CAS: 130669-74-8; (3As,5Ar,6Ar,6Bs)-4-Bromo-2,2-Dimethyl-3A,5A,6A,6B-Tetrahydrooxireno[2,3-G][1,3]Benzodioxole
该化合物是一种复杂的有机化合物,其独特的双环结构包含溴原子和二氧化物,具有独特的两环结构,含有一种溴原子和二氧化物.这种化合物具有多个立体特征,有助于其特定的三维配置,影响其再活动及其与生物系统的互动.溴分质的存在可以加强其电子动力特性,使其有可能用于各种合成应用.此外,氧化物(乙氧)功能表明,它可能参与环开反应,这在有机合成合成中具有重大作用.该化合物的结构性复杂性还可能具有特定的药理特性,从而引起对药化学的兴趣.
- 英文名称(3As,5Ar,6Ar,6Bs)-4-Bromo-2,2-Dimethyl-3A,5A,6A,6B-Tetrahydrooxireno[2,3-G][1,3]Benzodioxole
- 中文名称[3aS-(3aα,5aβ,6aβ,6bα)]-4-溴-3a,5a,6a,6b-四氢-2,2-二甲基环氧乙烷并[E]-1,3-苯并二茂
- 其它别名Oxireno[e]-1,3-benzodioxole,4-bromo-3a,5a,6a,6b-tetrahydro-2,2-dimethyl-, [3aS-(3aa,5ab,6ab,6ba)]-
- CAS编号130669-74-8
- MFCD编号:MFCD01863542
- 分子式:C9H11BrO3分子量:247.09
- 产品CID: 465632
- 产品分类化学试剂 → 有机试剂 → 环氧化物
物理性质
上下游产品
CAS号67-64-1 丙酮 | CAS号108-86-1 溴苯 | CAS号145107-27-3 [3aR-(3aα,5aβ,6... | CAS号87-89-8 肌醇合成工艺路线路线简述
📜(1R,2S,5R,6S)-3-Bromo-6-Iodo-1,2-O-Isopropylidenecyclohex-3-Ene-1,2,5-Triol置于sodium Hydroxide体系中,用 乙二醇二甲醚,水 用作溶剂,化学反应生成[3As-(3Aα,5Aβ,6Aβ,6Bα)]-4-溴-3A,5A,6A,6B-四氢-2,2-二甲基环氧乙烷并[e]-1,3-苯并二茂
参考文献:Selectivity In The Halohydroxylation Of Cyclohexadienediols
标题:Selectivity In The Halohydroxylation Of Cyclohexadienediols
摘要:The Halohydroxylation Of A Number Of Cyclohexadienediol Derivatives Has Been Investigated. The Selectivity Of The Reaction As A Function Of The Type Of Substituent On The Diene,Protecting Group Of The Diol Functionality,Halonium Donor,Medium Polarity,And Temperature Is Described. Best Selectivity Is Obtained For Iodohydrin Formation. The Course Of The Reaction For These Dienic Systems Is Heavily Dependent On Steric Factors. (C) 2007 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tet.2007.02.109
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905310000-1,2-乙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:The Synthesis Of Certain Phomentrioloxin A Analogues And Their Evaluation As Herbicidal Agents作者:Ehab S. Taher,Prue Guest,Amanda Benton,Xinghua Ma,Martin G. Banwell,Anthony C. Willis,Tobias Seiser,Trevor W. Newton,Johannes Hutzler |发布日期:2017.1.6
摘要:A Series Of 28 Analogues Of The Phytotoxic Geranylcyclohexentriol (−)-Phomentrioloxin A (1) Has Been Synthesized Through Cross-Couplings Of Various Enantiomerically Pure Haloconduritols Or Certain Deoxygenated Derivatives With Either Terminal Alkynes Or Borylated Alkenes. Some Of These Analogues Display Modest Herbicidal Activities, And Physiological Profiling Studies Suggest That Analogue 4 Inhibits
合成参考文献
摘要:Haufe, G., Science of Synthesis, (2005) 34, 357.
摘要:Bingham, M. J.; Greaney, M. F., Science of Synthesis, (2008) 36, 979.
摘要:McDonald, F. E., Science of Synthesis, (2008) 37, 158.
📝 需求与反馈
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