CAS: 83324-51-0; 4-(2-((1S,4As,8As)-5,5,8A-Trimethyl-2-Methylenedecahydronaphthalen-1-yl)Ethyl)Furan-2(5H)-One

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上下游产品

(E)-3-Methyl-5-((1S,4aS)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalen-1-yl)-pent-2-enal (17),13-diene-15,16-diol(+)-(Z)-labda-8-(17),13-diene-15,16-diol Bestmann ylide 4-[2-((1S,4aS,8aS)-5,5,8a-Trimethyl-2-methylene-decahydro-naphthalen-1-yl)-ethyl]-3,6-dihydro-[1,2]dioxine

合成工艺路线路线简述

    📜(E)-Labda-8(20),12-Diene-15,16-Dial置于sodium Tetrahydroborate,Jones Reagent,对甲苯磺酸,1,8-二氮杂双环[5.4.0]十一碳-7-烯体系中,用 甲醇,二氯甲烷,丙酮 作为反应溶剂,化学反应 20.5H,反应生成 8(17),13-赖百当二烯-15,16-内酯
    参考文献:Sheeja,Alan D. B.; Nair,Mangalam S.,Indian Journal Of Chemistry-Section B Organic And Medicinal Chemistry,2014,Vol. 53,# 3,P. 319-324
    标题:Sheeja,Alan D. B.; Nair,Mangalam S.,Indian Journal Of Chemistry-Section B Organic And Medicinal Chemistry,2014,Vol. 53,# 3,P. 319-324

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    主要参考文献

    参考标题:Facile Access To Labdane-Type Diterpenes: Synthesis Of Coronarin C, Zerumin B, Labda-8(17), 13(14)-Dien-15,16-Olide And Derivatives From (+)-Manool
    作者:José E. Villamizar,José Juncosa,Jean Pittelaud,Madeleyn Hernández,Nieves Canudas,Eleonora Tropper,Franklin Salazar,Juan Fuentes |发布日期:2007.6
    摘要:The Synthesis Of Optically Active Labdane-Type Diterpenes From (+)-Manool 8, Is Described. We Prepared The Natural Labdane-Type Diterpene 5 Via Key Intermediate Peroxide 9 And Coronarin C 1, Compound 8 And Zerumin B 6 Via A Furan Photosensitised Oxygenation Reactions.

    合成参考文献

    参考DOI号:10.3184/030823407X225527
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