CAS: 136-23-2; Zinc(Ii) Dibutyldithiocarbamate

相似化合物

13927-71-4 136-30-1 150-11-8

上下游产品

Di-n-butylammonium di-n-butyldithi°Carbamate zinc(II) chloride carbon disulfide dibutylaminebis(N,N-di-n-butyldithi°Carbamato)copper

福美锌,N,N-Dibutylcarbamodithioate;Tetramethylazanium 反应生成二丁基二硫氨基甲酸锌
参考文献:橡胶硫化的无机化学方面.第2部分.衍生自二烷基二硫代氨基甲酸酯,2-巯基-苯并噻唑,-苯并恶唑和-苯并咪唑的阴离子混合配体锌配合物,以及[net 4 ] [zn(s 2 Cnme 2)3 ],[nbu的晶体和分子结构ñ 4 ] [锌(c 7 H ^ 4 Ns 2)3(oh 2)],[nbu ñ 4 ] [锌(s 2 Cnme 2)2(c 7 H ^ 4 Ns 2)] C ^ 2 ^ H 5Oh和[nbu N 4 ] [zn(s 2 Cnme 2)(c 7 H 4 Ns 2)2 ]
标题:橡胶硫化的无机化学方面.第2部分.衍生自二烷基二硫代氨基甲酸酯,2-巯基-苯并噻唑,-苯并恶唑和-苯并咪唑的阴离子混合配体锌配合物,以及[net 4 ] [zn(s 2 Cnme 2)3 ],[nbu的晶体和分子结构ñ 4 ] [锌(c 7 H ^ 4 Ns 2)3(oh 2)],[nbu ñ 4 ] [锌(s 2 Cnme 2)2(c 7 H ^ 4 Ns 2)] C ^ 2 ^ H 5Oh和[nbu N 4 ] [zn(s 2 Cnme 2)(c 7 H 4 Ns 2)2 ]
摘要:的配合物[锌(s 2 Cnr 2)3 ]-(r = Me或et),[锌(s 2 Cnr 2)(s 2 Cnr' 2)2 ]-[r =甲基,乙基,或卜ñ ; R'= Me或et; R 2 =(ch 2)5,R'= Me或et],[zn(c 7 H 4 Ns 2)3(oh 2)]-(c 7 H 4 Ns 2 =苯并噻唑-2-硫醇盐),[锌(s 2 Cnr 2)2(c 7 H 4 Ns 2)]-[r = Me,Et或bu N;R 2 =(ch 2) 5 ],[zn(s 2 Cnr 2) 2(c 7 H 4 Nos)]-[r = Me,Et或bu N;R 2=(ch 2) 5;C 7 H 4 Nos =苯并恶唑-2-硫醇盐],[zn(s 2 Cnr 2)(c 7 H 4 Ns 2) 2 ]-[r = Me,Et,Bu N或c 6 H 11;R 2 =(ch 2) 5 ],[zn(s
Doi:10.1039/dt9800001945

专利信息

专利号:US-6184168-B1
优先权日:1997-09-22
标题:Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
发明人：LYNCH THOMAS J
权利人:BRIDGESTONE CORP
摘要:The invention provides a catalyst composition, comprising: (a) an organolithium compound; and, (b) an organic acid salt of lanthanide series element; wherein: (1) only components (a) and (b) are required to promote the synthesis of 1,4-trans-polybutadiene; (2) the ratio of component (a) to component (b) is selected to maximize formation of the trans structure of said 1,4-trans-polybutadiene; and, (3) components (a) and (b) are selected for enabling further diblock synthesis. The invention further contemplates a process for using the catalyst to synthesize 1,4-trans-polybutadiene and other polymers and copolymers having trans configuration in the conjugated diene monomer contributed units.

专利号:US-2009318592-A1
优先权日:2005-10-11
标 题 :Process for the Synthesis of Amine Ethers
发明人：FREY MARKUS; BROENNIMANN VALERIE
权利人:CIBA GEIGY CORP
摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

专利号:US-2007191516-A1
优先权日:2004-03-15
标题 :Process for the synthesis of amine ethers
发明人：FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

专利号:US-7402675-B2
优先权日:2000-05-26
标题 :Process for the synthesis of amine ethers from secondary amino oxides
发明人：HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
权利人:CIBA SC HOLDING AG
摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

专利号:WO-2014118073-A1
优先权日:2013-01-29
标 题 :Polysulfide polyols, their production and use in the synthesis of polyurethanes
发明人：BALBO BLOCK MARCO; RHUDY KEVIN; FLECKENSTEIN CHRISTOPH
权利人:BASF SE
摘要:The present invention relates to sulfur containing polyols, a process for their production by reaction of at least one unsaturated alcohol A with elemental sulfur, wherein the unsaturated alcohol A has only one carbon-carbon double bond-unsaturation per molecule. The sulfur containing polyols are used in the production of polyurethanes, in particular rigid foam polyurethanes, for high-temperature pipe insulation applications.

专利号:US-6417363-B1
优先权日:1997-12-04
标题 :Heterocyclyl ligand containing ruthenium and osmium catalysts
发明人：VAN DER SCHAAF PAUL ADRIAAN; MUEHLEBACH ANDREAS; HAFNER ANDREAS; KOLLY ROMAN
权利人:CIBA SC HOLDING AG
摘要:Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formulawherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groupswherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.