CAS: 1928-38-7; Methyl 2-(2,4-Dichlorophenoxy)Acetate

该化合物其结构特征为2,4-二氯苯氧基混合物,与乙酸酯酯组有关,为衍生和中间过程提供了活性;该化合物在标准条件下具有稳定性,便于处理和储存;其酯功能允许选择性水解或进一步功能化,使它成为合成除草剂,植物生长调节器和其他特殊化学品的多用途前体;二氯苯氧基成分有助于其目标应用的功效,而甲基酯组则提高了有机溶剂的溶性,简化配方和反应工作流程.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

methanol 2,4-Dichlorophenoxyacetic acid methyl iodide 2,4-dichlorophenoxyacetic acid dimethylamineN-[(2,4-dichloro-phenoxy)-acetyl]-N-methyl-D-glucamineN-[(2,4-dichloro-phenoxy)-acetyl]-N-methyl-D-glucamine Bromo-(2,4-dichloro-phenoxy)-acetic acid methyl ester 2,4-dichlorophenoxythioacetamide 2,4-dichlorophenoxyacetylhydrazine

合成工艺路线路线简述

    📜油酸甲酯 以 水 用作溶剂,化学反应 730.5H,反应生成2,4-二氯苯氧乙酸甲酯
    参考文献:Manufacture And Use Of Herbicide Chlorinated Phenoxy Formulation
    标题:Manufacture And Use Of Herbicide Chlorinated Phenoxy Formulation
    摘要:本发明涉及一种方法,通过使用特定的溶剂和选定的表面活性剂,将氯代苯氧基除草剂与特定配方混合,以提高其活性.该方法需要使用烷基化脂肪酸酯和碱性缓冲剂.这种独特的组合已被证明可以在提供稳定配方的同时,降低氯代苯氧基除草剂的使用量.

    海关参考信息

    专利信息


    专利号:US-9999223-B2
    优先权日:2008-05-21
    标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
    发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).

    专利号:CN-106278862-A
    优先权日:2016-08-04
    标题 :A new process for the synthesis of 2,4-dichlorophenoxyacetic acid

    专利号:CN-118179061-A
    优先权日:2024-03-18
    标题:A system and method for continuous synthesis of 2,4-dichlorophenoxyacetic acid isooctyl ester

    专利号:US-10506809-B2
    优先权日:2015-01-15
    标 题:Herbicidal combination comprising saflufenacil and glufosinate
    发明人:MASSA DARIO; EVANS RICHARD; WITSCHEL MATTHIAS; SEISER TOBIAS; LIEBL REX; FRATESCHI ALEXANDRE
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal combination which comprises:n a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a herbicide B which is glufosinate or one of its salts, and c) at least one herbicide C different from herbicides A and B which is selected fromn C.1) herbicides of the group of acetolactate synthase inhibitors which are selected from the group of triazolopyrimidine herbicides, sulfonylamino-carbonyl-triazolinone herbicides and pyrimidinyl(thio) benzoate herbicides, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors which are selected from the group of oxyacetamide herbicides and chloroacetamide herbicides.

    专利号:CN-106242971-A
    优先权日:2016-08-04
    标 题 :A kind of aqueous phase synthesis technology of chloroacetate and its new method for preparing 2,4-D ester

    专利号:CN-106242971-B
    优先权日:2016-08-04
    标题:A kind of aqueous phase synthesis technology of chloroacetate and new method for preparing 2,4-D ester

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Gershater MC, Cummins I, Edwards R. Role of a carboxylesterase in herbicide bioactivation in Arabidopsis thaliana. J Biol Chem. 2007 Jul 20;282(29):21460-6. Epub 2007 May 22. Epub 2006 Oct 31.

    合成参考文献


    参考文献:10.1007/s00216-010-3493-2
    摘要:Pérez-Arribas LV, Manuel de Villena-Rueda FJ, León-González ME, Gonzalo-Lumbreras R, Polo-Díez LM. New approach to optimize HPLC separations of acid–base compounds with elution order involved, by using combined three-band resolution maps. Analytical and Bioanalytical Chemistry. 2010 Feb 13;396(7):2647–56. doi: 10.1007/s00216-010-3493-2.
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