硅酸四乙酯置于苯基溴化镁体系中,用 Not Given 作为反应溶剂,化学反应生成 苯基三乙氧基硅烷 参考文献:Khotinsky,E.; Seregenkoff,B.,Archives Des Sciences Physiques Et Naturelles,1908,Vol. 25,P. 516-516 标题:Khotinsky,E.; Seregenkoff,B.,Archives Des Sciences Physiques Et Naturelles,1908,Vol. 25,P. 516-516
专利号:US-10768157-B2 优先权日:2015-10-20 标 题:Materials and methods for the detection of trace amounts of substances in biological and environmental samples 发明人:KABIR ABUZAR; FURTON KENNETH G 权利人:KABIR ABUZAR; FURTON KENNETH G; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES 摘要:The subject invention provides chemical compositions and synthesis strategies to create molecularly imprinted polymers (MIPs) via sol-gel processes. In a specific embodiment, the subject invention utilizes a(n) organic, inorganic, or metallic template analyte to create a hybrid organic-inorganic or inorganic three-dimensional network possessing cavities complementary to the shape, size, and functional orientation of the template molecule or ions. The subject invention further pertains to the use of the novel MIPs as selective solid phase extraction (SPE) sorbents for pre-concentration and clean-up of trace substances in biological and environmental samples. Synthesis of other molecularly imprinted polymers with environmental, pharmaceutical, chemical, clinical, toxicological, and national security implications can be conducted in accordance with the teachings of the subject invention.
专利号:US-5166110-A 优先权日:1989-12-22 标 题 :Process for the synthesis of ziegler-type catalytic solids or solid constituents of the same 发明人:BRUN CLAUDE 权利人:ATOCHEM ELF SA 摘要:A process is provided for the synthesis of a solid Ziegler catalyst or of a transition metal solid constituent thereof, which entails preparing the solid catalyst or constituent thereof as a suspension in an inert liquid medium by contacting precursors or ingredients of the catalyst or of the constituent in the inert liquid medium in one or more steps, and drying the suspension, and collecting the catalyst or constituent thereof; and wherein the process is conducted in a single multi-function reactor having a longitudinal axis and which can pivot around an axis which intersects perpendicularly with this axis.
专利号:US-10611864-B2 优先权日:2015-09-22 标 题:Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins 发明人:ZUIDEVELD MARTIN ALEXANDER; SAINANI JAIPRAKASH BRIJLAL; AL-HUMAIDAN OSAMAH; PADMANABHAN SUDHAKAR R; SHINGE PRASHANT SUKUMAR; SHETTY SHARANKUMAR G; SHAIKH ABBAS-ALLI GHUDUBHAI 权利人:SABIC GLOBAL TECHNOLOGIES BV 摘要:The present invention relates to a compound according to Formula (I) wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom, an aryl group or an alkyl group; and wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently a hydrogen atom, a halogen atom, a cyano group, an amino group, a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups or an alkoxy group, and one or more combinations thereof as internal electron donor and to a process for the synthesis of a compound according to Formula (I), wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom or an alkyl group; wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently selected from a group consisting of a hydrogen atom; a hydrocarbyl, preferably, said process comprising the step of reacting a compound according to Formula (II) [R 1 —C(â•?O)Cl] with a compound according to Formula (III) to obtain the compound according to Formula (I) and to the use of these compounds as internal donor in Ziegler-Natta catalysis of lefins.
专利号:US-2010119736-A1 优先权日:2008-10-07 标题 :Ambient pressure synthesis of zeolite films and their application as corrosion resistant coatings 发明人:YAN YUSHAN; CAI RUI; SUN MINWEI 权利人:UNIV CALIFORNIA 摘要:A method for producing zeolite films or membranes at essentially ambient pressure, which includes preparing a synthesis mixture comprising an ionic liquid solvent and an aluminum and/or silicon and/or phosphate source and converting the synthesis mixture to form a continuous zeolite layer. In addition, a method of synthesizing zeolite nanocrystals, which includes preparing a synthesis mixture, the synthesis mixture having a silica or a silica and alumina source, and a template; and synthesizing the synthesis mixture to form zeolite nanocrystals.
专利号:US-2010098623-A1 优先权日:2007-02-07 标 题 :Zeolite materials and synthesis method thereof 发明人:GAGEA BOGDAN; JACOBS PIERRE; MARTENS JOHAN; VANDEPITTE HANS 权利人:GAGEA BOGDAN; JACOBS PIERRE; MARTENS JOHAN; VANDEPITTE HANS 摘要:The present invention provides zeolites and zeolite-like material having an enhanced microporosity. It was found that such zeolites can be obtained using a zeolite synthesis method comprising the preparation of a gel or solution for the synthesis of a zeolite, said gel or solution comprising appropriate amounts of (i) a conventional monomeric or polymeric silica source and (ii) a molecular template as a microstructuring agent, characterized in that said gel or solution further comprises an organosilane compound having limited self-assembling capacity.
专利号:US-4616097-A 优先权日:1984-10-22 标 题:Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon-containing promoter at a temperature of at least 50 DEG C. and a pressure of at least 500 psi.
[参考文献]: Frank M Hauser, Et Al. Improvement In Fingerprint Detection Using Tb(Iii)-Dipicolinic Acid Complex Doped Nanobeads And Time Resolved Imaging. Forensic Sci Int. 2015 Aug:253:55-63. [参考文献]: Yueer Yan, Et Al. Silanization-Based Zeolite Crystallization: Participation Degree And Pathway. Chemistry. 2015 Aug 17;21(34):12161-70.
合成参考文献
摘要:Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 591. 摘要:Sartori, G.; Maggi, R., Science of Synthesis, (2010) 47, 520. 摘要:Stanforth, S. P., Science of Synthesis Knowledge Updates, (2015) 1, 184. 摘要:Denmark, S.; Chang, W.-T. T., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 407. 摘要:Denmark, S.; Chang, W.-T. T., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 416.