CAS: 3385-94-2; Trimethyl(Trimethylsilylsulfanyl)Silane

该化合物是一种含有有机合成和材料科学中广泛使用的含有有机硅的硫磺化合物,其关键优点包括作为硫转移剂的高度反应性,能够高效地进行硫化和硫化反应.三甲基硫化物组增强有机溶剂的稳定性和溶解性,便利在无水条件下进行处理.该化合物对于金属硫化物和铬化物材料的制作特别有用,因为精确的硫化物成分在其中至关重要.该化合物与敏感的次质和受控制的再活性相兼容,使得其在先进的合成应用中成为首选选择,包括半导体和纳米技术研究.建议在惰性条件下妥善储存,以保持其完整性.

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    专利信息


    专利号:US-7241399-B2
    优先权日:2000-09-08
    标题 :Synthesis of nanoparticles
    发明人:HAUBOLD STEPHAN; HAASE MARKUS; RIWOTZKI KARSTEN; WELLER HORST; MEYSSAMY HEIKE; IBARRA FERNANDO
    权利人:CT ANGEWANDTE NANOTECH CAN
    摘要:Methods for the preparation of inorganic nanoparticles capable of fluorescence, wherein the nanoparticles consist of a host material that comprises at least one dopant. The synthesis of the invention in organic solvents allows to gain a considerably higher yield compared to the prior art synthesis in water. All kinds of objects can advantageously be marked and reliably authenticated by using an automated method on the basis of a characteristic emission. Further, the size distribution of the prepared nanoparticles is nartower which renders a subsequent size-selected separation process superfluous.

    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:WO-2018020240-A1
    优先权日:2016-07-27
    标 题:Process for the synthesis of semiconductor nanocrystals
    发明人:HOU BO; CHA SEUNGNAM
    权利人:UNIV OXFORD INNOVATION LTD
    摘要:The invention relates to a process for the synthesis of semiconductor nanocrystals, comprising mixing a nonaqueous solution of a metal precursor with a solid-state chalcogen and reacting the resulting mixture at a temperature of about 90 °C or greater. In another aspect the invention relates to the use of a solid chalcogen in the heterogeneous synthesis of metal chalcogenide semiconductor nanocrystals. Semiconductor nanocrystals obtainable by the processes of the invention are further provided. In particular, nanocrystalline PbS or PbSe having a band gap of greater than 1.6 eV and/or a photoluminescence emission wavelength of about 440 to about 515 nm, and nanocrystalline ZnS or ZnSe having a photoluminescence emission wavelength of about 410 to about 430 nm, and solar cells comprising such nanocrystals, are provided.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:WO-2013057134-A1
    优先权日:2011-10-19
    标 题:Synthesis of semiconductor nanoparticles using metal precursors comprising non- or weakly coordinating anions
    发明人:BAHNMUELLER STEFAN; TIAN SUSAN; TIAN SHIZHE; HOHEISEL WERNER
    权利人:BAYER IP GMBH; BAYER SOUTH EAST ASIA PTE LTD
    摘要:The present invention relates to a method for the synthesis of semiconductor nanoparticles comprising elements of the groups IB, IIB, IIIA, IVA, VA or VIA of the periodic classification wherein the composition of the core nanoparticle is selected from the group consisting of IB-VIA, IIB-VIA, IIIA-VIA, IB-IIIA-VIA or IB-IIB-TVA-VIA, IIB-IIIA-VIA, IIB-TVA-VA or mixtures thereof, and at least one shell comprises elements of the groups IIB and VIA,, wherein in case the core composition is IIB-VIA the shell comprises at least a further element selected from the groups IB, IIIA, IVA or VA, using metal precursors comprising non- or weakly coordinating anions. It further relates to the consecutive process for the synthesis that includes first the preparation of a binary nanoparticle system then modified to make a ternary system which again can be further modified to make a quaternary system.

    专利号:US-RE48454-E
    优先权日:2013-03-14
    标题 :Continuous flow reactor for the synthesis of nanoparticles
    发明人:SCHUT DAVID M; NOVET THOMAS E; WILLIAMS GEORGE M
    权利人:SHOEI ELECTRONIC MAT INC
    摘要:A continuous flow reactor for the efficient synthesis of nanoparticles with a high degree of crystallinity, uniform particle size, and homogenous stoichiometry throughout the crystal is described. Disclosed embodiments include a flow reactor with an energy source for rapid nucleation of the procurors following precursors to form nucleates followed by a separate heating source for growing the nucleates. Segmented flow may be provided to facilitate mixing and uniform energy absorption of the precursors, and post production quality testing in communication with a control system allow automatic real-time adjustment of the production parameters. The nucleation energy source can be monomodal, multimodal, or multivariable frequency microwave energy and tuned to allow different precursors to nucleate at substantially the same time thereby resulting in a substantially homogenous nanoparticle. A shell application system may also be provided to allow one or more shell layers to be formed onto each nanoparticle.

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    合成参考文献


    参考文献:10.1088/0957-4484/21/10/105707
    摘要:Liu H, Liu Y, Wang Z, He P. Facile synthesis of monodisperse, size-tunable SnS nanoparticles potentially for solar cell energy conversion. Nanotechnology. 2010 Mar 12;21(10):105707. doi: 10.1088/0957-4484/21/10/105707.
    参考文献:10.3390/ijms12063888
    摘要:Vivero-Escoto JL, Huang YT. Inorganic-organic hybrid nanomaterials for therapeutic and diagnostic imaging applications. Int J Mol Sci. 2011;12(6):3888–927.
    参考文献:10.1007/s11671-008-9139-z
    摘要:Zhu C, Wang P, Wang X, Li Y. Facile Phosphine-Free Synthesis of CdSe/ZnS Core/Shell Nanocrystals Without Precursor Injection. Nanoscale Research Letters. 2008 Jun 24;3(6):213. doi: 10.1007/s11671-008-9139-z.
    参考文献:10.1007/s11671-007-9108-y
    摘要:Lin Y, Chen Y, Feng M, Yan A, Zhuang X. One-pot Synthesis of Soluble Nanoscale CIGS Photoactive Functional Materials. Nanoscale Research Letters. 2007 Dec 04;3(1):21. doi: 10.1007/s11671-007-9108-y.
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