CAS: 1576-95-0; Cis-2-Penten-1-Ol

相似化合物

13991-37-2 818-59-7 1576-87-0

上下游产品

CAS号6261-22-9 2-戊炔-1-醇 | CAS号6261-21-8 2-pent-2-ynylox... | CAS号16666-42-5 (Z)-戊-2-烯酸 | CAS号917-64-6 甲基碘化镁 | CAS号1576-93-8 反-4-氯巴豆醇 | CAS号74-83-9 溴甲烷 | CAS号113093-76-8 acetic acid,4-t... | CAS号930-22-3 3,4-环氧-1-丁烯 | CAS号676-58-4 甲基氯化镁 | CAS号33467-79-7 2,4-庚二烯-1-醇 | CAS号70979-88-3 2E, 4Z Heptadie... | CAS号488-10-8 顺茉莉酮 | CAS号50-00-0 甲醛 | CAS号123-38-6 丙醛 | CAS号141-46-8 羟乙醛 | CAS号107-02-8 丙烯醛 | CAS号760-20-3 3-甲基-1-戊烯 | CAS号56-82-6 DL-甘油醛 | CAS号4313-03-5 (E,E)-2,4-庚二烯醛

2-(Pent-2-Yn-1-Yloxy)Tetrahydro-2H-Pyran置于甲醇,Sodium Tetrahydroborate,氢气,Nickel(II) Acetate Tetrahydrate,乙二胺体系中,用 甲醇 用作溶剂,化学反应 28.0H,反应生成顺-2-戊烯醇
参考文献:通过同源混合物的组合合成构建挥发性化合物的化学文库:Alk-4-En-1-Ols,Alk-4-Enals 和 Methyl Alk-4-Enoates
标题:通过同源混合物的组合合成构建挥发性化合物的化学文库:Alk-4-En-1-Ols,Alk-4-Enals 和 Methyl Alk-4-Enoates
摘要:包含 66 个线性化合物的化合物库,六个分子家族的 11 个代表:( E )-和 ( Z )-Alk-4-En-1-Ols,Alk-4-Enals 和甲基 Alk-4-Enoates 的异构体,是通过组合合成制备的,以允许创建直接可用于在 Gc/ms 分析中识别它们的质谱数据库.我们在这里证明化合物库可以通过使用长线性合成序列的组合合成来制备,即.即,在 4-Enals 的情况下为八步.由此产生的同系物混合物仍然可以完美地用于提供所需的信息,例如干净的质谱和非常好的气相色谱保留指数.
Doi:10.1002/cbdv.202200817

专利信息

专利号:US-9096519-B2
优先权日:2013-01-10
标 题 :Process for the synthesis of ketones from internal alkenes
发明人：MORANDI BILL; GRUBBS ROBERT H; WICKENS ZACHARY K; LERCH MICHAEL M
权利人:CALIFORNIA INST OF TECHN
摘要:The present invention is directed to methods for oxidizing internal olefins to ketones. In various embodiments, each method comprising contacting an organic substrate, having an initial internal olefin, with a mixture of (a) a biscationic palladium salt; and (b) an oxidizing agent; dissolved or dispersed in a solvent system to form a reaction mixture, said solvent system comprising at least one C 2-6 carbon nitrile and optionally at least one secondary alkyl amide, said method conducted under conditions sufficient to convert at least 50 mol % of the initial internal olefin to a ketone, said ketone positioned on a carbon of the initial internal olefin. The transformation occurs at room temperature and shows wide substrate scope. Applications to the oxidation of seed oil derivatives and a bioactive natural product are described.

专利号:US-9150498-B2
优先权日:2011-10-25
标题:Process for the preparation of oseltamivir and methyl 3-epi-shikimate
发明人：RAWAT VARUN; DEY SOUMEN; ARUMUGAM SUDALAI
权利人:COUNCIL SCIENT IND RES
摘要:The present invention discloses high yielding enantioselective process for synthesis of Oseltamivir from readily available starting material, cis-1,4-butene diol. The process features incorporation of chirality using sharpless asymmetric epoxidation (AE) and diastereoselective Barbier allylation and construction of cyclohexene carboxylic acid ester core through a ring closing metathesis (RCM) reaction. Further also disclosed herein is synthesis of (−)-methyl 3-epi-shikimate.

专利号:US-5026918-A
优先权日:1990-04-27
标 题:Synthesis of 2,3,5-trisubstituted-2-cyclopentenones via base induced cyclization of alpha-chloro unsaturated ketones
发明人：MATHEW JACOB
权利人:PETROLITE CORP
摘要:2,3,5-trisubstituted-2-cyclopentenones or 2,3-disubstituted-2-cyclopentenones (such as cis-jasmone) are prepared by contacting a 3-chloro-3,4-disubstituted-4-pentene-2-one with a strong base. Methods of preparing the reactants are also disclosed.

专利号:US-9657030-B2
优先权日:2010-06-11
标 题 :Transition metal-catalyzed processes for the preparation of N-allyl compounds and use thereof
发明人：GIGUERE JOSHUA ROBERT; MCCARTHY KEITH EDWARD; REISCH HELGE ALFRED; SANDOVAL SERGIO; STYMIEST JAKE LARRY
权利人:RHODES TECH
摘要:The present disclosure provides processes for the N-dealkylation of tertiary amines and the use of transition metal catalysts to prepare tertiary N-allyl amine derivatives and secondary amine derivatives thereof. The tertiary amines can be alkaloids and, more particularly, the tertiary amines can be opioids. In specific embodiments, the present disclosure provides methods for use in processes for the synthesis of naloxone and naltrexone from oripavine.

专利号:US-7179918-B2
优先权日:2001-06-11
标 题:HIV protease inhibitors, compositions containing the same, their pharmaceutical uses and materials for their synthesis
发明人：CANAN KOCH STACIE S; ALEXANDER THERESE N; BURKE BENJAMIN J; JEWELL TANYA M; KUCERA DAVID J; LINTON MARIA ANGELICA; MITCHELL JR LENNERT J; REICH SIEGFRIED H; SKALITZKY DONALD J; TATLOCK JOHN H; VARNEY MICHAEL D; VIRGIL SCOTT C; WEBBER STEPHEN E; WORLAND STEPHEN T; BARVIAN MARK; BOLTON GARY; BOYER JR FREDERICK EARL; MACHAK JEFFREY J; HOLLER TOD; MURPHY SEAN T; MELNICK MICHAEL; JOSYULA VARA PRASAD
权利人:AGOURON PHARMA
摘要:Compounds of the formula: n nwhere the formula variables are as defined herein, are disclosed that advantageously inhibit or block the biological activity of the HIV protease. These compounds, as well as pharmaceutical compositions containing these compounds, are useful for treating patients or hosts infected with the HIV virus. Intermediates and synthetic methods for preparing such compounds are also described.

专利号:US-4207088-A
优先权日:1977-06-30
标题:Herbicidal 1,3-dioxanes
发明人：KONZ MARVIN J
权利人:FMC CORP
摘要:A new class of herbicidal compounds consisting of 1,3-dioxanes carrying substituents other than hydrogen in the 2-, 4-, 5-, and 6-positions of the dioxane ring exhibits preemergence and postemergence herbicidal activity, controlling effectively the growth of selected grassy species. The synthesis of members of this class is described in detail, and the utility of representative compounds in exemplified.