CAS: 23868-34-0; Tetrabutylammonium (Hydrogen Difluoride)

该化合物是一种该化合物是一种稳定的,非湿性二氟化离子(HF2)源,在有机合成和氟化反应中具有价值,其优点包括:与气体或高度腐蚀性氟化物来源相比易于处理,有机溶剂的溶性得到改善,以及受控再活性.TBAHDF在脱保护,核循环氟和作为温性氟化剂方面特别有用.其固态稳定性和与无水条件的兼容性增强了其在精确应用中的效用,为传统氟化剂提供了更安全的替代品,同时保持选择性转化的高效.

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CAS号26735-53-5 iodobenzene dif... | CAS号429-41-4 四丁基氟化铵

合成工艺路线路线简述

    📜四丁基氟化铵,5-Amino-3-(5-Phenyl-1H-Pyrrol-2-yl)-1H-Pyrazole-4-Carboxamide 以 二甲基亚砜作为反应溶剂,获得 Tetrabutylazanium,Fluoride,Hydrofluoride,
    参考文献:A Highly Selective Fluorescent Sensor For Fluoride Anion Based On Pyrazole Derivative: Naked Eye "No-Yes" Detection
    标题:A Highly Selective Fluorescent Sensor For Fluoride Anion Based On Pyrazole Derivative: Naked Eye "No-Yes" Detection
    摘要:A New Pyrazole-Based Fluorescent Sensor,5-Amino-3-(5-Phenyl-1H-Pyrrol-2-yl)-1H-Pyrazole-4-Carboxamide (Compound 1),Was Studied For Fluoride Anion (F-) Detection In Organic Or Water-Containing Solution. This Compound Displayed Both Changes In Uv-Vis Absorption And Fluorescence Emission Spectra Upon Addition Of F-. With Increasing Of F-,Blue Emission Intensity Increases Drastically And Reaches Saturation With 607-Fold Enhancement At 424 Nm. The Results Indicate That Compound 1 Has Highly Selectivity For Fluoride Detection Over Other Anions,Such As Cl-,Br-,I-,Hso4-,H2Po4-And Aco-In Dmso Or Aqueous Dmso Solutions. H-1 Nmr Titration And Other Experiments Confirm That The Sensing Process Is Mainly From The Deprotonation Of The Pyrazole-Nh In Compound 1. (C) 2010 Elsevier B.V. All Rights Reserved.
    Doi:10.1016/J.Jphotochem.2010.09.012

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    专利信息


    专利号:CN-120041848-A
    优先权日:2025-02-18
    标 题 :Method for electrochemically synthesizing chiral beta-ester nitrile and application of chiral beta-ester nitrile in synthesis of baclofen and rolipram

    专利号:CN-117165967-A
    优先权日:2023-09-01
    标题 :A method for photoelectrochemical synthesis of alkenyl-containing unnatural amino acid derivatives

    专利号:CN-118704017-A
    优先权日:2024-07-03
    标题 :Method for electrochemical synthesis of lithium hexafluorophosphate

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Challenger, S., Science of Synthesis, (2007) 29, 42.
    摘要:Haufe, G., Science of Synthesis, (2005) 34, 169.
    摘要:Haufe, G., Science of Synthesis, (2005) 34, 357.
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