CAS: 1919-48-8; 2,4,6-Triphenoxy-1,3,5-Triazine

该化合物是一种有机化合物,其特征是三环结构,以2,4和6个位置替换为2,4和6个苯氧基组,该化合物因其稳定性和耐热性而闻名于热降解,因此适合各种应用,特别是在材料科学领域和聚合物中的一种潜在添加物,多个苯氧组的存在有助于其疏水性,增强其紫外线稳定性,这有利于需要轻度的用途.此外,由于结构内的共聚,2,4,6-三苯基-1,3,5-三氨展示了有趣的电子特性,可影响其与其他化学物种的再活动与互动,经常研究其在阻燃剂,涂层和塑料中作为稳定剂的潜在用途.应当参考安全数据,以便处理和接触准则,如任何化学物质一样,用于处理和接触.

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CAS号4403-07-0 2,2,2-(1,3,5-Tr...

合成工艺路线路线简述

    📜氰酸苯酯 反应 48.0H,反应生成2,4,6-三苯氧基-1,3,5-三嗪
    参考文献:尝试合成受阻的2,4,6-三芳氧基-S-三嗪:碳酸双(2,4-二叔丁基苯基)酯-晶体结构
    标题:尝试合成受阻的2,4,6-三芳氧基-S-三嗪:碳酸双(2,4-二叔丁基苯基)酯-晶体结构
    摘要:一些较少位阻2,4,6-三-芳氧基-小号-Triazines分别通过相应的酚的反应如用溴化氰(的brcn)的起始材料,以获得相应的arylcyanates合成,然后三聚.出乎意料的是,2,4-二-叔-丁基-1-Cyanatobenzene从2,4-二-衍生的叔丁基苯酚没有三聚但是,的确,得到双(2,4-二-叔丁基苯基)碳酸酯.2,4,6-三-芳氧基的结构小号-Triazines和双(2,4-二-叔丁基苯基)碳酸酯进行了表征通过ir,手段1 H,和13个c NMR波谱.还通过x射线晶体学研究了后者的结构.
    Doi:10.1002/jccs.201700335

    海关参考信息

    专利信息


    专利号:WO-2023250039-A1
    优先权日:2022-06-23
    标 题 :Recyclable and malleable thermosets enabled by activating dormant dynamic linkages
    发明人:ZHANG WEI; LEI ZEPENG
    权利人:UNIV COLORADO REGENTS
    摘要:The invention disclosed herein relates a novel class of alkyl- and/or aryl-linked crosslinked polymeric polycyanurate compounds and their methods of synthesis from alkoxy substituted triazines by reacting said alkoxy substituted triazines with diols. Further provided a method of synthesis of an alkyl-linked polyarylether monomer/network comprising reacting the alkoxy substituted phenyl derivatives having electron withdrawing group, with diols.

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    主要参考文献

    参考标题:Nickel‐catalyzed Synthesis Of N ‐(Hetero)Aryl Carbamates From Cyanate Salts And Phenols Activated With Cyanuric Chloride
    作者:Iman Dindarloo Inaloo,Mohsen Esmaeilpour,Sahar Majnooni,Ali Reza Oveisi |发布日期:2020.11.5
    摘要:One‐pot Synthesis Of N‐(Hetero)Aryl Carbamates Through The Reaction Between Alcohols And In‐situ Produced (Hetero)Aryl Isocyanates In The Presence Of A Nickel Catalyst. The Phenolic C−o Bond Was Activated Via The Reaction Of Phenol With Cyanuric Chloride (2,4,6‐trichloro‐1,3,5‐triazine (Tct)) As An Inexpensive And Readily Available Reagent. This Strategy Provides Practical Access To N‐(Hetero)Aryl Carbamates

    合成参考文献


    摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382.
    摘要:Schafer, E.W., Jr., et al. 1982. Effects of 77 chemicals on reproduction in male and female coturnix quail. Ecotox. Environ. Safety 6:149-156
    参考文献:10.1007/s10895-018-2235-2
    摘要:Wang X, Xu Y, Yang L, Lu X, Zou H, Yang W, Zhang Y, Li Z, Ma M. Synthesis, Spectra, and Theoretical Investigations of 1,3,5-Triazines Compounds as Ultraviolet Rays Absorber Based on Time-Dependent Density Functional Calculations and three-Dimensional Quantitative Structure-Property Relationship. J Fluoresc. 2018 Mar;28(2):707–23. doi: 10.1007/s10895-018-2235-2.
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