吸收剂(UV-320)合成工艺路线路线简述
- 合成目标产物 2-(2'-Hydroxy-3',5'-Di-Tert-Butylphenyl)-5-Chlorobenzotriazole 主要起始原料 4,6-Di(Tert-Butyl)-2-[(4-Chloro-2-Nitrophenyl)Azo]Phenol
- (文献来源)合成步骤主要原料 4,6-Di(Tert-Butyl)-2-[(4-Chloro-2-Nitrophenyl)Azo]Phenol
2,4-二叔丁基苯酚置于盐酸,Sodium Hydroxide,葡萄糖,Sodium Dodecyl-Sulfate,锌体系中,用 乙醇 作为反应溶剂,化学反应 8.0H,反应生成 紫外线吸收剂 Uv-327
参考文献:Rosevear,Judi; Wilshire,John F. K.,Australian Journal Of Chemistry,1982,Vol. 35,# 10,P. 2089-2093
标题:Rosevear,Judi; Wilshire,John F. K.,Australian Journal Of Chemistry,1982,Vol. 35,# 10,P. 2089-2093
海关参考信息
- 2902600000-乙苯
2902700000-异丙基苯
2903919090-氯苯
2907121100-间甲酚 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2009318592-A1
优先权日:2005-10-11
标 题 :Process for the Synthesis of Amine Ethers
发明人:FREY MARKUS; BROENNIMANN VALERIE
权利人:CIBA GEIGY CORP
摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.
专利号:US-2007191516-A1
优先权日:2004-03-15
标题 :Process for the synthesis of amine ethers
发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.
专利号:US-2023047214-A1
优先权日:2020-02-03
标题:Methods for microwave synthesis of degradable polymers for drug delivery
发明人:MURATOGLU ORHUN K; ORAL EBRU; GRINDY SCOTT
权利人:MASSACHUSETTS GEN HOSPITAL
摘要:Provided herein are methods of making degradable, additive-blended polymeric materials using microwave radiation and catalysts. The methods can include incorporation of therapeutic materials into the polymeric materials. There also are provided polymeric materials made by the methods and medical devices comprising the polymeric materials made by the methods.
专利号:US-7402675-B2
优先权日:2000-05-26
标题 :Process for the synthesis of amine ethers from secondary amino oxides
发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
权利人:CIBA SC HOLDING AG
摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.
专利号:US-4207228-A
优先权日:1977-09-21
标 题:UV-Light-stabilized compositions containing substituted 1,5-diazacycloalkanes, novel compounds and synthesis thereof
发明人:LAI JOHN T; SON PYONG N
权利人:GOODRICH CO B F
摘要:Novel polysubstituted 1,5-diazacycloalkanes and polysubstituted 2-keto-1,5-diazacycloalkanes are powerful stabilizers for materials subject to ultraviolet (UV) light degradation, particularly for polyolefins. The cyclic compounds of this invention have (a) a fixed three-carbon bridge between the N1 and N5 atoms of the diaza ring, the remaining portion of the ring having a variable length bridge of two or more carbon atoms, (b) an N-adjacent carbon atom of the diaza ring is polysubstituted, that is, has two substituents which may be cyclizable. Compositions containing (a) the polysubstituted 1,5-diazacycloalkanes and polysubstituted 2-keto-1,5-diazacycloalkanes of this invention, and (b) prior art polysubstituted 1,5-diazacycloalkanes and polysubstituted 2-keto-1,5-diazacycloalkanes, exhibit excellent stability to UV light. A novel synthesis for preparing polysubstituted 2-keto-1,5-diazacycloalkanes is disclosed.
专利号:US-6417363-B1
优先权日:1997-12-04
标题 :Heterocyclyl ligand containing ruthenium and osmium catalysts
发明人:VAN DER SCHAAF PAUL ADRIAAN; MUEHLEBACH ANDREAS; HAFNER ANDREAS; KOLLY ROMAN
权利人:CIBA SC HOLDING AG
摘要:Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formulawherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groupswherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.