CAS: 2625-41-4; Nitrocyclobutane

相似化合物

6291-01-6 2516-34-9 1812174-83-6

上下游产品

CAS号51175-81-6 1-溴-1-硝基环丁烷 | CAS号2972-05-6 环丁烷酮肟 | CAS号463-49-0 丙二烯 | CAS号75-07-0 乙醛 | CAS号106-99-0 丁二烯 | CAS号74-86-2 乙炔 | CAS号1191-95-3 环丁酮 | CAS号2516-34-9 环丁基胺

📜环丁烷酮肟置于双氧水,碳酸氢钠,尿素,三氟乙酸酐体系中,用 水,乙腈 用作溶剂,化学反应 3.0H,以25%的收率获得硝基环丁烷
参考文献:对映选择性铱催化硝基烷烃的烯丙基化:反应生成β-立体异构 α-季伯胺
标题:对映选择性铱催化硝基烷烃的烯丙基化:反应生成β-立体异构 α-季伯胺
摘要:描述了铱催化烯丙基烷基化中简单硝基亲核试剂的首次系统研究.使用tol-Binap修饰的π-烯丙基铱c,O-苯甲酸酯催化剂,α,α-二取代硝基化合物取代外消旋支链烷基取代的烯丙基乙酸酯,从而提供β-立体异构α-季伯胺的入口. Dft 计算揭示了早期过渡态,使反应对空间效应和非对映手性铱 π-烯丙基络合物的明显反式效应不太敏感,从而促进了拥挤的三级-四级 C-C 键的形成.
Doi:10.1021/jacs.1C05212

专利信息

专利号:US-8492541-B1
优先权日:2007-07-16
标 题:Synthesis of azido heterocycles
发明人：DUDDU RAJA; DAVE PARITOSH; DAMAVARAPU REDDY; SURAPANENI RAO
权利人:DUDDU RAJA; DAVE PARITOSH; DAMAVARAPU REDDY; SURAPANENI RAO; US ARMY
摘要:Energetic candidate azido heterocycles and their synthesis are described.

专利号:WO-2007005037-A1
优先权日:2005-06-30
标 题 :Process for synthesis of diorganosilanes by disproportionation of hydridosiloxanes
发明人：RUBINSZRAJN SLAWOMIR; CELLA JAMES ANTHONY; CHOJNOWSKI JULIAN; FORTUNIAK WITOLD; KURJATA JAN
权利人:GEN ELECTRIC; RUBINSZRAJN SLAWOMIR; CELLA JAMES ANTHONY; CHOJNOWSKI JULIAN; FORTUNIAK WITOLD; KURJATA JAN
摘要:The present invention provides a novel method for the preparation of diorganosilanes by disproportionation of a hydridosiloxanes comprising at least one terminal SiH group and at least one siloxane bond in the presence of Lewis acid catalysts. The reaction is both selective and occurs under mild conditions. The triaryl borane, tris(petafluorophenyl)borane, is especially suited for use as a catalyst in the reaction. Organic catalysts such as tris(pentafluorophenyl)borane are typically preferred owing to their greater solubility and stability in the reaction mixture, relative to inorganic Lewis acid catalysts. The product, diorganosilane may be isolated from the product mixture by conventional techniques such as distillation.

专利号:US-7148370-B1
优先权日:2005-07-20
标 题 :Process for synthesis of diorganosilanes by disproportionation of hydridosiloxanes
发明人：RUBINSZTAJN SLAWOMIR; CELLA JAMES ANTHONY; CHOJNOWSKI JULIAN; FORTUNIAK WITOLD; KURJATA JAN
权利人:GEN ELECTRIC
摘要:The present invention provides a novel method for the preparation of diorganosilanes by disproportionation of a hydridosiloxanes comprising at least one terminal SiH group and at least one siloxane bond in the presence of Lewis acid catalysts. The reaction is both selective and occurs under mild conditions. The triaryl borane, tris(petafluorophenyl)borane, is especially suited for use as a catalyst in the reaction. Organic catalysts such as tris(pentafluorophenyl)borane are typically preferred owing to their greater solubility and stability in the reaction mixture, relative to inorganic Lewis acid catalysts. The product, diorganosilane may be isolated from the product mixture by conventional techniques such as distillation.

专利号:US-8133993-B1
优先权日:2005-09-21
标题:Hydrogenolytic denitration of polynitro compounds: pentanitrohexaazaisowurtzitane
发明人：DUDDU RAJA; DAVE PARITOSH; DAMAVARAPU REDDY; SURAPANENI RAO
权利人:DUDDU RAJA; DAVE PARITOSH; DAMAVARAPU REDDY; SURAPANENI RAO; US ARMY
摘要:A method for synthesizing pentanitrohexaazaisowurtzintane under neutral reaction conditions. Which synthesis involves treating a solution of hexanitrohexaazaisowurtzitane in ethyl acetate in the presence of a catalytic quantity of palladium on a carbon substrate, until a heterogeneous mixture is formed. This heterogeneous mixture is hydrogenated under a balloon atmosphere until the starting hexanitrohexaazaisowurtzitane is substantially reacted. The resulting pentanitrohexaazaisowurzitane mixture is filtered, dried and recovered from the dried residue through a Si-gel column.

专利号:EP-1913059-A1
优先权日:2005-06-30
标题:Process for synthesis of diorganosilanes by disproportionation of hydridosiloxanes

专利号:US-8153786-B1
优先权日:2007-07-16
标 题 :Synthesis of azido heterocycles