CAS: 202831-65-0; 4'-Bromo-N,N-Diphenyl-[1,1'-Biphenyl]-4-Amine

上下游产品

CAS号92-86-4 4,4-二溴联苯 | CAS号122-39-4 二苯胺 | CAS号105946-82-5 4-溴-4'-碘联苯 | CAS号589-87-7 对溴碘苯 | CAS号201802-67-7 4-(二苯基胺基)苯硼酸 | CAS号106-37-6 对二溴苯 | CAS号92-66-0 4-溴联苯 | CAS号36809-26-4 4-溴三苯胺 | CAS号167218-30-6 N,N,N'-三苯基联苯胺 | CAS号668493-36-5 4-(N,N-二氨基)联苯-4"-硼酸 | CAS号668493-37-6 4-[4-(4-bromoph...

4-溴三苯胺置于(1,1'-Bis(Diphenylphosphino)Ferrocene)Palladium(II) Dichloride,四(三苯基膦)钯,Potassium Acetate,Potassium Carbonate体系中,用 1,4-二氧六环,乙醇,水,甲苯 用作溶剂,化学反应 36.0H,反应生成4-溴-4'-(二苯氨基)联苯
参考文献:具有增强的三阶非线性光学性质的新型喹ac啶酮衍生物的研究
标题:具有增强的三阶非线性光学性质的新型喹ac啶酮衍生物的研究
摘要:设计并合成了七个新的喹ac啶酮衍生物.通过循环伏安法,Dft计算和z扫描研究了分子结构与非线性光学性质之间的关系.通过在喹ac啶酮的两侧引入强的给电子基团,然后引入强的吸电子基团二氰基乙烯基,可以有效地减小分子的带隙,并且可以促进分子内的电荷转移.结果表明,目标化合物的homo / Lumo带隙均减小,Qa-F具有最佳的三阶非线性光学性能,其γ(γ = 5.32x10-33 Esu)是其的4.38倍.Qa-1(γ = 1.21x10-33 Esu).
Doi:10.1016/j.Tet.2020.131169

专利信息

专利号:WO-2024185814-A1
优先权日:2023-03-06
标题:Method for producing aryl compound containing tritylsulfanyl group
发明人：OKAZOE TAKASHI; NOZAKI KYOKO; GATZENMEIER Tim; LIU YUE
权利人:AGC INC; UNIV TOKYO
摘要:The present invention provides: a substrate for achieving the highly efficient synthesis of an aryl compound containing a tritylsulfanyl group; a method for producing a compound containing an SF 5 group using the substrate; and others. The present invention is a method for producing an aryl compound containing a tritylsulfanyl group, the method comprising thiotritylating a halogenated aryl compound represented by general formula (1) [wherein A 1 represents an aryl group that may have a substituent or a heteroaryl group that may have a substituent; and X represents a halogen atom] using [(triphenylmethyl)sulfanyl]potassium or [(triphenylmethyl)sulfanyl]sodium to produce an aryl compound containing a tritylsulfanyl group, the aryl compound being represented by general formula (2) [wherein A 1 is the same as A 1 in general formula (1); and Ph represents a phenyl group].