- 英文名称[1,1'-Biphenyl]-4,4'-Dicarbonyl Dichloride
- 中文名称4,4'-联苯二乙酰氯
- IUPAC名称4-(4-carbonochloridoylphenyl)benzoyl chloride
- 其它别名4,4'-DIPHENYLDICARBONYL CHLORIDE; 4,4'-DIBENZOYL CHLORIDE; 4,4'-BIBENZOYL CHLORIDE; 4,4'-BIPHENYLDICARBONYL CHLORIDE; [1,1'-BIPHENYL]-4,4'-DICARBONYL DICHLORIDE; Biphenyldicarbonylchloride; BIPHENYL-4,4'-DICARBONYL CHLORIDE; 4,4''-BIPHENYLDICARBONYL CHLORIDE
- CAS编号2351-37-3
- MFCD编号:MFCD00058934
- EINECS号:219-085-2
- FDA UNII编号:39R3G8K3DU
- 分子式:C14H8Cl2O2
- 分子量:279.12
- 产品CID: 1177234
- 产品分类有机原料→材料科学→MOF有机配体→羧酸MOF配体
相似化合物
14002-51-8 66-98-8 3218-36-8欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号787-70-2 4,4'-联苯二甲酸 | CAS号79-37-8 草酰氯 | CAS号100-20-9 对苯二甲酰氯 | CAS号4342-61-4 二氯四甲基二硅烷 | CAS号613-33-2 4,4'-二甲基联苯 | CAS号30061-79-1 4,4'-bis-trichl... | CAS号792-74-5 联苯二甲酸二甲酯 | CAS号1591-30-6 4,4'-联苯二腈 | CAS号92-87-5 联苯胺 | CAS号98-07-7 三氯甲苯 | CAS号47230-38-6 4,4'-联苯二甲酸二乙酯 | CAS号66-98-8 4,4'-联苯二甲醛 | CAS号1667-12-5 4,4'-二羟甲基联苯 | CAS号4433-13-0 4,4'-二乙烯基联苯合成工艺路线路线简述
- 合成目标产物 4,4'-Biphenyldicarbonyl Chloride 主要起始原料 Oxalyl Chloride And Biphenyl-4,4'-Dicarboxylic Acid
- (文献来源)合成步骤主要原料 Oxalyl Chloride 和 Biphenyl-4,4'-Dicarboxylic Acid
4,4'-二甲基联苯置于chromium(Vi) Oxide,五氯化磷,三氯氧磷体系中,用 溶剂黄146 用作溶剂,化学反应 6.0H,反应生成4,4'-苯偶酰氯
参考文献:快速真空热解稳定的磷化氢.第16部分.共轭聚合物构建的模型研究
标题:快速真空热解稳定的磷化氢.第16部分.共轭聚合物构建的模型研究
摘要:一系列双(酰化物)与酰氯的反应已用于制备双(氧酰化物)11-15.同样,一系列简单的叶立德与双(酰氯)反应,生成具有异构体结构的双(氧酰)19-27.第一种类型的快速真空热解(fvp)导致ph 3 P挤出,而不是预期的ph 3 Po挤出,而第二种类型的六个实例确实在500oc的fvp压力下挤出ph 3 Po以获得双(炔烃)28.还已经制备了相应的双(三丁基phosph)的实例,但是使用逐步方法构建四(氧代酰)31的尝试是失败的.完全分配给出了其中的六个双(氧酰化物)的13 C NMR光谱.
Doi:10.1016/s0040-4020(99)00611-0
专利信息
专利号:US-8309655-B2
优先权日:2009-12-22
标题 :Methods for the preparation of a poly(arylene ether) polysiloxane multiblock copolymer, multiblock copolymers produced thereby, and associated compositions and articles
发明人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT
权利人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT; SABIC INNOVATIVE PLASTICS IP
摘要:A poly(arylene ether)-polysiloxane multiblock copolymer is prepared by the reaction of a hydroxy-diterminated poly(arylene ether), a hydroxyaryl-diterminated polysiloxane, and an aromatic diacid chloride. This synthesis overcomes disadvantages of known syntheses of poly(arylene ether)-polysiloxane block copolymers. The poly(arylene ether)-polysiloxane multiblock copolymer is useful for improving the melt processability of poly(arylene ether) compositions.
专利号:US-11511238-B1
优先权日:2021-07-20
标 题 :Composite covalent organic framework membranes
发明人:BIKSON BENJAMIN
权利人:Avanpore LLC
摘要:Disclosed is the preparation of composite fluid separation membranes based on poly (aryl ether ketone) (PAEK) polymers with the separation layer formed by a layer-by-layer reticular synthesis. The porous PAEK substrate is semicrystalline, exhibits a mesoporous surface structure, and is surface functionalized. The separation layer formed by the hierarchical layer-by-layer process is in the form of a covalent organic network integrally linked via covalent bonds to the functional groups of the substrate. The composite separation layer may be synthesized in situ in a preformed separation device on the surface of the PAEK substrate. Device configurations include flat sheet, spiral wound, monolith, and hollow fiber configurations with the hollow fiber configuration being preferred. Hollow fibers are formed from PAEK polymers with poly (ether ether ketone) and poly (ether ketone) particularly preferred. Composite PAEK membranes of the present invention are useful for a broad range of fluid separation applications.
专利号:US-2016032052-A1
优先权日:2014-08-01
标 题:Process for manufacturing polyamide
发明人:KATAYAMA TOSHIHIKO; OKADA JUN; KAWASAKI RITSUYA; UMEDA HIDEO
权利人:SUMITOMO BAKELITE CO
摘要:In one or a plurality of embodiments, a process for manufacturing polyamide, with a reduced use of an amide-based solvent in synthesis, is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) dissolving diacid dichloride in a non-amide-based organic solvent; (b) adding diamine to a solution obtained in the step (a) and reacting the diacid dichloride with the diamine so as to generate polyamide; and (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (b), at the same time of starting the step (b), or during the step (b).
专利号:US-2016075826-A1
优先权日:2014-09-11
标 题:Process for manufacturing polyamide
发明人:SUN LIMIN; ZHANG DONG; JING JIAOKAI; HARRIS FRANK W; OKADA JUN; KATAYAMA TOSHIHIKO; UMEDA HIDEO; KAWASAKI RITSUYA
权利人:AKRON POLYMER SYSTEMS INC; SUMITOMO BAKELITE CO
摘要:In one or a plurality of embodiments, a process for manufacturing polyamide without using PrO (propylene oxide) in synthesis is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) reacting diacid dichloride monomer with at least two kinds of diamine monomers in a solvent so as to generate polyamide; and (b) removing hydrochloric acid physically out of a reaction system, the hydrochloric acid being generated during the reaction in the step (a); or (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (a), at the same time of starting the step (a), or during the step (a), wherein at least one of the diamine monomers is a diamine monomer containing a carboxyl group, and the trapping reagent does not include propylene oxide.
专利号:US-2012305484-A1
优先权日:2011-06-03
标题 :Thermally Rearranged (TR) Polymers as Membranes for Ethanol Dehydration
发明人:FREEMAN BENNY D; PAUL DONALD R; CZENKUSCH KATRINA; RIBEIRO JR CLAUDIO P; BA CHAOYI
权利人:FREEMAN BENNY D; PAUL DONALD R; CZENKUSCH KATRINA; RIBEIRO JR CLAUDIO P; BA CHAOYI; UNIV TEXAS
摘要:Synthesis and use of a new class of polymeric materials with favorable separation characteristics for the dehydration of ethanol and other organic solvents is described herein. The thermally rearranged (TR) polybenzoxazole (PBO), polybenzimidazole (PBI) and polybenzothiazole (PBT) membranes of the present invention can be used for the dehydration of ethanol during processing to fuel grade biodiesel by either pervaporation or vapor permeation. The unique microstructure of the membranes provides excellent separation characteristics, and this, coupled with their inherent thermal and chemical stability, enables their usage in other separations, such as the dehydration of other organic solvents.