CAS: 875666-39-0; Cis-3,4-Dihydroxy-Beta-Ionone

英文名称Cis-3,4-Dihydroxy-Beta-Ionone
中文名称(3E)-4-[(3R,4S)-3,4-二羟基-2,6,6-三甲基-1-环己烯-1-基]-3-丁烯-2-酮
IUPAC名称(E)-4-((3R,4S)-3,4-dihydroxy-2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-one
其它别名Cis-3,4-Dihydroxy-β-Ionone; (3E)-4-[(3R,4S)-3,4-Dihydroxy-2,6,6-Trimethyl-1-Cyclohexen-1-Yl]-3-Buten-2-One; Cis-3,4-Dihydroxy-Beta-Ionone; 3-Buten-2-One, 4-[(3R,4S)-3,4-Dihydroxy-2,6,6-Trimethyl-1-Cyclohexen-1-Yl]-, (3E)-; 4-(3,4-Dihydroxy-2,6,6-Trimethylcyclohexen-1-Yl)But-3-En-2-One
CAS编号875666-39-0
MFCD编号:MFCD28100345
分子式:C13H20O3分子量:224.3
产品CID: 1883590
产品分类天然产物 → 倍半萜

相似结构搜索
InChIKey: FXRGLHAKDUTPCV-CYLBZQBVSA-N
InChI=1S/C13H20O3/c1-8(14)5-6-10-9(2)12(16)11(15)7-13(10,3)4/h5-6,11-12,15-16H,7H2,1-4H3/b6-5+/t11-,12+/m0/s1
计算化学: 氢键受体数3.0氢键供体数2.0可旋转键数2.0

MSDS等安全信息

警示词Warning
危险描述H302-
防范说明P280-P305+P351+P338-
安全声明H303+H313+H333

上下游产品

Komaroveside A
3α-Hydroxy-4α-(β-D-Glucopyranosyloxy)-5,7-Megastigmadien-9-One

合成工艺路线路线简述

1373886-90-8 = 875666-39-0
反应条件:1.1 Catalysts: Glucosidase,β- Solvents: Water; 7 D,37 °C
标题:Three New Megastigmane Glucopyranosides From Cardamine Komarovii
作者:Lee,Il Kyun; Et Al
参考文献:Chemical & Pharmaceutical Bulletin 日期:2011 卷标:59(6) 页码:773-777

📜3α-Hydroxy-4α-(β-D-Glucopyranosyloxy)-5,7-Megastigmadien-9-One置于水,β-Glucosidase体系中,化学反应 96.0H,以75%的收率获得产物(3E)-4-[(3R,4S)-3,4-二羟基-2,6,6-三甲基-1-环己烯-1-基]-3-丁烯-2-酮
参考文献:Bioactive Constituents From Chinese Natural Medicines. Xv. Inhibitory Effect On Aldose Reductase And Structures Of Saussureosides A And B From Saussurea Medusa
标题:Bioactive Constituents From Chinese Natural Medicines. Xv. Inhibitory Effect On Aldose Reductase And Structures Of Saussureosides A And B From Saussurea Medusa
摘要:水母雪莲 Maxim 全草的 80% 丙酮水溶液提取物.发现抑制大鼠晶状体醛糖还原酶(ic50=1.4 μg/ml).从该提取物中分离出类黄酮,木脂素和奎尼酸衍生物以及两种新的紫罗兰酮糖苷(雪莲苷 A 和 B).基于化学和物理化学证据(包括应用改良的 Mosher 方法)阐明了它们的绝对立体结构.此外,还发现一些分离株对醛糖还原酶表现出抑制作用.
DOI:10.1248/cpb.53.1416