CAS: 19529-00-1; Dihydridotetrakis(Triphenylphosphine)Ruthenium(Ii)

该化合物是的协调综合体,其特点是中央原子,与两只氢化和四只三苯硫素和4只三联苯硫协调,其特征是低氧化状态,在许多过渡金属复合体中,这是典型的,由于金属中心周围的和的协调,该产品具有平方平方形平面几何结构;三苯基苯丙基(三苯磷)(I)的存在有助于其稳定性和有机溶解性;二丁二丁基(三联磷)氮(一)经常研究其催化特性,特别是在氢化反应和涉及小分子的其他变异方面;其再活动可能受到磷的电磁性影响,使它成为有机金属化学和催化中的宝贵化合物;此外,氢丁丁基可以参与各种化学反应,进一步提高该化合物在合成应用中的效用.

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上下游产品

chlorohydridotris(triphenylphosphine)ruthenium(II) tert-butylatepotassium tert-butylate sodium tetrahydroborate ruthenium(III) chloride trihydratehydrid°Chlorotris(triphenylphosphine)ruthenium(II) carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) RuH(η5-°C6H5)(PPh3) (0)tricarbonylbis(triphenylphosphine)ruthenium(0)

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    专利信息


    专利号:US-2023212216-A1
    优先权日:2019-12-20
    标 题:Synthesis of lactone derivatives and their use in the modification of proteins
    发明人:MORRIS ALEXANDER REDFERN; SUTOV GRIGORIJ; BRUNE KARL DIETRICH
    权利人:GENIE BIOTECH UK LTD
    摘要:Site-specific modifications of proteins are desirable in biotechnological applications such as biopharmaceuticals, immunotherapy, vaccines, and are useful in chemical biology. Gluconoylation is a non-enzymatic, covalent, post-translational modification commonly observed on N-terminal His-Tags bearing proteins. We synthesized glucono-1,5-lactone derivatives, including azido variants for selective acylation. High yield acylation is achieved by simply mixing derivatives with target protein amidst diverse conditions of temperatures, aqueous buffers, excipients, or complex cell lysate.

    专利号:US-2022126276-A1
    优先权日:2020-10-26
    标题:Catalyst for ammonia synthesis and method for synthesizing ammonia using the same
    发明人:HARA MICHIKAZU; HOSONO HIDEO; HATTORI MASASHI
    权利人:TOKYO INST TECH
    摘要:The invention provides a catalyst for ammonia synthesis which has a high ammonia synthesis activity even at a low reaction temperature and a low reaction pressure and shows no decrease in the catalytic activity even when the synthesis reaction is repeated. The catalyst for ammonia synthesis comprises a metal supported material containing a transition metal and a support for supporting the transition metal. The support contains a metal hydride represented by XHn and an F ion. In the formula, X represents at least one kind selected from the group consisting of atoms of Group 2 and Group 3 of the periodic table, and lanthanoid atoms; and n represents a number represented by 2≤n≤3.

    专利号:US-9493494-B2
    优先权日:2014-05-30
    标题:Phosphinine oxide derivative and preparation method thereof
    发明人:LEE PHIL HO; PARK YOUNG CHUL; JEON IN CHEOL; SEO JUNG MIN; SEO BO RAM
    权利人:KNU INDUSTRY COOPERATION FOUND
    摘要:Provided are a novel phosphinine oxide derivative and a preparation method thereof, and more specifically, the phosphinine oxide derivative includes an oxaphosphinine oxide derivative and an azaphosphinine oxide derivative. n The phosphinine oxide derivative according to the present invention may have a pharmacological activity and a physiological activity, and may be used as a basic framework of a natural product and may be used for development of new drug and synthesis of various medical supplies. n In addition, according to the preparation method of the phosphinine oxide derivative according to the present invention, various phosphinine oxide derivatives with a high yield may be prepared by a simple synthesis process using an intramolecular annulation between a phosphinic derivative and an alkyne derivative in the presence of a rhodium (Rh) catalyst or a ruthenium (Ru) catalyst and an oxidant.

    专利号:EP-4076533-A1
    优先权日:2019-12-20
    标 题:Synthesis of lactone derivatives and their use in the modification of proteins

    专利号:US-10759668-B2
    优先权日:2015-11-10
    标题:Supported metal material, supported metal catalyst, and ammonia synthesis method using the same
    发明人:HOSONO HIDEO; HARA MICHIKAZU; KITANO MASAAKI; MIZOGUCHI HIROSHI; YOKOYAMA TOSHIHARU; YAMAGATA Kyosuke
    权利人:JAPAN SCIENCE & TECH AGENCY; TOKYO INST TECH
    摘要:The present invention provides a supported metal catalyst, a method for synthesizing ammonia using said catalyst, and a supported metal material in which a transition metal is supported on a support, wherein the support is a metal hydride represented by general formula (1): XH n . . . (1); and in general formula (1), X represents at least one selected from the group consisting of atoms from Groups 2 and 3, and lanthanoid atoms, and n is in a range of 2
    专利号:WO-2021123229-A1
    优先权日:2019-12-20
    标题:Synthesis of lactone derivatives and their use in the modification of proteins

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    合成参考文献

    合成方法参考DOI号:10.1021/ja961373w
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