- ⚠️危险化学品目录(2015年版) 严重眼损伤/眼刺激,类别1
- 英文名称Tetrachlorophthalic Anhydride
- 中文名称四氯苯二甲酸酐
- IUPAC名称4,5,6,7-tetrachloro-2-benzofuran-1,3-dione
- 其它别名4,5,6,7-Tetrachloro-1,3-isobenzofurandione; Tetrachloro-1,2-benzenedicarboxylic acid anhydride
- CAS编号117-08-8
- MFCD编号:MFCD00005920
- EINECS号:204-171-4
- FDA UNII编号:76GLW0LBEK
- 分子式:C8Cl4O3
- 分子量:285.9
- 产品CID: 2508310
- 产品分类有机原料 → 羧酸类化合物及衍生物 → 羧酸酐的卤化,磺化,硝化或硝化衍生物
物理性质
- 熔点253-257 °C(文献)
- 沸点371.0±0.0 °C at 760 mmHg
- 闪点161.6±25.5 °C
- 密度1.9±0.1 g/cm3
- pKa:3.01[at 20 °C]
- PSA:43.37
- LogP:3.56
- 折射率1.656
- 蒸汽压0.0±0.8 mmHg at 25°C
- 溶解性Chloroform (Slightly, Heated), DMSO (Heated), Methanol (Slightly, Heated)
- 敏感性易受潮
- 外观形态白色至类白色薄片状物
- 储存条件存储低于 +30°C.
- 产品应用该品为反应型阻燃剂,可用于聚酯,环氧树脂,但效果不如四溴苯酐.四氯苯二甲酸酐也是农药(稻瘟酞),染料,药物,增塑剂,防火漆等有机合成的中间体.
- 性质描述无色针状结晶或粉末.熔点255°C(升华),沸点366°C(371°C).溶于二氧六环,难溶于醚,不溶于冷水,在热水中分解成四氯苯二甲酸.无气味.
欧盟法规
统一分类与标签REACH注册ECHA物质ECHA物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单上下游产品
CAS号85-44-9 苯酐 | CAS号632-58-6 四氯酞酸半水合物 | CAS号84333-99-3 3,4,5,6-Tetrach... | CAS号91-20-3 萘 | CAS号34973-71-2 Perchlor-bicycl... | CAS号84333-84-6 2,3,4,5,7,8-Hex... | CAS号7664-93-9 硫酸 | CAS号6310-29-8 Benzoic acid,2,... | CAS号31039-74-4 N-苯基四氯邻苯二甲酰亚胺 | CAS号33795-85-6 3,4,5,6-四氟-N-甲基... | CAS号30675-13-9 4,5,6,7-四氯茚满-1,3-二酮 | CAS号50-74-8 2,3,4,5-四氯苯甲酸 | CAS号90348-16-6 methyl 2,3,4,5-... | CAS号104517-34-2 N,N-dimethyl-2,... | CAS号42221-52-3 2,3,4,5-四氯苯甲酰氯 | CAS号4466-59-5 3,6-二氯邻苯二甲酸酐 | CAS号446-17-3 2,4,5-三氟苯甲酸 | CAS号2134-15-8 2',4',5',7'-Tet...合成工艺路线路线简述
- 合成目标产物 Tetrachlorophthalic Anhydride 主要起始原料 Phthalic Anhydride
- (文献来源)合成步骤主要原料 Phthalic Anhydride
3,4,5,6-四氯-1,2-苯二甲酸半水合物置于乙酸酐体系中,化学反应生成四氯苯二甲酸酐
参考文献:快速方便的微波辅助合成芳香族酰亚胺和 N-羟甲基酰亚胺
标题:快速方便的微波辅助合成芳香族酰亚胺和 N-羟甲基酰亚胺
摘要:摘要 报道了极其简单的高产率和快速微波辅助合成多种芳香族单亚胺和二亚胺以及单-和双-N-羟甲基亚胺.
Doi:10.1081/scc-120018768
海关参考信息
- 2906210000-苄醇
2912110000-甲醛
2912210000-苯甲醛
2915110000-甲酸 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2024024489-A1
优先权日:2020-11-20
标 题:Protected disaccharides, their process of preparation and their use in the synthesis of zwitterionic oligosaccharides, and conjugates thereof
发明人:MULARD LAURENCE; DHARA DEBASHIS; PFISTER HELENE; PAOLETTI JULIE; PHALIPON ARMELLE; GUERREIRO-INVERNO CATHERINE
权利人:PASTEUR INSTITUT
摘要:The present invention provides zwitterionic oligosaccharides, in particular fragments of the surface polysaccharides from Shigella sonnei and Shigella sonnei conjugates comprising them. The present invention also provides protected disaccharides, their process of preparation and their use in the synthesis of zwitterionic oligosaccharides, and conjugates thereof, the disaccharide repeating unit of Shigella sonnei being: (I)
专利号:US-7772439-B2
优先权日:2004-10-25
标题 :Amino or thiol linker building block for the synthesis of amino- or thiol-functionalized nucleic acids and methods of making and use thereof
发明人:WEISS PATRICK A; WEISS VIOLETTE Y; PITSCH STEFAN
权利人:OPERON BIOTECHNOLOGIES INC
摘要:An amino or thiol linker building block for the synthesis of amino or thiol functionalized amino acids and generally of the following structure: n nis provided. Such building block may be introduced in the 5′ end position of an amino acid under standard coupling conditions. Such building block allows in-line coupling control, “trityl-onâ€? purification, and solid support functionalization/derivatization. Such building block is a stable, solid compound and can therefore be easily handled. With the building block of the present invention, deprotection may be carried out under standard detritylation conditions.
专利号:WO-2009135600-A1
优先权日:2008-05-07
标题:Catalysts for the synthesis of polyurethanes
发明人:LINDNER STEFAN; BAHNMUELLER STEFAN; SCHMIDT AXEL; WEIKARD JAN; BUCHMEISER MICHAEL; BANTU BHASKER; FRIEDERICHS WOLFGANG; KRAUSE JENS; REITER STEPHAN
权利人:BAYER MATERIALSCIENCE AG; LINDNER STEFAN; BAHNMUELLER STEFAN; SCHMIDT AXEL; WEIKARD JAN; BUCHMEISER MICHAEL; BANTU BHASKER; FRIEDERICHS WOLFGANG; KRAUSE JENS; REITER STEPHAN
摘要:The invention relates to novel catalysts for the synthesis of polyurethanes, represented by general formula (I) or (II), or compounds obtained by reacting a metal salt of the metals magnesium, calcium, yttrium, lanthanum, titanium, zirconium, manganese, iron, cobalt, zinc, aluminium, tin, comprising an anion from the group fluoride, chloride, bromide, sulphonate, trifluoromethanesulphonate, methanesulphonate, benzolsulphonate, para-toluenesulphonate, carboxy-C1-C10-alkyl, carboxy-C3-C10-cycloalkyl, carboxy- C2-C10-alkenyl, C1-C10-alkoxy, acetylacetonate, trifluoroacetlyacetonate or hexafluoroacetylacetonate, with N-heterocyclic compounds of general structure I; or with N-heterocyclic compounds of general structure II; or with N-heterocyclic compounds of general structure III.
专利号:US-10829792-B2
优先权日:2017-03-21
标 题 :Biocatalytic synthesis of strained carbocycles
发明人:CHEN KAI; HUANG XIONGYI; KAN S B JENNIFER
权利人:CALIFORNIA INST OF TECHN
摘要:Provided herein are methods for producing products containing strained carbocycles, such as cyclopropene moieties and/or bicyclobutane moieties. The methods include combining an alkyne and a carbene precursor in the presence of a heme protein, e.g., a cytochrome P450, under conditions sufficient to form the strained carbocycle. Reaction mixtures for producing strained carbocycles are also described, as well as whole-cell catalysts comprising heme proteins and variants thereof for forming cyclopropenes, bicyclobutanes, and related products.
专利号:US-10336912-B2
优先权日:2014-08-01
标 题 :Methods for producing and using aqueous polyurethane/polyacrylate hybrid dispersions and use of said aqueous polyurethane/polyacrylate hybrid dispersions in coating agents
发明人:JAHNS EKKEHARD; MANGEL TIMO; ROESCH CHRISTINE; ROMANATO PAOLA; BURK YENI; PAKUSCH JOACHIM
权利人:BASF SE
摘要:The present invention provides an aqueous polyurethane (PU)-polyacrylate hybrid dispersion obtainable by free radical polymerization of at least one acrylate polymer (A1) in the presence of at least one polyurethane (P1), a process for preparing these aqueous polyurethane-polyacrylate hybrid dispersions, wherein said process comprises a) preparing an aqueous polyurethane dispersion and b) using the polyurethane dispersion thus prepared as raw material for the further synthesis of a polyacrylate dispersion, and the use of the hybrid dispersion thus obtained as binder in filled coating materials, particularly as a binder for flexible roof coatings.
专利号:WO-8503665-A1
优先权日:1984-02-15
标题:Synthesis of polyurethane products
发明人:HOSTETTLER FRITZ
权利人:PIRRI JAQUELYN P; HOSTETTLER FRITZ
摘要:Wide range of polyurethane products, e.g., cellular, dense elastomer, and integral skin microcellular products, obtained by the reaction of (a) a polyisocyanate compound, (b) a polyol, (c) optionally a chain extender and/or blowing agent with/without other known additives, (d) in the presence of a nonhydroxyl flow modifier characterized by carbon and hydrogen atoms, at least one and, generally, a plurality of oxyalkylene groups, and at least one urethane, $(1,5)omicronp. Several of the polyurethane products exhibit unique properties, e.g., foamed articles with capability to conduct static electricity, soft elastomers characterized by improved coefficient of friction, etc. Several classes of the flow modifiers are novel per se. The polyurethane products can be synthesized via the one shot or prepolymer process. Multipackage systems, in particular, two and three component systems are useful in molding operations, e.g., manufacture of shoe soles.