CAS: 283594-90-1; Spiromesifen

该化合物是一种化学化合物,被归类为杀虫剂和杀虫剂,主要用于农业用途,以控制各种作物的害虫;它属于被称为螺旋状环状物的化合物,其特点是独特的螺旋结构,有助于其生物活动; Spiromesifen通过抑制目标生物体中的脂肪生物合成,有效干扰其生长和繁殖; 众所周知,该化合物有选择性地针对特定害虫,同时尽量减少对有益昆虫和授粉者的影响; 它通常用作花生喷雾,对包括蜘蛛微粒和白虫在内的一系列害虫有效; Spiromesifen也因其对哺乳动物和鸟类的毒性相对较低,因此是综合虫害管理战略的一个更安全的选择; 此外,它具有中度的环境持久性,需要谨慎管理,以防止生态系统的潜在积累; 总的来说,Spiromeifen是现代农业的一个宝贵工具,有助于可持续的虫害控制做法.

结构式图片

欧盟法规

REACH注册ECHA物质欧盟农药活性物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号815-17-8 三甲基丙酮酸 | CAS号16841-19-3 1-羟基-环戊甲酸 | CAS号1070-83-3 3,3-二甲基丁酸 | CAS号5117-85-1 1-羟基环戊烷甲腈 | CAS号41248-23-1 1-乙氧羰基-1-环戊醇 | CAS号120-92-3 环戊酮

合成工艺路线路线简述

  • 合成目标产物 Spiromesifen 主要起始原料 3,3-Dimethylbutyryl Chloride And 4-Hydroxy-3-Mesityl-1-Oxaspiro(4.4)Non-3-En-2-One
  • (文献来源)合成步骤主要原料 3,3-Dimethylbutyryl Chloride 和 4-Hydroxy-3-Mesityl-1-Oxaspiro(4.4)Non-3-En-2-One
📜3,3-二甲基-1-丁酸置于氯化亚砜体系中,化学反应生成螺甲螨酯
参考文献:Spirodiclofen And Spiromesifen-Novel Acaricidal And Insecticidal Tetronic Acid Derivatives With A New Mode Of Action
标题:Spirodiclofen And Spiromesifen-Novel Acaricidal And Insecticidal Tetronic Acid Derivatives With A New Mode Of Action
摘要:广谱杀螨剂斯比羧菲(baj2740,商品名:Envidor®)和斯比菌酯(bsn2060,商品名:Oberon®)对烟粉虱有额外优异的活性,均属于拜耳作物科学在1990年代发现的新化学类别--四酮酸衍生物.从除草剂ppo(原卟啉原氧化酶)化学开始的发现过程,导致产品的合成路线,以及对中间体的过程开发的一些见解.斯比羧菲和斯比菌酯具有新的作用方式(干扰脂质生物合成),不对任何抗性螨虫或烟粉虱野外种群产生交叉抗性,因此是抗性管理的宝贵工具.
Doi:10.2533/000942903777678588

海关参考信息

专利信息


专利号:EP-4353356-A1
优先权日:2022-10-14
标题:Bifunctional catalyst formulation for synthesis of dimethylether (dme) from waste carbon dioxide and hydrogen by one-step and the synthesis method thereof
发明人:SEKER EROL; ZAHIDOVA AYSEL; MUTLU VAHIDE NURAN; DELIISMAIL OZGUN; SARRAFI SAHIN; TUNCER BASAK
权利人:SOCAR TURKEY ARASTIRMA GELISTIRME VE INOVASYON A S; IZMIR YUKSEK TEKNOLOJI ENSTITUSU REKTORLUGU
摘要:This invention relates to bifunctional catalyst formulation for synthesis of dimethyl-ether (DME) from waste carbon dioxide (CO2) and hydrogen (H2) and the preparation method of this catalyst formulation. In the preparation method, aluminum oxide-silicon dioxide-copper oxide (Al2O3-SiO2-CuO) catalyst mixture formulation is obtained by using the sol-gel method. The catalysts that are the subject of the invention are bifunctional and perform the synthesis of DME from CO2 and H2 in a single-step without forming unwanted byproduct of CH4, and thus, the synthesis of DME can be done much simply and economically. In addition to this, the sol-gel method in the current invention yields the controlled crystallite size of the active component in the catalysts; thus, the active site loss problem due to uncontrolled growth of crystal sizes that occurs in traditional preparation methods is prevented. The catalyst mixture formulation weight percentages are 10%-90% Al2O3, 10%-90% SiO2 and 10%-90% CuO.

专利号:US-2022298136-A1
优先权日:2019-08-21
标题 :Process for synthesis of pyrazolidinone compounds
发明人:MATHUR SUCHET SARAN; JAIN NANDKUMAR JANARDAN; MORE MAHENDRA MAHIPAT
权利人:GHARDA CHEMICALS LTD
摘要:A process for the synthesis of pyrazolidinone, particularly alkyl 2-(3-chloropyridin-2-yl)-5-oxo-pyrazolidine-3-carboxylate (pyrazolidinone) compound, is provided. The process is simple, economical, and produces alkyl 2-(3-chloropyridin-2-yl)-5-oxo-pyrazolidine-3-carboxylate with a comparatively high yields.

专利号:EP-1431274-B1
优先权日:2002-12-18
标题 :Synthesis of mono-N-substituted functionalized anilines
发明人:SELVA MAURIZIO; TUNDO PIETRO
权利人:CONSORZIO INTERUNIVERSITARIO N
摘要:The present invention relates to a process for direct and selective synthesis of mono-N-substituted functionalized anilines by using alkylating agents selected from the class of organic carbonates, preferably of the dialkyl, dibenzyl and diallyl types, in the presence of suitable catalysts that are chemically related to the class of aluminosilicates.

专利号:US-11008285-B2
优先权日:2017-03-27
标 题 :Process for synthesis of mesotrione
发明人:GHARDA KEKI HORMUSJI; MATHUR SUCHET SARAN; JAIN NANDKUMAR JANARDAN; SATHE SHEKHAR VISHWANATH; DAMANIA PRAGNESH DALPATRAM
权利人:GHARDA CHEMICALS LTD
摘要:The present disclosure relates to a process for synthesis of mesotrione. The process comprises reacting 4-toluene sulfonyl chloride with alkali metal sulphite and alkali metal bicarbonate to obtain alkali metal toluene-4-sulfinate. The alkali metal toluene-4-sulfinate is reacted with alkali metal salt of monochloroacetic acid to obtain 4-methylsulfonyl toluene. Further, 4-methylsulfonyl toluene is nitrated to obtain 2-nitro-4-methylsulfonyl toluene. 2-nitro-4-methylsulfonyl toluene is oxidized and then halogenated to obtain 2-nitro-4-methylsulfonylbenzoyl halide. 2-nitro-4-methylsulfonylbenzoyl halide is reacted with alkali metal salt of 1,3-cyclohexanedione to obtain 3-(2-Nitro-4-methylsulfonylbenzoyloxy)cyclohexen-1-one which is reacted with base, a third fluid medium and cyanide ion source to obtain an amorphous mesotrione. The present disclosure also discloses the steps of converting the amorphous mesotrione to crystalline mesotrione having purity greater than 99%. The process of the present disclosure for preparing mesotrione is rapid, economic, and environment friendly.

专利号:US-2005175774-A1
优先权日:2004-02-09
标题:Synthesis of inverted titania photonic crystal
发明人:EXIR JULIA
摘要:A novel method was devised to synthesis an inverted titania crystal on a substrate. At first, a film of surfactant sodium dodecylsulfate (SDS) polystyrene spherical particles was grown on a substrate using Colvin method. Surfactant sodium dodecylsulfate (SDS) stabilizes polystyrene particles and induces necking between the polystyrene particles. Next, the film was dropped inside a Falcon tube that half-filled with a solution comprising Titanium Isopropoxide (TiPT) or Titanium ethoxide (TEOT) diluted with anhydrous ethanol. Then, the Falcon tube was rotated in a centrifuge machine set at 1200-3600 rpm. After 30 minutes the film was removed from the tube and placed inside an anti-static plastic container. The film was stored inside the container for at least 6 hours. This was repeated many times depending on the dilution of the precursor solution (the more diluted the precursor the more the repetition) to fill up voids among the polystyrene colloidal particles. At last, the film was placed inside a tube furnace under airflow with a predetermined ramping temperature setting to remove the polystyrene template and to crystallize titania to its anatase or rutile form. At this stage titania is transformed into a crystalline form. The result of this method is a stable and well-structured inverted titania photonic crystal on a substrate.

专利号:US-2017198027-A1
优先权日:2012-01-31
标 题:Process of afod and afcc and manufacturing and purification processes of proteins
发明人:HOANG KIEU
权利人:HOANG KIEU
摘要:Manufacturing and purification processes of proteins, KH 1-through KH-52, and more KH proteins are being discovered in good healthy cells—named KH CELLS. KH CELLS are good healthy cells in which the RNA synthesizes good proteins that: 1) Send signal to the damaged, sick, and bad cells that triggers that synthesis of good proteins that transform these cells to become GOOD healthy cells; 2) Send signal to the other currently undamaged cells to synthesis of good proteins to protect them from being damaged, infected and prone to DNA and other cellular alterations; and 3) Send signal to the body to produce new cells that are healthy and forbid them from being affected by intra- and extracellular damaging signals. The mechanism that governs these processes is that the KH good healthy cells provide innate good signals that make good proteins to boost the immune system.

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品牌试剂参考报价(招募中)

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主要参考文献


1: Prabhaker N, Naranjo S, Perring T, Castle S. Comparative Toxicities of Newer and Conventional Insecticides: Against Four Generalist Predator Species. J Econ Entomol. 2017 Sep 27. doi: 10.1093/jee/tox202. [Epub ahead of print] doi: 10.1007/s11356-017-9954-9. Epub 2017 Aug 29. doi: 10.1002/ps.4639. Epub 2017 Aug 9. doi: 10.1002/ps.4571. Epub 2017 May 11. doi: 10.1007/s11356-017-8589-1. Epub 2017 Feb 22. Epub 2016 Aug 17. doi: 10.1016/j.vetpar.2016.05.019. Epub 2016 May 17. doi: 10.1111/jfd.12463. Epub 2016 Apr 1. doi: 10.1016/j.foodchem.2016.01.143. Epub 2016 Feb 1. doi: 10.1007/s10661-016-5165-y. Epub 2016 Feb 11. doi: 10.1603/EC14234. doi: 10.1093/jee/tov206. Epub 2015 Jul 16. doi: 10.1093/jee/tov181. Epub 2015 Jul 1. doi: 10.1016/j.pestbp.2014.12.014. Epub 2014 Dec 17. doi: 10.1007/s10493-015-9903-6. Epub 2015 Apr 12. doi: 10.1016/j.chroma.2015.03.032. Epub 2015 Mar 23. doi: 10.1007/s10661-014-4207-6. Epub 2015 Jan 24. doi: 10.1111/1744-7917.12190. Epub 2015 Jan 29.

合成参考文献


摘要:40 CFR 180.607(b) (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of January 4, 2011:
摘要:USEPA/Prevention, Pesticides, and Toxic Substances; Citizen's Guide to Pest Control and Pesticide Safety p.22 (March 2005) EPA 730-K-04-002
摘要:40 CFR 180.607(a) (2) (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of January 4, 2011:
摘要:National Pesticide Information Retrieval System's USEPA/OPP Chemical Ingredients Database on Spiromesifen (283594-90-1). Available from, as of January 5, 2011:
摘要:USEPA; Spiromesifen Human Health Risk Assessment. Document ID: EPA-HQ-OPP-2007-0331-0004. p.44 (December 20, 2007). Available from, as of February 2, 2011: https://www.regulations.gov/#!home
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