📜对三氟甲基苯乙烯置于双(乙腈)氯化钯(II),1-Hydroxytetraphenyl-Cyclopentadienyl(Tetraphenyl-2,4-Cyclopentadien-1-One)-μ-Hydrotetracarbonyldiruthenium(II),水,对苯醌体系中,用 甲醇,异丙醇 用作溶剂,化学反应 36.0H,以55%的收率获得1-[4-(三氟甲基)苯基]乙醇 参考文献:Formal Hydration Of Non-Activated Terminal Olefins Using Tandem Catalysts 标题:Formal Hydration Of Non-Activated Terminal Olefins Using Tandem Catalysts 摘要:使用pd(II)/ru(II)催化剂组合,成功实现了端烯向仲醇的高区域选择性和产率的水合反应.不论是乙烯基芳烃还是脂肪族烯烃,都能在低催化剂负载量(1 Mol%)下,利用这种串联催化体系轻松进行水合反应. Doi:10.1039/c3Cc48810A
专利号:US-2020384451-A1 优先权日:2017-09-05 标题:Phosphine free cobalt based catalyst, process for preparation and use thereof 发明人:BALARAMAN EKAMBARAM; MIDYA SIBA PRASAD; LANDGE VINOD GOKULKRISHNA 权利人:COUNCIL SCIENT IND RES 摘要:The present invention discloses a phosphine free cobalt based catalyst of formula (I) and a process for preparation thereof. The present invention further discloses a process for the synthesis of aromatic heterocyclic compounds of formula (II) and pyrazine derivative using the phosphine free cobalt based catalyst of formula (I).
专利号:CN-119819362-A 优先权日:2025-01-03 标题 :A photocatalyst for the efficient catalytic synthesis of halogenated aromatic hydrocarbons and its preparation method and application