CAS: 34539-84-9; (4Bs,8As)-2-Isopropyl-4B,8,8-Trimethyl-4B,5,6,7,8,8A-Hexahydrophenanthren-3-Ol

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    上下游产品

    ferruginol (4bS-trans)-4b,5,6,7,8,8a-Hexahydro-4b,8,8-trimethyl-2-(1-methylethyl)-3-phenanthrenylacetat taxodione Acetic acid (S)-2-isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a-hexahydro-phenanthren-3-yl ester (+)-taxodione

    合成工艺路线路线简述

      📜6β-Hydroxyferruginol置于对甲苯磺酸体系中,用 丙酮 作为反应溶剂,化学反应 24.0H,以4 Mg的收率获得产物△6-去氢弥罗松酚
      参考文献:6-Oxoferruginol And 6α-Acetoxyferruginol,New Abietane-Type Diterpenes From The Heartwood Of Juniperus Formosana
      标题:6-Oxoferruginol And 6α-Acetoxyferruginol,New Abietane-Type Diterpenes From The Heartwood Of Juniperus Formosana
      摘要:New Abietane Diterpenes,6 Alpha-Acetoxyferruginol And 6-Oxoferruginol Were Isolated From The Heartwood Of Juniperus Formosana Hay. Var. Concolor Hay. Together With The Known Compounds Ferruginol,Sugiol,Xanthoperol,5-Epi-Xanthoperol,And 6,12-'Dihydroxyabieta-5,8,11,13-Tetraen-7-One. The Structures Of The New Compounds Were Elucidated On The Basis Of Spectral And Chemical Evidence.
      DOI:10.1021/np960389X

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      ✅ COA系统入驻 | 共享模式

      合成参考文献


      参考文献:10.1016/0031-9422(92)83493-i
      摘要:Luis JG, González AG, Andrés LS, Mederos S. Diterpenes from in vitro-grown Salvia canariensis. Phytochemistry. 1992 Sep;31(9):3272–3. doi: 10.1016/0031-9422(92)83493-i.
      参考文献:10.1016/s0040-4020(01)87965-5
      摘要:Luis JG, Grillo TA. New diterpenes from Salvia munzii: chemical and biogenetic aspects. Tetrahedron. 1993 Jul;49(28):6277–84. doi: 10.1016/s0040-4020(01)87965-5.
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