CAS: 4526-07-2; 1,4-Bis(Trimethylsilyl)Buta-1,3-Diyne

相似化合物

6224-91-5 2975-46-4 62108-37-6

上下游产品

CAS号1066-54-2 三甲基硅基乙炔 | CAS号61210-52-4 trimethylsilyle... | CAS号75-77-4 三甲基氯硅烷 | CAS号87-68-3 六氯-1,3-丁二烯 | CAS号81952-80-9 三甲基硅基乙炔氯化镁 | CAS号703-55-9 1-萘基溴化镁 | CAS号16035-50-0 环己烯-d10 | CAS号2798-73-4 1-甲氧基-1-丁烯-3-炔 | CAS号73513-58-3 1,2-dichloro-4,... | CAS号110373-04-1 4-bromobuta-1,3... | CAS号20932-80-3 trimethyl-[1,1,... | CAS号6130-98-9 2,2,7,7-四甲基-3,5-辛二炔 | CAS号36333-41-2 1,4-dibromobuta... | CAS号16954-96-4 1,4-dideuteriob... | CAS号139033-11-7 methyl 4-oxo-8-... | CAS号886-66-8 1,4-二苯基丁二炔 | CAS号16900-51-9 1,4-DI-(2-THIEN... | CAS号71482-87-6 Isoxazole, 5-[(... | CAS号73084-25-0 lithium,buta-1,...

📜三甲基乙炔基硅置于四甲基乙二胺体系中,用 乙醇,水 作为反应溶剂,化学反应生成 1,4-双(三甲硅基)-1,3-丁二炔
参考文献:Tuning Of Cross-Glaser Products Mediated By Substrate-catalyst Polymeric Backbone Interactions
标题:Tuning Of Cross-Glaser Products Mediated By Substrate-catalyst Polymeric Backbone Interactions
摘要:通过调整催化剂骨架实现了交叉格拉瑟产物中的可调选择性.负责这一作用的相互作用被揭示.
DOI:10.1039/c9Cc08565C

专利信息

专利号:US-7605218-B2
优先权日:2004-02-03
标题:Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions
发明人：KELLER TEDDY M; KOLEL-VEETIL MANOJ K
权利人:US NAVY
摘要:A carborane-siloxane compound is provided having the repeat unit n nQ contains any of —SiR 2 —, —SiR 2 —O—, —C≡C—C≡C—, carboranyl, and U′. Each R and R′ is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, or mixtures thereof. Each U′ is derivable from hydrosilation of an alkenyl or alkynyl group. Each T is alkyl, aryl, alkylaryl, haloalkyl, haloaryl mixtures thereof, —(O—SiR′ 2 ) x H, or the repeat unit. Each x and x′ is a positive integer. The compounds may be made be reacting a carborane-siloxane precursor having unsaturated end groups with a siloxane crosslinker in the presence of a hydrosilation catalyst.

专利号:US-7153921-B2
优先权日:2004-02-03
标 题 :Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions
发明人：KELLER TEDDY M; KOLEL-VEETIL MANOJ K
权利人:US NAVY
摘要:A crosslinked polymer and process of making it are disclosed. A copolymer having at least one alkyne group, carborane group, and alkylsiloxane group is reacted with a siloxane crosslinker in a hydrosilation reaction. This produces a crosslinked polymer where the crosslink sites are reacted alkyne groups.

专利号:US-9790207-B2
优先权日:2015-09-04
标题 :Pan-genomic inhibitors of NS5A protein encoded by HCV, pharmaceutical compositions, intermediates for inhibitor synthesis, and their synthesis and application methods
发明人：IVACHTCHENKO ALEXANDRE VASILIEVICH; MITKIN OLEG DMITRIEVICH
权利人:IVACHTCHENKO ALEXANDRE VASILIEVICH; IVASHCHENKO ANDREY ALEXANDROVICH; SAVCHUK NIKOLAY FILIPPOVICH; ALLA CHEM LLC
摘要:Compound represented by formula 1: n nor a pharmaceutically acceptable salt, a hydrate, a crystalline form, or a stereoisomer thereof, wherein:n nR1 is hydrogen, tert-butoxycarbonyl,n n nwhere R11 is an optionally substituted C 1 -C 6 alkyl, an optionally substituted C 3 -C 6 cycloalkyl, or an optionally substituted C 1 -C 6 alkyloxy, and arrows (â†?) indicate the position of substituents attachment;n nR2 is hydrogen, halogen, or C 1 -C 4 alkyl;n nR3 is an optionally substituted aryl, an optionally substituted aryloxy, an optionally substituted arylsulfanyl, an optionally substituted arylamino, or an optionally substituted nitrogen hetaryl;n n n n n n n n n n n n n where R41 is an optionally substituted C 1 -C 6 alkyl, an optionally substituted C 3 -C 6 cycloalkyl, or an optionally substituted C 1 -C 6 alkyloxy; X is buta-1,3-diynylene or 1,4-phenylene; arrows (â†?) indicate the position of substituents attacment.

专利号:US-7238766-B2
优先权日:2004-02-03
标题 :Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions

专利号:US-2005171317-A1
优先权日:2004-02-03
标 题 :Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions

专利号:US-10787576-B2
优先权日:2015-04-30
标 题 :Method for the preparation of a coating comprising oligomeric alkynes
发明人：FRAUENRATH HOLGER; SCHRETTL STEPHEN; SCHULTE BJOERN; LETERRIER YVES
权利人:ECOLE POLYTECHNIQUE FED DE LAUSANNE EPFL EPFL TTO
摘要:The invention relates to a method for the preparation of a coating comprising at least one coating layer on a substrate, the method comprising the steps of a. providing monomers of the type R—(N) x -(L) m -(Câ•?C) n -(L′) o -(N′) y —R′, wherein R is a head moiety, R′ is a tail moiety, (C≡C) n is an oligoyne moiety, L and L′ are linker moieties, N and N′ independently are branched or unbranched optionally substituted C 1 -C 25 alkyl moieties optionally containing 1 to 5 heteroatoms, x, m, o, and y are independently 0 or 1, n is 4 to 12, and wherein the head moiety allows for an interaction with the surface of the substrate; b. bringing the monomers into contact with the substrate wherein the interaction of the head moieties of the monomers with the surface of the substrate induces at least a part of the monomers to align in a defined manner thereby forming a film on the surface and bringing the oligoyne moieties of the monomers into close contact with each other; c. inducing a reaction between oligoyne moieties by providing an external stimulus so as to at least partially cross-link the aligned monomers, thereby forming a coating layer on the substrate. The invention further relates to a coating obtainable according to the method of the invention, the use of a coating obtainable according to the method of the invention, a substrate comprising a coating obtainable according to the invention and the use of solid substrate. The invention further relates to a method for the synthesis ofthe monomers according to the invention.