CAS: 25161-91-5; Loline
该化合物是* * 的草种中,是一种藻类,是被称为藻类的化合物的一部分,其特点是复杂的双环结构;Loline展示了一系列生物活动,包括潜在的杀虫性能,这可作为生产这种植物的植物的自然防御机制;该化合物一般没有色色,可粉黄,在有机溶剂中可溶解;其结构包括氮原子,有助于其基本性和与生物系统的潜在互动;Loline及其衍生物由于对草药和虫害管理的潜在应用的影响,因此对农业和制药研究产生了兴趣;此外,研究表明,线在...
- 英文名称Loline
- 中文名称(2R,3R,3aS,4S,6aS)-六氢-N-甲基-2,4-甲桥-4H-呋喃并[3,2-b]吡咯-3-胺
- IUPAC名称(1S,6R,7R,7aS)-N-methylhexahydro-1H-1,6-epoxypyrrolizin-7-amine
- 其它别名2,4-Methano-4H-furo[3,2-b]pyrrol-3-amine,hexahydro-N-methyl-, [2R-(2a,3a,3ab,4a,6ab)]-; 2,4-Methano-4H-furo[3,2-b]pyrrole, hexahydro-3-(methylamino)- (7CI); Loline(6CI,8CI); (+)-Loline; Festucine
- CAS编号25161-91-5
- MFCD编号:MFCD01754778
- FDA UNII编号:IC997T2WZ9
- 分子式:C8H14N2O分子量:154.212
- 产品CID: 1208950
物理性质
- 沸点103 °C(压力: 5 Torr)
- 闪点94.5°C
- 密度1.20±0.1 g/cm3(预测)
- pKa:9.36±0.20(预测)
- LogP:-0.4
- 折射率1.573
- 外观形态固体-粉末
- 储存条件Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
- 产品应用该化合物是一种天然的杀虫药,抑制了广泛的昆虫,包括七虫,科洛普特拉,希门托特拉,莱皮多特拉和布拉托德的物种. LOLINE抑制了鸟类樱桃虫(GENUS RHOPALOSIPHUM),大型牛奶丝虫(ONCOPELTUS FASCIATUS)和美国蟑螂(PERIPLANETA AMERICANA)等物种,从而保护宿主植物免受昆虫菌害.
MSDS等安全信息
合成工艺路线路线简述
海关参考信息
- 2905122000-异丙醇
2909110000-乙醚
2921211000-乙二胺
2922110001-单乙醇胺 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:JP-2001503782-A
优先权日:1996-11-22
标题 :Method and compound for inhibiting release of beta-amyloid peptide and / or its synthesis
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品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Adhikari KB, Boelt B, Fomsgaard IS. Identification and Quantification of Loline-Type Alkaloids in Endophyte-Infected Grasses by LC-MS/MS. J Agric Food Chem. 2016 Aug 10;64(31):6212-8. doi: 10.1021/acs.jafc.6b02616. Epub 2016 Aug 2. doi: 10.1016/j.fct.2016.06.002. Epub 2016 Jun 6. doi: 10.1093/jee/tou058. Epub 2015 Feb 4. doi: 10.1021/jo502493e. Epub 2015 Jan 22. doi: 10.1371/journal.pone.0115590. eCollection 2014.
6: Pan J, Bhardwaj M, Faulkner JR, Nagabhyru P, Charlton ND, Higashi RM, Miller AF, Young CA, Grossman RB, Schardl CL. Ether bridge formation in loline alkaloid biosynthesis. Phytochemistry. 2014 Feb;98:60-8. doi: 10.1016/j.phytochem.2013.11.015. Epub 2013 Dec 26.
7: Roberts E, Lindow S. Loline alkaloid production by fungal endophytes of Fescue species select for particular epiphytic bacterial microflora. ISME J. 2014 Feb;8(2):359-68. doi: 10.1038/ismej.2013.170. Epub 2013 Oct 10.
合成参考文献
参考文献:10.1002/cbic.200600066
摘要:Faulkner JR, Hussaini SR, Blankenship JD, Pal S, Branan BM, Grossman RB, Schardl CL. On the sequence of bond formation in loline alkaloid biosynthesis. Chembiochem. 2006 Jul;7(7):1078–88. doi: 10.1002/cbic.200600066.
参考文献:10.1186/1471-2458-8-100
摘要:Mouchtouri VA, Anagnostopoulou R, Samanidou-Voyadjoglou A, Theodoridou K, Hatzoglou C, Kremastinou J, Hadjichristodoulou C. Surveillance study of vector species on board passenger ships, risk factors related to infestations. BMC Public Health. 2008 Mar 27;8():100.
参考文献:10.1093/jee/tou058
摘要:Barker GM, Patchett BJ, Cameron NE. Epichloe uncinata Infection and Loline Content Protect Festulolium Grasses From Crickets (Orthoptera: Gryllidae). Journal of Economic Entomology. 2015 Feb 04;108(2):789–97. doi: 10.1093/jee/tou058.
参考文献:10.1016/s1087-1845(02)00023-3
摘要:Spiering MJ, Wilkinson HH, Blankenship JD, Schardl CL. Expressed sequence tags and genes associated with loline alkaloid expression by the fungal endophyte Neotyphodium uncinatum. Fungal Genet Biol. 2002 Aug;36(3):242–54. doi: 10.1016/s1087-1845(02)00023-3.
参考文献:10.1007/s11745-006-5118-2
摘要:Rymer C, Givens DI. Effect of species and genotype on the efficiency of enrichment of poultry meat with n-3 polyunsaturated fatty acids. Lipids. 2006 May;41(5):445–51. doi: 10.1007/s11745-006-5118-2.
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