CAS: 4706-81-4; Tetradecan-2-Ol

相似化合物

2345-27-9 123-96-6 1653-30-1

上下游产品

laurylmagnesium bromide acetaldehyde dodecylmagnesium chloride tetradecan-2-one tetradecan-2-one 2-chlorotetradecane Caprinsaeure-2-tetradecylester Caprylsaeure-2-tetradecylester

📜Phenyl Tetradecan-2-Yl Telluride置于sodium Hydroxide,溴体系中,用 四氯化碳 作为反应溶剂,化学反应生成 2-十四醇
参考文献:碲氧化物消除的新方面:轻松消除导致烯烃,烯丙醇和烯丙醚的仲烷基苯基碲氧化物
标题:碲氧化物消除的新方面:轻松消除导致烯烃,烯丙醇和烯丙醚的仲烷基苯基碲氧化物
摘要:描述了碲氧化物用于烯烃合成的效用,该反应以前似乎没有什么价值.除环己基体系外,在室温下用 Naoh 水溶液处理仲烷基苯基二溴化碲,可以高产率地提供烯烃,烯丙醇和/或烯丙基醚,这可能是通过仲烷基苯基碲氧化物的形成和它们容易的碲消除而产生的.对于直链烯烃的形成,观测到比硒氧化物和亚砜消除更倾向于消除较少取代的碳.在环十二烷基的情况下,仅反式环十二烯形成为烯烃组分,与氧化硒消除形成鲜明对比,消除提供顺式和反式异构体的 1:1 混合物.相反,
DOI:10.1021/ja00347A039

专利信息

专利号:WO-2014108526-A1
优先权日:2013-01-11
标题 :Synthetic process for the manufacture of pipecolidepsin compounds
发明人：PELAY GIMENO MARTA; GARCÃ?A-RAMOS YESICA; TULLA PUCHE JUDIT; ALBERICIO PALOMERA FERNANDO; MARTÃ?N LÓPEZ M JES S
权利人:PHARMA MAR SA
摘要:(I) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , n and Y are as described. The invention provides a process for the synthesis of complex pipecolidepsin and related compounds of formula (I), opening a new field of compounds with useful biological properties. The invention also provides intermediates, useful in the synthesis of compounds of formula (I).

专利号:US-8178585-B2
优先权日:2007-11-14
标题 :Solvent-free synthesis of soluble nanocrystals
发明人：PETRUSKA MELISSA; PAN GUIQUAN
权利人:PETRUSKA MELISSA; PAN GUIQUAN; ADVANCED TECH MATERIALS
摘要:Methods for preparing high quality and high yields of nanocrystals, i.e., metal-oxide-based nanocrystals, using a novel solvent-free method. The nanocrystals advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents.

专利号:US-8329854-B2
优先权日:2010-09-27
标题 :Synthesis of tri-component resins
发明人：BIRAU MARIA; ALLEN C GEOFFREY
权利人:BIRAU MARIA; ALLEN C GEOFFREY; XEROX CORP
摘要:A resinous compound of the formulas or a salt thereof, wherein G1 is —X1C(O)OR1, —X2OC(O)R2, or —X2OH; G2 is R4, R12, —C(O)R2, —C(O)X1C(O)OR1, or —C(O)X2OC(O)R2; R1 is an alkyl having from 10 to 80 carbon atoms; R2 is an alkyl having from 2 to 40 carbon atoms; each R3 and R4 is independently hydrogen, alkyl, arylalkyl or alkylaryl; each R5 and each R6 is independently hydrogen or alkyl; X1 and X2 are both a straight or branched alkylene group; t1 is 1 to 20; t2 and t3 is independently 0 to 20; u1 is 1 to 30; u2 and u3 is independently 0 to 30; each R7 and each R8 is independently hydrogen, alkyl, or alkoxyl; each R9 and each R10 is independently hydrogen, alkyl, or alkoxyl; Ar is a substituted or unsubstituted aromatic moiety; p is 1 to 5; q is 1 to 12; A⊖ is selected from the group consisting of Cl−, Br−, I−, HSO4−, HSO3−, CH3SO3−, NO3−, HCOO−, CH3COO−, H2PO4−, SCN−, BF4−, ClO4−, SSO3−, PF6−, and SbCl6−; and J is alkyl, arylalkyl, or alkylaryl.

专利号:US-10017465-B2
优先权日:2014-08-12
标 题 :Method for producing astaxanthin from astacin
发明人：Schäfer Bernd; SIEGEL WOLFGANG
权利人:BASF SE
摘要:The invention relates to a method for the non-stereoselective and also for the stereoselective synthesis of astaxanthin from astacin. For this purpose, a reducing agent is used selected from the group of hydrogen, a secondary alcohol, formic acid and also the salts of formic acid or from a mixture of at least two representatives of the compound classes stated above. The invention further relates to the use of astacin as starting compound for the synthesis of astaxanthin.

专利号:JP-2012072137-A
优先权日:2010-09-27
标 题 :Synthesis of three-component resin

专利号:US-2012077953-A1
优先权日:2010-09-27
标 题:Synthesis of tri-component resins